Engineering topics

Ajo, Henry

Publications and source records attributed to Ajo, Henry.

4 records

DOE OSTI2024

Magnetic properties of Lutetium and Yttrium doped Ce 2 Fe 14 B magnets

The increasing demand for Nd-Dy and Sm-Co based permanent magnets is exacerbating the current critical materials shortage, therefore improving and optimizing current candidate critical element free permanent magnets is necessary to develop future clean energy technologies. In this work, we aim to increase the thermal stability and magnetic performance of Ce 2 Fe 14 B based permanent magnets through the substitution of Ce ions with noncritical rare earth elements Lu and Y. The substitution of Lu (x=0; 0.05; 0.1; 0.15) for Ce ions in (LuxCe 2-x )Fe 14 B was unsuccessful, likely due to disparities in ionic size and valencies, and failed to exhibit improved thermal stability or magnetic performance. In contrast, Y substitution for Ce ions in (Y x Ce 2-x )Fe14B (x= 0.1; 0.2; 0.3; 0.4; 0.5) alloys was successful. Notably, these alloys demonstrated enhanced thermal stability, as evidenced by an increase in the Curie temperature, reaching a peak of 443 K at x= 0.5. Y substitution also helped to suppress the CeFe2 Laves phase. Without loss of the anisotropy field Y substitution increased the saturation magnetization, MS, peaking at MS = 125 emu/g for a Y concentration of x= 0:4, demonstrating (Y 0.4 Ce 1.6 )Fe 14 B as a potential critical element free permanent magnet with an energy product as high as 29 MGOe. This work is advantageous in developing low cost high performance permanent magnets with reduced or little to no critical rare earth elements.

Rai, Binod K.↗

DOE OSTI2023

Structure and properties of NdCuGa 3 single crystals

Here this manuscript reports on the structural and magnetic properties of NdCuGa 3 using powder and single crystal X-ray diffraction (XRD), zero-field single crystal neutron diffraction, magnetization, and specific heat measurements. Our XRD on a single crystal specimen of NdCuGa3 confirmed that it crystallizes in the tetragonal BaNiSi 3 -type structure. A magnetic phase transition at T N = 3.3 K is assessed using specific heat and ac magnetic susceptibility measurements. No additional anomaly below T N down to 50 mK was detected by performing specific heat measurements. Neutron single crystal diffraction data collected at T = 300 mK confirm the antiferromagnetic phase below T N = 3.3 K with the propagation vector $\vec{\tau}$ = (0.2, 0, 0). Possible magnetic structure solutions of NdCuGa 3 are discussed

36 MATERIALS SCIENCE↗

DOE OSTI2021

Growth and Development of Quantum Materials

Topological insulators (TIs) display a new state of quantum matter, which is broadly known as quantum materials. The TIs have a unique property of being an insulator as a bulk property and having conducting surface states, which are symmetry-protected Dirac Fermions and well isolated from the bulk valence and conduction bands. Ideally, these topological surface states and bulk electronic states should act independently. The degree to which they intermix depends on the crystalline quality, composition and defects present in the material. These materials thus demand very high-quality crystals to observe the desired quantum properties. We proposed growth of high-quality single crystals and thin films to enhance the ability to fabricate devices with unique performance attributes. Two separate approaches will be made to make the thin films, one is exfoliation of 2D monolayer from the grown single crystals and the second is thin films grown by pulsed laser deposition. Both techniques will subsequently allow for fabrication of meso structures using a Focused Ion Beam technique.

36 MATERIALS SCIENCE↗

DOE OSTI2019

Particle Size Analysis and Distribution

Scanning Electron Microscope (SEM) is a instrument used for examining samples at magnifications from 32 X to 500,000 X (for our instrument). The SEM is attached with an electron gun and is directed onto the sample. The sample then produces an image where it is read on the monitor. The electron gun is positioned at the top because it needs to shoot at the sample that is being tested. The electrons are then shot in a downward motion traveling through several lenses, such as the condenser lens for a more precise reading. Once the samples have been read by the instrument, it will show a picture that has a certain number of particles. Particle size distribution have many uses that are essential to life habits (health) or even conventional use for example construction. Here are just a few examples of how particle size analysis and distribution are being used even today. This Standard Reference Material (SRM) is primarily intended for use in the calibration of equipment used to measure particle size distributions (PSD) in the 9 μm to 30 μm range. A unit of SRM 1984 consists of a single bottle containing approximately 14 g of tungsten carbide/cobalt powder. Certified values: The PSD values at five mass percentiles were measured by scanning electron microscopy (SEM) and laser light scattering (LLS). The NIST certified PSD values by SEM are listed. These certified values were determined by the measurement of over 10 000 individual particles from three bottles. Comparing the certified NIST SRM 1984 tungsten carbide/cobalt powder with our results are almost identical. This is great because more accurate work can be done and proves that our laboratory is able to reproduce NIST results. In conclusion, the scanning electron microscope is used to capture the sampled element and display it to be counted. Without the use of particle distribution, it would be a difficult time to get necessities such as medicine, asthma pumps, constructing materials, or as simple as ink. Overall, our study is an experimental comparison of the techniques we have in house, which are LLS and SEM (combined with the NIH ImageJ software) using the NIST SRM-1984 as a common, well characterized sample so that we have an idea of how the results from the techniques compare.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