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At least 19 records
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

The possibility of hydrogen-water demixing in Uranus, Neptune, K2-18 b and TOI-270 d

Context. The internal structures of Uranus and Neptune remain unknown. In addition, sub-Neptunes are now thought to be the most common type of exoplanets. Improving our understanding of the physical processes that govern the interiors of such planets is therefore essential. Phase separation between planetary constituents may occur, in particular, hydrogen-water immiscibility in cold, water-rich intermediate-mass planets. Aims. We assess whether hydrogen-water demixing could occur in Uranus, Neptune, K2-18 b and TOI-270 d, and investigate its effect on the planetary evolution and inferred internal structure. Methods. We couple planetary evolution models with recent ab initio calculations of the hydrogen-water phase diagram, allowing for temperature shifts to account for uncertainties in miscibility gaps. Results. We find that demixing may occur and could lead to a complete depletion of water in the outermost regions of Uranus and Neptune. Temperature offsets of up to 1100 K lead to a depleted region comprising as much as 16% of the planet’s mass, and an increase in planetary radius by nearly 20%. For K2-18 b, our models suggest that hydrogen-water demixing is ongoing and may explain the absence of water features in its JWST spectrum. A temperature offset of 500 K is required to get a complete depletion of water in the atmosphere of K2-18b. TOI-270d may also have experienced hydrogen-water demixing. When applying a similar temperature offset on the phase diagram as for K2-18 b, we find a partial depletion of water in the atmosphere of TOI-270 d, consistent with JWST’s detection of water. Conclusions. Hydrogen-water immiscibility may play a key role in shaping the structure and evolution of both Solar System giant planets like Uranus and Neptune, and cold/temperate exoplanets such as K2-18 b and TOI-270 d. Accounting for such internal processes is crucial to accurately interpret atmospheric observations from current (e.g., JWST) and upcoming (e.g., ARIEL) missions.

planets and satellites: composition↗
DOE OSTI2024

Uranus Study Report: KISS

Determining the internal structure of Uranus is a key objective for planetary science. Knowledge of Uranus’s bulk composition and the distribution of elements is crucial to understanding its origin and evolutionary path. In addition, Uranus represents a poorly understood class of “intermediate-mass planets" (intermediate in size between the relatively well studied terrestrial and gas giant planets), which appear to be very common in the Galaxy. As a result, a better characterization of Uranus will also help us to better understand exoplanets in this mass and size regime.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2026

Rotation‐Controlled Diurnal Evolution of Uranus' Asymmetric Bow Shock at Equinox

Uranus possesses the most extreme magnetic and rotational geometry in the solar system, resulting in a uniquely dynamic and asymmetric interaction between its magnetosphere and the solar wind. Here we investigate the diurnal evolution of the Uranian bow shock (BS) at equinox using global multifluid magnetohydrodynamic simulations constrained by Voyager 2 observations. The BS structure and variability are quantified using the stand‐off distance, terminator distance, flaring parameter, and BS parameter, enabling a systematic assessment of its global asymmetry over one planetary rotation. Our results show that the BS exhibits pronounced diurnal asymmetry that is primarily controlled by planetary rotation. Even under steady upstream solar wind conditions, the BS undergoes periodic expansion and contraction, reflecting rotation‐driven reconfiguration of the planetary magnetospheric topology. This diurnal modulation represents a remarkably large asymmetry in planetary BS geometry within the solar system. These results establish planetary rotation as the intrinsic primary driver of Uranus' BS dynamics at equinox and provide essential constraints for the design and formulation of future space missions to the ice giants. These findings also offer a unique framework for understanding shock physics in the abundant population of ice‐giant exoplanets.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2025

Auroral and Non‐Auroral H 3 + Ion Winds at Uranus With Keck‐NIRSPEC and IRTF‐iSHELL

Abstract To date, no investigation has documented ionospheric flows at Uranus. Previous investigations of Jupiter and Saturn have demonstrated that mapping ion winds can be used to understand ionospheric currents and how these connect to magnetosphere‐ionosphere coupling. We present a study of Uranus's near infrared emissions (NIR) using data from the Keck II Telescope's Near InfraRed SPECtrograph (NIRSPEC) and the InfraRed Telescope Facility's iSHELL spectrograph. H 3 + emission lines were used to derive dawn‐to‐dusk intensity, ionospheric temperatures and ion densities to identify auroral emissions, with their Doppler shifts used to measure ion velocities. We confirm the presence of the southern NIR aurora in 2016, driven by elevated H 3 + column densities up to 6.0 × 10 16 m −2 . While no auroral emissions were detected in 2014, we find a 14%–20% super rotation across the planet's disk in 2014 and a 7%–18% super rotation in 2016.

