Effect of Precursors on Trimetallic Ruthenium-Based Catalysts Supported on γ-Al 2 O 3 Pellets for Low-Temperature Ammonia Decomposition
Not Available
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Engineering topics
Angelette, Lucas M.
Publications and source records attributed to Angelette, Lucas M..
Evaluation of Getters for Helium Purification
• Helium-3 is a vital commodity in both medical and defense applications • Ultra-low cryogenic coolant (MRI imaging, etc.) • Neutron detectors • Being investigated as possible fusion fuel • Managed and distributed by DOE-OS • New PDRD project exploring helium isotope separation • Limited supply • Only available from tritium decay • Prohibitively difficult to separate from helium-4 • SRS Tritium Facility provides a steady source
Angelette, Lucas M.↗
Synthesis of Zeolites LiX and LiAgX
In this work, we produced approximately 50 grams of zeolite LiX and 50 grams of zeolite LiAgX from commercially available zeolite X. The production of the two specialized zeolite phases was accomplished via a series of ion exchange steps followed by washing, drying, and calcining to produce the final materials. The ion exchange was confirmed by several methods including inductively-coupled plasma emission spectroscopy of exchange solution aliquots, gravimetric analysis, energy dispersive x-ray spectroscopy, and X-ray diffraction. We synthesized approximately 115 grams of zeolite LiX in a large-scale production step after completing a proof-of-concept experiment demonstrating the methodology. The production of zeolite LiX from zeolite X yielded an ion exchange (Li + →Na + ) of approximately 82%. The production of zeolite LiAgX from the previously synthesized zeolite LiX was targeted to exchange approximately 20% of the Li + ions with Ag + ions. We first performed a proof-of-concept experiment demonstrating the reaction pathway and selectivity of the Ag + ion, and then performed a large-scale synthesis of zeolite LiAgX using approximately 50 grams of the zeolite LiX. Our final exchange percentage of silver into the zeolite LiX matrix was approximately 20.8%.
36 MATERIALS SCIENCE↗
Tritium Compatible Pump Development
Vacuum pumps are routinely discontinued for newer models, discontinued permanently, or manufacturers go out of business. It is necessary that new pump models and technologies are evaluated for tritium service, and even what can be done for pumps are not rated for tritium service to be re-engineered for tritium service.
Klein, James E.↗
Halogen Removal from Tritium Gas Streams
Halogen impurities are poisonous and/or corrosive • Poison for catalysts and equipment • Causes pitting in most austenitic stainless steels • Minimized to prevent damage over time • Prone to appear in certain processes • Appear if certain materials degrade (i.e., elastomers, etc.) • Present as trace impurities in a large number of metals and zeolites (<200 ppm)
Angelette, Lucas M.↗