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Low-Temperature Rate Coefficients of C2H with CH4 and CD4 from 154 to 359 K

Rate coefficients for the reaction C2H + CH4 yields C2H2 + CH3 and C2H + CD4 yields C2HD + CD3 are measured over the temperature range 154-359 K using transient infrared laser absorption spectroscopy. Ethynyl radicals are produced by pulsed laser photolysis of C2H2 in a variable temperature flow cell, and a tunable color center laser probes the transient removal of C2H (Chi(exp 2) Sigma(+) (0,0,0)) in absorption. The rate coefficients for the reactions of C2H with CH4 and CD4 both show a positive temperature dependence over the range 154-359 K, which can be expressed as k(sub CH4) = (1.2 +/- 0.1) x 10(exp -11) exp((-491 +/- 12)/T) and k(sub CD4) = (8.7 +/- 1.8) x 10(exp -12) exp((-650 +/- 61)/T) cm(exp 3) molecule(exp -1) s(exp -1), respectively. The reaction of C2H + CH4 exhibits a significant kinetic isotope effect at 300 K of k(sub CH4)/k(sub CD4) = 2.5 +/- 0.2. Temperature dependent rate constants for C2H + C2H2 were also remeasured over an increased temperature range from 143 to 359 K and found to show a slight negative temperature dependence, which can be expressed as k(sub C2H2) = 8.6 x 10(exp -16) T(exp 1.8) exp((474 +/- 90)/T) cm(exp 3) molecule(exp -1) s(exp -1).

Opansky, Brian J.↗

The transient performance of a two-phase fluid reservoir

Thermal control of future large, high power spacecraft will require a two-phase fluid central bus. The two-phase fluid reservoir is a critical component in the two-phase fluid bus. It both controls the saturation temperature and provides a space for volumetric changes. A dynamic reservoir simulation model does not currently exist, but it is needed to expedite efforts and reduce risk. During 1989 an effort was made to develop a simulation model of the transient performance of a two-phase fluid reservoir. As a beginning, a preliminary model was developed. It is based upon component mathematical models in lumped parametric form and build upon five component mathematical models for calculating dynamic responses of two-phase fluid reservoirs, primary feedback elements, controller commands, heater actuators, and reservoir heaters. As much as possible, the model took advantage of the available SINDA'85/FLUINT thermal/fluid integrator. Additional calculation logic and computer subroutines were developed to complete implementation of the model. The model is capable of simulating dynamic response of an equilibrium two-phase fluid reservoir. Modification of the model to include the liquid/vapor nonequilibrium is required for applications of the model to simulate performance of reservoir in which the liquid and vapor phases of the reservoir fluid are not in equilibrium. In addition, the model in its present form, needs to be refined in several respects. More empirical data are needed to guide the model development. The model may then be used to conduct a full parametric study of two-phase fluid reservoirs. More complexities in two-phaes flow regions in laboratory and flight conditions may have to be considered eventually if empirical data cannot be simulated satisfactorily. System with other components arrangement also need to be simulated if optimization is ever to be attained. The present model does, however, preliminarily demonstrates that such analyses are quite possible and offers a far less expensive method to understand the transient of a two-phase fluid reservoir system than a totally headware approach.

Chi, Joseph↗

Rate Coefficients of C2H with C2H4, C2H6, and H2 from 150 to 359 K

Rate coefficients for the reactions C2H with C2H4, C2H6, and H2 are measured over the temperature range 150-359 K using transient infrared laser absorption spectroscopy. The ethynyl radical is formed by photolysis of C2H2 with a pulsed excimer laser at 193 nm, and its transient absorption is monitored with a color center laser on the Q(sub 11)(9) line of the A(sup 2) Pi-Chi(sup 2) Sigma transition at 3593.68 cm(exp -1). Over the experimental temperature range 150-359 K the rate constants of C2H with C2H4, C2H6, and H2 can be fitted to the Arrhenius expressions k(sub C2H4) = (7.8 +/- 0.6) x 10(exp -11) exp[(134 +/- 44)/T], k(sub C2H6) = (3.5 +/- 0.3) x 10(exp -11) exp[(2.9 +/- 16)/T], and k(sub H2) = (1.2 +/- 0.3) x 10(exp -11) exp[(-998 +/- 57)]/T cm(exp 3) molecule(exp -1) sec(exp -1). The data for C2H with C2H4 and C2H6 indicate a negligible activation energy to product formation shown by the mild negative temperature dependence of both reactions. When the H2 data are plotted together with the most recent high-temperature results from 295 to 854 K, a slight curvature is observed. The H2 data can be fit to the non-Arrhenius form k(sub H2) = 9.2 x 10(exp -18) T(sup 2.17 +/- 0.50) exp[(-478 +/- 165)/T] cm(exp 3) molecules(exp -1) sec(exp -1). The curvature in the Arrhenius plot is discussed in terms of both quantum mechanical tunneling of the H atom from H2 to the C2H radical and bending mode contributions to the partition function.