Thomas, Emma M. [Department of Mathematics Physics↗
DOE OSTI2023

Thermodynamics of diamond formation from hydrocarbon mixtures in planets

Hydrocarbon mixtures are extremely abundant in the Universe, and diamond formation from them can play a crucial role in shaping the interior structure and evolution of planets. With first-principles accuracy, we first estimate the melting line of diamond, and then reveal the nature of chemical bonding in hydrocarbons at extreme conditions. We finally establish the pressure-temperature phase boundary where it is thermodynamically possible for diamond to form from hydrocarbon mixtures with different atomic fractions of carbon. Notably, here we show a depletion zone at pressures above 200 GPa and temperatures below 3000 K-3500 K where diamond formation is thermodynamically favorable regardless of the carbon atomic fraction, due to a phase separation mechanism. The cooler condition of the interior of Neptune compared to Uranus means that the former is much more likely to contain the depletion zone. Our findings can help explain the dichotomy of the two ice giants manifested by the low luminosity of Uranus, and lead to a better understanding of (exo-)planetary formation and evolution.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2020

Composition and Dynamical Processes of Ions in Giant Magnetospheres: The Importance of In Situ Measurements for Advancing the Current Knowledge [Slides]

In this white paper, we emphasize the importance of in situ ion composition measurements provided by plasma mass spectrometers in planetary magnetospheres (Uranus and Neptune) aimed for future planetary missions. We present our current understanding on magnetospheres of Uranus and Neptune that are largely based on Plasma Science Investigation (PLS, faraday cups) and Low Energy Charged Particle (LECP) instrument on Voyager 2 and what measurements need to be made to improve it. We emphasize that the future missions equipped with plasma mass spectrometers must visit these magnetospheres again to advance our current knowledge. Finally, this white paper summarizes key science questions that needs to be addressed which all of them requires a direct ion composition measurements from a plasma spectrometer.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2025

Experimental Pathways for Detecting Double Superionicity in Planetary Ices

The ice giant planets Uranus and Neptune are assumed to contain large amounts of planetary ices such as water, methane, and ammonia. The properties of mixtures of such ices at the extreme pressures and temperatures of planetary interiors are not yet well understood. Ab initio computer simulations have predicted that a number of ices exhibit a hydrogen superionic state and a doubly superionic state. Since the latter state has not yet been generated with experiments, we outline here two possible pathways for reaching and detecting such a state with dynamic compression experiments. Here, we suggest X-ray diffraction as the principal tool for detecting when the material becomes doubly superionic and the sublattice of one of the heavy nuclei melts. That would require a temperature of ~3500 K and pressures greater than ~200 GPa for H 3 NO 4 , which we use as an example material here. Such conditions can be reached with experiments that employ an initial shock that is followed by a ramp compression wave. Alternatively, one may use triple-shock compression because a single shock does not yield sufficiently high densities.

Neptune↗
DOE OSTI2024

Diamond precipitation dynamics from hydrocarbons at icy planet interior conditions

The pressure and temperature conditions at which precipitation of diamond occurs from hydrocarbon mixtures is important for modelling the interior dynamics of icy planets. However, there is substantial disagreement from laboratory experiments, with those using dynamic compression techniques finding much more extreme conditions are required than in static compression. Here we report the time-resolved observation of diamond formation from statically compressed polystyrene, (C 8 H 8 ) n , heated using the 4.5 MHz X-ray pulse trains at the European X-ray Free Electron Laser facility. Diamond formation is observed above 2,500 K from 19 GPa to 27 GPa, conditions representative of Uranus’s and Neptune’s shallow interiors, on 30 μs to 40 μs timescales. This is much slower than may be observed during the ~10 ns duration of typical dynamic compression experiments, revealing reaction kinetics to be the reason for the discrepancy. In conclusion, reduced pressure and temperature conditions for diamond formation has implications for icy planetary interiors, where diamond subduction leads to heating and could drive convection in the conductive ice layer that has a role in their magnetic fields.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2021

