SEARCH · Engineering Papers

Results for “trace gas concentration”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

SourceResearch connectionFrom yearThrough year

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 19 records

All sources NASA NTRS DOE OSTI

NASA NTRS2002

Applications of Kalman filtering to real-time trace gas concentration measurements

A Kalman filtering technique is applied to the simultaneous detection of NH3 and CO2 with a diode-laser-based sensor operating at 1.53 micrometers. This technique is developed for improving the sensitivity and precision of trace gas concentration levels based on direct overtone laser absorption spectroscopy in the presence of various sensor noise sources. Filter performance is demonstrated to be adaptive to real-time noise and data statistics. Additionally, filter operation is successfully performed with dynamic ranges differing by three orders of magnitude. Details of Kalman filter theory applied to the acquired spectroscopic data are discussed. The effectiveness of this technique is evaluated by performing NH3 and CO2 concentration measurements and utilizing it to monitor varying ammonia and carbon dioxide levels in a bioreactor for water reprocessing, located at the NASA-Johnson Space Center. Results indicate a sensitivity enhancement of six times, in terms of improved minimum detectable absorption by the gas sensor.

Non-NASA Center↗

NASA NTRS1987

The potential impact on atmospheric ozone and temperature of increasing trace gas concentrations

The response of the atmosphere to emission of chlorofluorocarbons and other chlorocarbons and to increasing concentrations of other radiatively active trace gases is calculated using a coupled, one-dimensional, time-dependent chemical-radiative-transport model. The model predicts future changes in the ozone content and in the temperature based on several possible time-dependent scenarios of future atmospheric emissions. The sensitivity of the atmospheric responses to the values adopted for parameters such as the eddy diffusion coefficient for vertical transport and the atmospheric budget of nitrogen oxides is estimated and discussed.

Brasseur, Guy↗

NASA NTRS1987

The potential impact on atmospheric ozone and temperature of increasing trace gas concentrations

The response of the atmosphere to emissions of chlorofluorocarbons (CFCs) and other chlorocarbons, and to increasing concentrations of other radiatively active trace gases such as CO2, CH4, and N2O is calculated by a coupled chemical-radiative transport one-dimensional model. It is shown that significant reductions in the ozone concentration and in the temperature are expected in the upper stratosphere as a result of increasing concentrations of active chlorine produced by photodecomposition of the CFCs. The ozone content is expected to increase in the troposphere, as a consequence of increasing concentrations of methane and nitrogen oxides. Due to enhanced greenhouse effects, the Earth's surface should warm up by several degrees. The amplitude and even the sign of future changes in the ozone column are difficult to predict as they are strongly scenario-dependent. An early detection system to prevent noticeable ozone changes as a result of increasing concentrations of source gases should thus be based on a continuous monitoring of the ozone amount in the upper stratosphere rather than on measurements of the ozone column only. Measurements of NOx, Clx, and HOx are also required for unambiguous trend detection and interpretation.

Brasseur, G.↗

NASA NTRS1974

Effect of aerosol emission on the inference of trace gas concentrations from limb radiance data

This note reports on an analysis of atmospheric emission spectra in the 10-12 micron region measured with a limb-oriented balloon-borne spectrometer. Data clearly show the existence of an additional feature at 10.8 microns which is probably due to measurement contamination from aerosols. The 10.8 micron emitter has a strong reducing effect on the HNO3 mixing ratio profile as determined by application of a symmetrical band shape model to the 10.8 spectral feature.

Remsberg, E. E.↗

NASA NTRS1977

Inversion of infrared limb emission measurements for temperature and trace gas concentrations

Limb emission measurements are characterized by sharp weighting functions at high altitudes, and for temperature determinations, strongly nonlinear dependence of the weighting function on the temperature. Several methods for inverting this type of measurement have been described and used, including iterative, statistical, nonlinear and approximate direct approaches. These approaches are described and advantages and disadvantages of each are outlined.

Gille, J. C.↗

NASA NTRS1979

Trace gas concentrations, intertropical convergence, atmospheric fronts, and ocean currents in the tropical Pacific

Descriptions of the intertropical convergence zones (ITCZ) in the tropical Pacific have been obtained from shipboard measurements of Rn-222, CO, and CH4 in combination with conventional meteorological data and satellite images. The intertropical convergence zone is marked by light shifting waves near an area of heavy cloud cover and precipitation, and appears to be located north and south of the south equatorial current. A 'second' ITCZ with the same atmospheric features was encountered just north of the south equatorial current in the Southern Hemisphere. Atmospheric Rn-222 increases north of the ITCZ and serves as a sensitive indicator for this atmospheric boundary.