Opansky, Brian J.↗

The ROSAT variable sky

The spectral and timing characteristics from a sample, of 91 objects, of the variable sources obtained using the Kolmogorov-Smirnov test technique are presented. The data were extracted from the catalog constructed by White, Giommi and Angelini, the WGACAT, based on the pointed observations from the Rosat missions. The application of the test revealed more than 2400 individual variable candidates, with 'sq chi' greater than 12. The sample of these variable sources, mostly unidentified, probably contains many flare stars, a few cataclysmic variables and a possible transient source.

Angelini, L.↗

An EXOSAT detection of the transient X-ray pulsar GRO J1008-57

The hard X-ray transient, GRO J1008-57, was discovered during a bright outburst in 1993 July by the Burst and Transient Source Experiment (BATSE) instrument on board the Compton Gamme-Ray Observatory (CGRO). There are no published reports of previous emission from this 93.6 sec X-ray pulsar. Recent optical results have suggested a Be star as the companion. A search of the EXOSAT archives shows that an ME observation centered on the star HD 88661 includes GRO J1008-57 within the field of view. The characteristics of the medium-energy detection including a hard spectrum and pulsed emission at 91.36 sec (with chance probability of 3 x 10(exp -4)) indicates that EXOSAT detected GRO J1008-57 rather than the field star. The estimated flux is 2.4 x 10(exp -11) ergs/cm sq/sec for a luminosity of 1.1 x 10(exp 34) (D/2 kpc)(exp 2) ergs/sec. The X-ray spectrum is hard (photon index approximately equals 1.2) and highly absorbed (N(sub H) approximately equals 0.7 x 10(exp 22)). The detection of this transient suggests that there is a pulse shape dependence on luminosity, a spectral shape independent of luminosity, a large period derivative of P-dot/P = 2.3 x 10(exp -3)/yr, and a dynamic range of at least 100 in L(sub chi). We discuss GRO J1008-57 data in the context of wind-accretion models for this new member of the Be class of X-ray binaries.

Macomb, D. J.↗

Three-dimensional simulations of wintertime ozone variability in the lower stratosphere

The evolution of ozone has been calculated for the winters of 1979 and 1989 using winds derived from the stratospheric data assimilation system STRATAN. The ozone fields calculated using this technique are found to compare well with satellite-measured fields for simulations of 2-3 months. This paper presents comparisons of model fields with both satellite and sonde measurements to verify that stratospheric transport processes are properly represented by this modeling technique. Attention is focused on the Northern Hemisphere middle and high latitudes at the 10-hPa level and below, where transport processes are most important to the ozone distribution. First-order quantities and derived budgets from both the model and satellite data are presented. By sampling the model with a limb-viewing satellite and then Kalman filtering the 'observations' of the model, it is shown that transient subplanetary-scale features that are essential to the ozone budget are missed by the satellite system.

Rood, Richard B.↗

Serendipitous Detections of XTE J1906+09 with the Rossi X-Ray Timing Explorer

The 89 s X-ray pulsar XTE J1906+09 was discovered during Rossi X-Ray Timing Explorer (RXTE) observations of SGR 1900+14 in 1996. Because of monitoring campaigns of SGR 1900+14, XTE J1906+09 was also monitored regularly in 1996 September, 1998 May-June, 1998 August-1999 July, and 2000 March-2001 January. A search for pulsations resulted in detections of only the two previously reported outbursts in 1996 September and 1998 August-September. Pulsed flux upper limits for the rest of the observations show that XTE J1906+09 is a transient X-ray pulsar and likely has a Be star companion. The RXTE all-sky monitor did not reveal XTE J1906+09. Pulse-timing analysis of the second outburst discovered a sinusoidal signature in the pulse frequencies that is likely produced by an orbital periastron passage. Fits to pulse phases using an orbital model and quadratic phase model have chi(exp 2) minima at orbital periods of 26-30 days for fixed mass functions of 5, 10, 15, and 20 solar masses. The pulse shape showed energy- and intensity-dependent variations. Pulse-phase spectroscopy quantified the energy-dependent variations. The phase-averaged spectrum used the pulse minimum spectrum as the background spectrum to eliminate effects from SGR 1900+14 and the Galactic ridge and was well fitted by an absorbed power law with a high-energy cutoff with column density N(sub H) = 6 +/- 1 x 10(exp 22)/sq cm, a photon index of 1.01 +/- 0.08, cutoff energy E(sub cut) = 11 +/- 1 keV, and e-folding energy E(sub fold) = 19 +/- 4 keV. Estimated 2-10 keV peak fluxes, corrected for contributions from the Galactic ridge and SGR 1900+14, are 6 x l0(exp -12) and 1.1 x 10(exp -10) ergs/sq cm/s for the 1996 and 1998 outbursts, respectively. XTE J1906+09 may be part of an unusual class of Be/X-ray binaries that do not lie on the general spin period versus orbital period correlation with the majority of Be/X-ray binaries.