Superionic iron oxide–hydroxide in Earth’s deep mantle

Water ice becomes a superionic phase under the high pressure and temperature conditions of deep planetary interiors of ice planets such as Neptune and Uranus, which affects interior structures and generates magnetic fields. The solid Earth, however, contains only hydrous minerals with a negligible amount of ice. Here we combine high pressure and temperature electrical conductivity experiments, Raman spectroscopy and first-principles simulations to investigate the state of hydrogen in the pyrite-type FeO 2 H x (x ≤ 1), which is a potential H-bearing phase near the core–mantle boundary. We find that when the pressure increases beyond 73 GPa at room temperature, symmetric hydroxyl bonds are softened and the H + (or proton) becomes diffusive within the vicinity of its crystallographic site. Increasing temperature under pressure, the diffusivity of hydrogen is extended beyond the individual unit cell to cover the entire solid, and the electrical conductivity soars, indicating a transition to the superionic state, which is characterized by freely moving protons and a solid FeO 2 lattice. Furthermore, the highly diffusive hydrogen provides fresh transport mechanisms for charge and mass, which dictate the geophysical behaviours of electrical conductivity and magnetism, as well as geochemical processes of redox, hydrogen circulation and hydrogen isotopic mixing in Earth’s deep mantle.

58 GEOSCIENCES↗
DOE OSTI2022

Orbital stability analysis of hypothetical Earth-mass and Luna-mass moons in the Sagarmatha (HD 100777) star system

Abstract Six of the solar system planets have 150 confirmed moons (Earth—1, Mars—2, Jupiter—53, Saturn—53, Uranus—27, Neptune—14) and seven of them (Ganymede, Titan, Callisto, Io, the Moon, Europa, Triton) have masses >0.001 $M_\oplus$. However, no exomoons have yet been discovered despite the successful detection of ∼5000 exoplanets. We can infer, based on the solar system planets, that these exoplanets are capable of hosting one or more exomoons. In this paper, we study the possible existence of hypothetical Earth-mass and Luna-mass moons orbiting the Jupiter-mass planet, Laligurans (HD 100777b) in the Sagarmatha (HD 100777) star system by means of orbital stability. We apply long-term orbital integrations and the MEGNO (mean exponential growth of nearby orbits) chaos indicator to study the orbital stability of the moons and predict a phase-space region comprising periodic, chaotic, and unstable orbits. The phase spaces primarily constitute the moon's semimajor axis, which extends from the host planet's Roche radius to the Hill radius, and full range of eccentricity. Specific points are picked from three different regions of the MEGNO map and run as single-orbit integration for up to 10 billion periods of the innermost orbit. Furthermore, the lifetime and maximum eccentricity maps are generated from the direct integration to inspect the stable and unstable orbital configurations. The analyses of these maps, with the aid of time-series plots, show that both moons maintain stable orbits in the low-eccentricity regime and semimajor axis between the Roche limit and 28.4% of the Hill radius of the planet.

Gautam, Aayush (ORCID:0000000247257589)↗
DOE OSTI2020

Measurement of diamond nucleation rates from hydrocarbons at conditions comparable to the interiors of icy giant planets

We present measurements of the nucleation rate into a diamond lattice in dynamically compressed polystyrene obtained in a pump-probe experiment using a high-energy laser system and in situ femtosecond x-ray diffraction. Different temperature-pressure conditions that occur in planetary interiors were probed. For a single shock reaching 70 GPa and 3000 K no diamond formation was observed, while with a double shock driving polystyrene to pressures around 150 GPa and temperatures around 5000 K nucleation rates between 10 29 and 10 34 m –3 s –1 were recorded. These nucleation rates do not agree with predictions of the state-of-the-art theoretical models for carbon-hydrogen mixtures by many orders of magnitude. Our data suggest that there is significant diamond formation to be expected inside icy giant planets like Neptune and Uranus.