Wilkniss, P. E.↗

NASA NTRS1986

Quality indicators for trace gas concentrations determined from earthlimb emission spectra

Different techniques which can be used to indicate the quality of the mixing ratios retrieved from spectral radiance measurements made by the CLAES instrument for 11 different atmospheric gases are discussed. A key to retrieval from noisy data is the Singular Value Decomposition (SVD), which is described. The use of the SVD with simulated data and radiance measurements from a balloon floating at 30 km is discussed.

Uplinger, W. G.↗

NASA NTRSDate not supplied

Variations in radiative heating of humid biomass burning aerosols in the southeast Atlantic from airborne observations and reanalysis

The atmosphere over the southeast Atlantic Ocean (SEA) experiences consistent springtime biomass burning (BB) smoke from widespread agricultural fires on the African continent. This smoke layer is initially lofted high in a continental mixed layer (~5-6km) and is then transported westward into the free troposphere where it overlies and ultimately mixes into a stratocumulus-topped oceanic boundary layer. Coincident with this smoke is an elevated humidity signal which is present from the time a given airmass is over the continental source region. ORACLES (ObseRvations of Aerosols above CLouds and their intEractionS) was a NASA Earth Venture Suborbital mission with the goal of measuring aerosol, cloud, and atmospheric properties over this region over three deployments in September 2016, August 2017, and October 2018. Measurements included in situ profile measurements of aerosol physical and optical properties, trace gas concentrations, and cloud properties, as well as column measurements of aerosol optical depth and trace gas concentrations from an airborne sun photometer. Here we present results from each of the ORACLES deployments over the southeast Atlantic Ocean. Despite the differing locations and season of each deployment, we show that there is good agreement between the airborne ORACLES dataset and large-scale reanalyses, specifically the ECMWF ERA5 reanalyses (and, to a degree, the CAMS product) as compared to other available products. This agreement allows us to examine multi-year seasonal patterns and trends beyond the three months with available aircraft data. In both the data and reanalysis, we find distinct variations between each deployment in terms of vertical smoke distribution and correlation to atmospheric specific humidity, due to changing conditions over the BB season. We trace the origin and the history of these smoky airmasses and finally, we briefly discuss the broader radiative and dynamical implications of these results for conditions of aerosols overlying stratocumulus clouds.

K. Pistone↗

NASA NTRSDate not supplied

Variation and evolution of atmospheric structure over the SEA BB season as seen from aircraft and reanalysis

The presence of absorbing aerosols and atmospheric water vapor will impact clouds both radiatively and dynamically. The atmosphere over the southeast Atlantic Ocean (SEA) experiences consistent springtime biomass burning (BB) smoke from widespread agricultural fires on the African continent. This smoke layer is initially lofted high in a continental mixed layer (~5-6km) and is then transported westward into the free troposphere where it overlies and ultimately mixes into the underlying stratocumulus-topped oceanic boundary layer. Coincident with this smoke is an elevated humidity signal which is present from the time a given airmass is over the continental source region. ORACLES (ObseRvations of Aerosols above CLouds and their intEractionS) was a NASA Earth Venture Suborbital mission with the goal of measuring aerosol, cloud, and atmospheric properties over this region over three deployments in September 2016, August 2017, and October 2018. Measurements included in situ profile measurements of aerosol physical and optical properties, trace gas concentrations, and cloud properties, as well as column measurements of aerosol optical depth and trace gas concentrations from an airborne sun photometer, allowing for calculation of radiative heating at different altitudes. Here we present results from the three ORACLES deployments over the southeast Atlantic Ocean. The airborne observations capture both seasonal patterns (August through October) and spatial patterns (north/south and east/west) in the vertical smoke distribution and its correlation to atmospheric specific humidity over the SEA basin. We describe the observed variations and show that the variability in both meteorological and emissions is largely captured in the European Centre for Medium-range Weather Forecasting Copernicus Atmosphere Monitoring Service (ECMWF CAMS) reanalysis, which allows for a more systematic examination of the relative frequency of observed conditions and their radiative impact over the region. Finally, we discuss the broader radiative and dynamical implications of these results for conditions of biomass burning aerosols overlying stratocumulus clouds.