Wilson, Colleen A.↗

On the VHF Source Retrieval Errors Associated with Lightning Mapping Arrays (LMAs)

This presentation examines in detail the standard retrieval method: that of retrieving the (x, y, z, t) parameters of a lightning VHF point source from multiple ground-based Lightning Mapping Array (LMA) time-of-arrival (TOA) observations. The solution is found by minimizing a chi-squared function via the Levenberg-Marquardt algorithm. The associated forward problem is examined to illustrate the importance of signal-to-noise ratio (SNR). Monte Carlo simulated retrievals are used to assess the benefits of changing various LMA network properties. A generalized retrieval method is also introduced that, in addition to TOA data, uses LMA electric field amplitude measurements to retrieve a transient VHF dipole moment source.

inversion↗

ASDA - Advanced Suit Design Analyzer computer program

An ASDA model developed to evaluate the heat and mass transfer characteristics of advanced pressurized suit design concepts for low pressure or vacuum planetary applications is presented. The model is based on a generalized 3-layer suit that uses the Systems Integrated Numerical Differencing Analyzer '85 in conjunction with a 41-node FORTRAN routine. The latter simulates the transient heat transfer and respiratory processes of a human body in a suited environment. The user options for the suit encompass a liquid cooled garment, a removable jacket, a CO2/H2O permeable layer, and a phase change layer.

Bue, Grant C.↗

Turbulent boundary layer in an adverse pressure gradient without effect of wall curvature

The hypersonic compressible turbulent boundary layer in an adverse pressure gradient along a cylindrical axisymmetric body was studied. The tests were conducted in a Mach 6 contoured axisymmetric nozzle. An external compression cowl was used to produce the gradual adverse pressure gradient and a maximum pressure rise of 7 times the freestream static pressure was achieved in a test region of 23 cm. Boundary layer profiles of static pressure, total pressure, and total temperature, as well as wall transient heat transfer rates were measured. Comparisons of the velocity total temperature profiles to linear and quadratic relations were made. Measured heat transfer data were in good agreement with the prediction from the flat-plate reference enthalpy method. Integral parameters were also in good agreement with results of numerical solutions for compressible turbulent boundary layer equations.

Zakkay, V.↗

Inferring the spatial and energy distribution of gamma-ray burst sources. 1: Methodology

We describe Bayesian methods for analyzing the distribution of gamma-ray burst peak photon fluxes and directions. These methods fit the differential distribution, and have the following advantages over rival methods: (1) they do not destroy information by binning or averaging the data (as do, say, chi squared, the averaged value of V/V(sub max), and angular moment analyses); (2) they straightforwardly handle uncertainties in the measured quantities; (3) they analyze the strength and direction information jointly; (4) they use information available about nondetections; and (5) they automatically identify and account for biases and selection effects given a precise description of the experiment. In these methods, the most important information needed about the instrument threshold is not its value at the times of burst triggers, as is used in the average value of V/V(sub max) analyses, but rather the value of the threshold at times when no trigger occurred. We show that this information can be summarized as an average detection efficiency that is similar to the product of the exposure and efficiency reported in the First Burst and Transient Source Experiment (BATSE) Burst (1B) Catalog, but significantly different from it at low fluxes. We also quantify an important bias that results from estimating the peak flux by scanning the burst to find the peak number of counts in a window of specified duration, as was done for the 1B Catalog. When the duration of the peak of the light curve is longer than the window duration, a simple flux estimate based on the peak counts significantly overestimates the peak flux in a nonlinear fashion that distorts the shape of the log(N)-log(P) distribution. This distortion also corrupts analyses of the V/V(sub max) distribution that use ratios of counts above background to estimate V/V(sub max). The Bayesian calculation specifies how to account for this bias. Implementation of the Bayesian approach requires some changes in the way burst data are reported that we describe in detail. Subsequent papers will report analyses of the 1B Catalog data using the methods described here.

Loredo, Thomas J.↗

Origin of coronal mass ejection and magnetic cloud: Thermal or magnetic driven?