43 PARTICLE ACCELERATORS↗
DOE OSTI2022

Diamond formation kinetics in shock-compressed C$-$H$-$O samples recorded by small-angle x-ray scattering and x-ray diffraction

Extreme conditions inside ice giants such as Uranus and Neptune can result in peculiar chemistry and structural transitions, e.g., the precipitation of diamonds or superionic water, as so far experimentally observed only for pure C$-$H and H 2 O systems, respectively. Here, we investigate a stoichiometric mixture of C and H 2 O by shock-compressing polyethylene terephthalate (PET) plastics and performing in situ x-ray probing. We observe diamond formation at pressures between 72 ± 7 and 125 ± 13 GPa at temperatures ranging from ~3500 to ~6000 K. Combining x-ray diffraction and small-angle x-ray scattering, we access the kinetics of this exotic reaction. The observed demixing of C and H 2 O suggests that diamond precipitation inside the ice giants is enhanced by oxygen, which can lead to isolated water and thus the formation of superionic structures relevant to the planets’ magnetic fields. Moreover, our measurements indicate a way of producing nanodiamonds by simple laser-driven shock compression of cheap PET plastics.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Ryugu's nucleosynthetic heritage from the outskirts of the Solar System

Little is known about the origin of the spectral diversity of asteroids and what it says about conditions in the protoplanetary disk. Here we show that samples returned from Cb­type asteroid Ryugu have Fe isotopic anomalies indistinguishable from Ivuna­type (CI) chondrites, which are distinct from all other carbonaceous chondrites. Iron isotopes, therefore, demonstrate that Ryugu and CI chondrites formed in a reservoir that was different from the source regions of other carbonaceous asteroids. Growth and migration of the giant planets destabilized nearby planetesimals and ejected some inwards to be implanted into the Main Belt. In this framework, most carbonaceous chondrites may have originated from regions around the birthplaces of Jupiter and Saturn, while the distinct isotopic composition of CI chondrites and Ryugu may reflect their formation further away in the disk, owing their presence in the inner Solar System to excitation by Uranus and Neptune

58 GEOSCIENCES↗
DOE OSTI2020

The Great Inequality and the Dynamical Disintegration of the Outer Solar System

Using an ensemble of N-body simulations, this paper considers the fate of the outer gas giants (Jupiter, Saturn, Uranus, and Neptune) after the Sun leaves the main sequence and completes its stellar evolution. Due to solar mass loss—which is expected to remove roughly half of the star’s mass—the orbits of the giant planets expand. This adiabatic process maintains the orbital period ratios, but the mutual interactions between planets and the width of mean-motion resonances (MMR) increase, leading to the capture of Jupiter and Saturn into a stable 5:2 resonant configuration. The expanded orbits, coupled with the large-amplitude librations of the critical MMR angle, make the system more susceptible to perturbations from stellar flyby interactions. Accordingly, within about 30 Gyr, stellar encounters perturb the planets onto the chaotic subdomain of the 5:2 resonance, triggering a large-scale instability, which culminates in the ejections of all but one planet over the subsequent ∼10 Gyr. After an additional ∼50 Gyr, a close stellar encounter (with a perihelion distance less than ∼200 au) liberates the final planet. Through this sequence of events, the characteristic timescale over which the solar system will be completely dissolved is roughly 100 Gyr. Our analysis thus indicates that the expected dynamical lifetime of the solar system is much longer than the current age of the universe, but is significantly shorter than previous estimates.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2022

K2-79b and K2-222b: Mass Measurements of Two Small Exoplanets with Periods beyond 10 days that Overlap with Periodic Magnetic Activity Signals

We present mass and radius measurements of K2-79b and K2-222b, two transiting exoplanets orbiting active G-type stars observed with HARPS-N and K2. Their respective 10.99 day and 15.39 day orbital periods fall near periods of signals induced by stellar magnetic activity. The two signals might therefore interfere and lead to an inaccurate estimate of exoplanet mass. We present a method to mitigate these effects when radial velocity (RV) and activityindicator observations are available over multiple observing seasons and the orbital period of the exoplanet is known. We perform correlation and periodogram analyses on subsets composed of each target's two observing seasons, in addition to the full data sets. For both targets, these analyses reveal an optimal season with little to no interference at the orbital period of the known exoplanet. We make a confident mass detection of each exoplanet by confirming agreement between fits to the full RV set and the optimal season. For K2-79b, we measure a mass of 11.8 ± 3.6 M ⊕ and a radius of 4.09 ± 0.17 R ⊕ . For K2-222b, we measure a mass of 8.0 ± 1.8 M ⊕ and a radius of 2.35 ± 0.08 R ⊕ . According to model predictions, K2-79b is a highly irradiated Uranus analog and K2-222b hosts significant amounts of water ice. We also present a RV solution for a candidate second companion orbiting K2-222 at 147.5 days.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2021