Kristina Marie Myers Pistone↗

NASA NTRS1988

Trace gas exchanges and convective transports over the Amazonian rain forest

The NASA Amazon Boundary Layer Experiment (ABLE 2A) based in Manaus, Brazil, in July and August 1985, is used to examine meteorological processes responsible for the vertical and horizontal transport of biogenic and anthropogenic trace gases generated over the Amazon basin. Direct sampling of the surrounding environment of deep convective clouds shows marked changes in the vertical distribution of the lower and midtroposphere concentration of O3 and such surface-derived species as CO, CO2, and NO. Thermodynamic observations, together with two-dimensional cloud model simulations, confirm vertical transports within the convection and provide a basis for an estimation of the magnitude and efficiency of cloud upward and downward exchanges. A distinction is drawn between local changes due to convective updrafts and downdrafts and convective overturning as a net result of the storm processes. Marked variability is seen in trace gas concentrations along horizontal flight paths in the vicinity of the convection. Interpretation of simultaneously measured thermodynamic quantities and trace gas concentrations provide the information to infer the presence and direction of atmospheric transports and/or the presence of anthropogenic influences.

Garstang, Michael↗

NASA NTRS1983

Axial compressor middle stage secondary flow study

This report describes an experimental investigation of the secondary flow within and aft of an axial compressor model with thick endwall boundary layers. The objective of the study was to obtain detailed aerodynamic and trace gas concentration traverse data aft of a well documented isolated rotor for the ultimate purpose of improving the design phases of compressor development based on an improved physical understanding of secondary flow. It was determined from the flow visualization, aerodynamic, and trace gas concentration results that the relative unloading of the midspan region of the airfoil inhibitied a fullspan separation at high loading preventing the massive radial displacement of the hub corner stall to the tip. Radial distribution of high and low total pressure fluid influenced the magnitude of the spanwise distribution of loss, such that, there was a general decreases in loss near the hub to the extent that for the least loaded case a negative loss (increase in total pressure) was observed. The ability to determine the spanwise distribution of blockage was demonstrated. Large blockage was present in the endwall regions due to the corner stall and tip leakage with little blockage in the core flow region. Hub blockage was found to increase rapidly with loading.

Wagner, J. H.↗

NASA NTRS2012

Satellite Contributions to the Quantitative Characterization of Biomass Burning for Climate Modeling

Characterization of biomass burning from space has been the subject of an extensive body of literature published over the last few decades. Given the importance of this topic, we review how satellite observations contribute toward improving the representation of biomass burning quantitatively in climate and air-quality modeling and assessment. Satellite observations related to biomass burning may be classified into five broad categories: (i) active fire location and energy release, (ii) burned areas and burn severity, (iii) smoke plume physical disposition, (iv) aerosol distribution and particle properties, and (v) trace gas concentrations. Each of these categories involves multiple parameters used in characterizing specific aspects of the biomass-burning phenomenon. Some of the parameters are merely qualitative, whereas others are quantitative, although all are essential for improving the scientific understanding of the overall distribution (both spatial and temporal) and impacts of biomass burning. Some of the qualitative satellite datasets, such as fire locations, aerosol index, and gas estimates have fairly long-term records. They date back as far as the 1970s, following the launches of the DMSP, Landsat, NOAA, and Nimbus series of earth observation satellites. Although there were additional satellite launches in the 1980s and 1990s, space-based retrieval of quantitative biomass burning data products began in earnest following the launch of Terra in December 1999. Starting in 2000, fire radiative power, aerosol optical thickness and particle properties over land, smoke plume injection height and profile, and essential trace gas concentrations at improved resolutions became available. The 2000s also saw a large list of other new satellite launches, including Aqua, Aura, Envisat, Parasol, and CALIPSO, carrying a host of sophisticated instruments providing high quality measurements of parameters related to biomass burning and other phenomena. These improved data products have enabled significant progress in the study of biomass burning from space. However, appreciable uncertainty remains in many of the measurements that still needs to be addressed. Nevertheless, climate and other atmospheric models are

Ichoku, Charles↗

NASA NTRS1982

CO2 lidar for measurements of trace gases and wind velocities

CO2 lidar systems technology and signal processing requirements relevant to measurement needs and sensitivity are discussed. Doppler processing is similar to microwave radar, with signal reception controlled by a computer capable of both direct and heterodyne operations. Trace gas concentrations have been obtained with the NASA DIAL system, and trace gas transport has been determined with Doppler lidar measurements for wind velocity and turbulence. High vertical resolution measurement of trace gases, wind velocity, and turbulence are most important in the planetary boundary layer and in regions between the PBL and the lower stratosphere. Shear measurements are critical for airport operational safety. A sensitivity analysis for heterodyne detection with the DIAL system and for short pulses using a Doppler lidar system is presented. The development of transient injection locking techniques, as well as frequency stability by reducing chirp and catalytic control of closed cycle CO2 laser chemistry, is described.