A fundamental problem in Solar-Terrestrial Physics is the origin of the solar transient plasma output, which includes the coronal mass ejection and its interplanetary manifestation, e.g. the magnetic cloud. The traditional blast wave model resulted from solar thermal pressure impulse has faced with challenge during recent years. In the MHD numerical simulation study of CME, the authors find that the basic feature of the asymmetrical event on 18 August 1980 can be reproduced neither by a thermal pressure nor by a speed increment. Also, the thermal pressure model fails in simulating the interplanetary structure with low thermal pressure and strong magnetic field strength, representative of a typical magnetic cloud. Instead, the numerical simulation results are in favor of the magnetic field expansion as the likely mechanism for both the asymmetrical CME event and magnetic cloud.

Zhang, Gong-Liang↗

Efficient parametric analysis of performance measures for communication networks

Efficient techniques for estimating performance measures in communication networks in a steady-state or transient setting are developed. These techniques may be used in a simulation environment or in connection with real-time observations. For Markov chain models, the recently proposed standard clock approach is extended, and a class of real-time algorithms for simultaneously generating multiple sample paths under different parameter sets is presented. Attention is focused on the link crash time estimation problem, where a 'crash' is defined as the first time a buffer overflows, given some initial conditions. An algorithm for estimating crash times under various traffic shocks is derived, where all estimates are obtained in parallel to an actual network's normal operation. An algorithm for crash time estimation of a G/D/1 link model is also derived using a different (perturbation-analysis-based) approach. Finally, extensive simulation results are provided to validate the proposed algorithms and compare them to brute-force simulation.

Cassandras, Christos G.↗

Propagation of Interplanetary Disturbances in the Outer Heliosphere

Contents include the following: 1. We have developed a one-dimensional, spherically symmetric, multi-fluid MHD model that includes solar wind protons and electrons, pickup ions, and interstellar neutral hydrogen. This model advances the existing solar wind models for the outer heliosphere in two important ways: one is that it distinguishes solar wind protons from pickup ions, and the other is that it allows for energy transfer from pickup ions to the solar wind protons. Model results compare favorably with the Voyager 2 observations. 2. 2. Solar wind slowdown and interstellar neutral density. The solar wind in the outer heliosphere is fundamentally different from that in the inner heliosphere since the effects of interstellar neutrals become significant. 3. ICME propagation from the inner to outer heliosphere. Large coronal mass ejections (CMEs) have major effects on the structure of the solar wind and the heliosphere. The plasma and magnetic field can be compressed ahead of interplanetary CMEs. 4. During the current solar cycle (Cycle 23), several major CMEs associated with solar flares produced large transient shocks which were observed by widely-separated spacecraft such as Wind at Earth and Voyager 2 beyond 60 AU. Using data from these spacecraft, we use the multi-fluid model to investigate shock propagation and interaction in the heliosphere. Specifically, we studied the Bastille Day 2000, April 2001 and Halloween 2003 events. 5. Statistical properties of the solar wind in the outer heliosphere. In a collaboration with L.F. Burlaga of GSFC, it is shown that the basic statistical properties of the solar wind in the outer heliosphere can be well produced by our model. We studied the large-scale heliospheric magnetic field strength fluctuations as a function of distance from the Sun during the declining phase of a solar cycle, using our numerical model with observations made at 1 AU during 1995 as input. 6. Radial heliospheric magnetic field events. The heliospheric magnetic field (HMF) direction, on average, conforms well to the Parker spiral.

Wang, Chi↗

Flashback Arrestor for LPP, Low NOx Combustors

Lean premixed, prevaporized (LPP) high temperature combustor designs as explored for the Advanced Subsonic Transport (AST) and High Speed Civil Transport (HSCT) combustors can achieve low NO(x), emission levels. An enabling device is needed to arrest flashback and inhibit preignition at high power conditions and during transients (surge and rapid spool down). A novel flashback arrestor design has demonstrated the ability to arrest flashback and inhibit preignition in a 4.6 cm diameter tubular reactor at full power inlet temperatures (725 C) using Jet-A fuel at 0.4 less than or equal To phi less than or equal to 3.5. Several low pressure loss (0.2 to 0.4% at 30 m/s) flashback arrestor designs were developed which arrested flashback at all of the test conditions. Flame holding was also inhibited off the flash arrestor face or within the downstream tube even velocities (less than or equal to 3 to 6 m/s), thus protecting the flashback arrestor and combustor components. Upstream flow conditions influence the specific configuration based on using either a 45% or 76% upstream geometric blockage. Stationary, lean premixed dry low NO(x) gas turbine combustors would also benefit from this low pressure drop flashback arrestor design which can be easily integrated into new and existing designs.

Kraemer, Gil↗