C/2014 UN 271 (Bernardinelli-Bernstein): The Nearly Spherical Cow of Comets

Abstract Comet C/2014 UN 271 (Bernardinelli-Bernstein), incoming from the Oort cloud, is remarkable in having the brightest (and presumably largest) nucleus of any well-measured comet and having been discovered at the heliocentric distance r h ≈ 29 au, farther than any Oort cloud comet. In this work, we describe the discovery process and observations and the properties that can be inferred from images recorded until the first reports of activity in 2021 June. The orbit has i = 95°, with a perihelion of 10.97 au to be reached in 2031 and a previous aphelion at 40,400 ± 260 au. Backward integration of the orbit under a standard Galactic tidal model and known stellar encounters suggests a perihelion of q ≈ 18 au on its previous perihelion passage 3.5 Myr ago; hence, the current data could be the first ever obtained of a comet that has not been inside Uranus’s orbit in 4 Gyr. The photometric data show an unresolved nucleus with absolute magnitude H r = 8.0, colors that are typical of comet nuclei or Damocloids, and no secular trend as it traversed the range 34–23 au. For the r -band geometric albedo p r , this implies a diameter of 150 ( p r / 0.04 ) − 0.5 km. There is strong evidence of brightness fluctuations at the ±0.2 mag level, but no rotation period can be discerned. A coma, nominally consistent with a “stationary” 1/ ρ surface brightness distribution, grew in scattering cross section at an exponential rate from A f ρ ≈ 1 to ≈150 m as the comet approached from 28 to 20 au. The activity rate is consistent with a very simple model of sublimation of a surface species in radiative equilibrium with the Sun. The inferred enthalpy of sublimation matches those of CO 2 and NH 3 . More volatile species, such as N 2 , CH 4 , and CO, must be far less abundant on the sublimating surfaces.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2020

Reveal of Uranium Bioremediation Mechanisms by Bacillus Species through Proteomics Studies

Radionuclides, such as Uranium (U) and heavy metals continue to pose threats to the ecosystem health and processes at the Department of Energy (DOE) managed, Savannah River Site (SRS), located along the Savannah River near Aiken, SC. Such co-contaminated environments are difficult to remediate using conventional excavation and disposal or pump-and-treat approaches. Globally, more than 109 tons of uranium contaminated areas pose a long term threat to human and ecological health. Even with presented low concentrations in the brain, central nervous effects are still observed. Uranium and depleted uranium (DU) have long term effects on the kidneys. Some small general health effects include severe headaches and breathing problems. Uranus ions are toxic to living cells because they inhibit metabolism of carbohydrates by blocking ATP binding sites. Bioremediation by microorganisms represents an alternative solution, which is advantageous because of the possibility of biosorbent regeneration, cost-effectiveness, increased metal removal and easy recovery of some valuable metals. Bacillus sp. bacterium was previously used in the bioremediation of heavy metals in coal mine run off waters of SRS. However, its ability to bioremediate uranium was unknown so far. Hence, in the present study, uranium bioremediation by Bacillus sp. bacterium was investigated. The mechanism of bioremediation was also revealed through proteomics studies. Heavy metals contamination poses a serious threat to water, soil and human health. Soil and water are contaminated due to excessive exploitation of uranium mines for generation of nuclear energy and weaponry. It is not degradable easily and persist in soil and water for a long period of time due to its long half- life. Savannah river site (SRS) is one of the uranium contaminated sites. The physical or chemical remediation techniques are costly and complex. Microbial system approaches with competent bacteria has received increased attention due to its adaptability in various environmental matrices and cost effectiveness. However, even though there are multiple suggested pathways (F1), the specific mechanisms that drive this behavior are still unclear, especially with popular microorganisms such as Bacillus species. In a previous research (Ibeanusi et al, 2003) Bacillus sp. was shown to detoxify and precipitate a variety of heavy metals in coal pile runoff waters of SRS site. Additionally, genomic analysis demonstrated that this microorganism posses multiple attributes for chemical transport regulation and metabolic pathways. U remediation occurs during the first 20 hours of exposure. During this time period, Bacillus sp. may work primarily under two mechanisms - sorption and accumulation. These two mechanisms simultaneously work to protect the microorganism from high concentrations. Figure 10 demonstrates that certain proteins are up regulated and down regulated under extreme stressful conditions. Membrane fraction proteins were up regulated. Cytosolic fraction proteins were down regulated. This protein information coincides with the adsorption behavior. Bacillus sp. is a good candidate for U remediation at various concentrations.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