Hess, R. V.↗

NASA NTRS2014

Up in the Air: Methane and Ozone over California

The Alpha Jet Atmospheric eXperiment (AJAX) at NASA Ames Research Center measures in-situ carbon dioxide, methane, and ozone concentrations in the Earth's atmosphere several times each month. The AJAX team studies local photochemical smog production, provides data for long-term studies of trans-Pacific transport of pollution, and supports the observation of greenhouse gases from satellites. The aircraft is stationed at Moffett Field and is outfitted with scientific instruments to measure trace gas concentrations and 3-D wind speeds. Vertical profiles from near the surface up to approximately 27,000 ft are routinely collected over locations such as: Merced, Edwards Air Force Base, Railroad Valley, NV, and over the Pacific Ocean. In addition, boundary layer measurements scout for surface sources such as fires, oil gas infrastructure, livestock, and urban pollution. This talk will focus on recent observations over dairy operations, fossil fuel infrastructure, and wildfires.

Trace Gas Concentrations↗

NASA NTRS1982

A theoretical investigation of gaseous absorption by water droplets from SO2-HNO3-NH3-CO2-HCl mixtures

A physical-chemical model is developed and used to investigate gaseous absorption by water droplets from trace gas mixtures. The model is an extension of that of Carmichael and Peters (1979) and includes the simultaneous absorption of SO2, NH3, HNO3, CO2, and HCl. Gas phase depletion is also considered. Presented results demonstrate that the absorption behavior of raindrops is strongly dependent on drop size, fall distance, trace gas concentrations, and the chemical and physical properties of the constituents of the mixture. In addition, when gas phase depletion is considered, the absorption rates and equilibrium values are also dependent on the precipitation rate itself. Also, the trace constituents liquid phase concentrations may be a factor of six or more lower when gas depletion is considered then when the depletion is ignored. However, the hydrogen ion concentration may be insensitive to the gas phase depletion.

Adewuyi, Y. G.↗

NASA NTRS2000

Chance Encounter with a Stratospheric Kerosene Rocket Plume From Russia Over California

A high-altitude aircraft flight on April 18, 1997 detected an enormous aerosol cloud at 20 km altitude near California (37 N). Not visually observed, the cloud had high concentrations of soot and sulfate aerosol, and was over 180 km in horizontal extent. The cloud was probably a large hydrocarbon fueled vehicle, most likely from rocket motors burning liquid oxygen and kerosene. One of two Russian Soyuz rockets could have produced the cloud: a launch from the Baikonur Cosmodrome, Kazakhstan on April 6; or from Plesetsk, Russia on April 9. Parcel trajectories and long-lived trace gas concentrations suggest the Baikonur launch as the cloud source. Cloud trajectories do not trace the Soyuz plume from Asia to North America, illustrating the uncertainties of point-to-point trajectories. This cloud encounter is the only stratospheric measurement of a hydrocarbon fuel powered rocket.

Newman, P. A.↗

NASA NTRS2011

Effect of Tropospheric Aerosols in Satellite-Based Trace Gas Retrieval

Scattering and absorption by tropospheric aerosol particles have an effect on the airmass factor (AMF), a fundamental quantity for trace gas concentration retrieval by inversion of satellite measurements. The interference effect depends on the aerosols micro-physical and optical properties as well as the relative distribution of the tropospheric trace gas and aerosol load. Quantifying the aerosol impact on trace gas retrieval requires a sensitivity study using radiative transfer calculations. In this presentation we will describe a recently initiated effort to characterize the aerosol-related error in trace gas retrievals when the presence of aerosol particles is not accounted in the inversion procedure. A general description of the project will be presented and preliminary results on aerosol effects on SO2 retrieved concentrations will be discussed.

Krotkov, Nickolay↗

NASA NTRS2000

BOREAS TGB-1 CH4 Concentration and Flux Data from NSA Tower Sites

The BOREAS TGB-1 team made numerous measurements of trace gas concentrations and fluxes at various NSA sites. This data set contains half-hourly averages of ambient methane (CH4) measurements and calculated fluxes for the NSA-Fen in 1996 and the NSA-BP and NSA-OJP tower sites in 1994. The purpose of this study was to determine the CH4 flux from the study area by measuring ambient CH 4 concentrations. This flux can then be compared to the chamber flux measurements taken at the same sites. The data are provided in tabular ASCII files.

Hall, Forrest G.↗