Models of the lunar surface including temperature-dependent thermal properties.
Temperature dependent thermal property models of lunar surface and radiative energy transport deduced from RF and IR observations
LUNAR SURFACE↗
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Temperature dependence of the HNO3 UV absorption cross sections
The temperature dependence of the HNO3 absorption cross sections between 240 and 360 K over the wavelength range 195 to 350 nm has been measured using a diode array spectrometer. Absorption cross sections were determined using both (1) absolute pressure measurements at 298 K and (2) a dual absorption cell arrangement in which the absorption spectrum at various temperatures is measured relative to the room temperature absorption spectrum. The HNO3 absorption spectrum showed a temperature dependence which is weak at short wavelengths but stronger at longer wavelengths which are important for photolysis in the lower stratosphere. The 298 K absorption cross sections were found to be larger than the values currently recommended for atmospheric modeling (DeMore et al., 1992). Our absorption cross section data are critically compared with the previous measurements of both room temperature and temperature-dependent absorption cross sections. Temperature-dependent absorption cross sections of HNO3 are recommended for use in atmospheric modeling. These temperature dependent HNO3 absorption cross sections were used in a two-dimensional dynamical-photochemical model to demonstrate the effects of the revised absorption cross sections on loss rate of HNO3 and the abundance of NO2 in the stratosphere.
Burkholder, James B.↗
Mantle plumes - A boundary layer approach for Newtonian and non-Newtonian temperature-dependent rheologies
Stress is placed on the temperature dependence of both a linear Newtonian rheology and a nonlinear olivine rheology in accounting for narrow mantle flow structures. The boundary-layer theory developed incorporates an arbitrary temperature-dependent power-law rheology for the medium, in order to facilitate the study of mantle plume dynamics under real conditions. Thermal, kinematic, and dynamic structures of mantle plumes are modelled by a two-dimensional natural-convection boundary layer rising in a fluid with a temperature-dependent power-law relationship between shear stress and strain rate. An analytic similarity solution is arrived at for upwelling adjacent to a vertical isothermal stress-free plane. Newtonian creep as a deformation mechanism, thermal anomalies resulting from chemical heterogeneity, the behavior of plumes in non-Newtonian (olivine) mantles, and differences in the dynamics of wet and dry olivine are discussed.
Yuen, D. A.↗
Temperature dependence of the ClONO2 UV absorption spectrum
The temperature dependence of the ClONO2 absorption spectrum has been measured between 220 and 298 K and between 195 and 430 nm using a diode array spectrometer. The absorption cross sections were determined using both: (1) absolute pressure measurements at 296 K and (2) measurements at various temperatures relative to 296 K using a dual absorption cell arrangement. The temperature dependence of the ClONO2 absorption spectrum shows very broad structure. The amplitude of the temperature dependence relative to that at 296 K is weak at short wavelengths, less than 2% at 215 nm and 220 K, but significant at the wavelengths important in the stratosphere, about 30% at 325 nm and 220 K. Our ClONO2 absorption cross section data are in good general agreement with the previous measurements of Molina and Molina (1979).
Burkholder, James B.↗
Assessment of Temperature-Dependent Regression Model Terms of a RUAG Six-Component Block-Type Balance
A metric called the percent contribution was applied to regression models of temperature-dependent calibration data of a RUAG six-component block-type balance in order to assess the influence of temperature-dependent regression model terms on the balance load prediction. Regression models were examined that are needed if either the Iterative or the Non-Iterative Method is used for the load prediction. Computed values of the percent contribution confirmed that the cross-product term defined by a primary load and the temperature difference is the most influential temperature-dependent term of the regression model of a primary output that the Iterative Method needs. Similarly, the analysis showed that the cross-product term defined by a primary output and the temperature difference is the most influential temperature-dependent term of the regression model of a primary load that the Non-Iterative Method needs. Computed results support conclusions that were reported in an earlier theoretical study. This study asserted that the cross-product term defined by a primary load or output and the temperature difference models the temperature-dependent shift of the gage sensitivity. The influence of other temperature-dependent terms used in the regression models of the calibration data of RUAG's balance was negligible. This observation may be explained by the fact that RUAG's block-type balances have highly linear characteristics. Overall, the percent contribution has proven itself to be a reliable and easy-to-implement metric that may also be used for the assessment of the influence of temperature-dependent regression model terms on the load prediction of a six-component strain-gage balance.
Ulbrich, N.↗
Assessing the Temperature Dependence of Narrow-Band Raman Water Vapor Lidar Measurements: A Practical Approach
Narrow-band detection of the Raman water vapor spectrum using the lidar technique introduces a concern over the temperature dependence of the Raman spectrum. Various groups have addressed this issue either by trying to minimize the temperature dependence to the point where it can be ignored or by correcting for whatever degree of temperature dependence exists. The traditional technique for performing either of these entails accurately measuring both the laser output wavelength and the water vapor spectral passband with combined uncertainty of approximately 0.01 nm. However, uncertainty in interference filter center wavelengths and laser output wavelengths can be this large or larger. These combined uncertainties translate into uncertainties in the magnitude of the temperature dependence of the Raman lidar water vapor measurement of 3% or more. We present here an alternate approach for accurately determining the temperature dependence of the Raman lidar water vapor measurement. This alternate approach entails acquiring sequential atmospheric profiles using the lidar while scanning the channel passband across portions of the Raman water vapor Q-branch. This scanning is accomplished either by tilt-tuning an interference filter or by scanning the output of a spectrometer. Through this process a peak in the transmitted intensity can be discerned in a manner that defines the spectral location of the channel passband with respect to the laser output wavelength to much higher accuracy than that achieved with standard laboratory techniques. Given the peak of the water vapor signal intensity curve, determined using the techniques described here, and an approximate knowledge of atmospheric temperature, the temperature dependence of a given Raman lidar profile can be determined with accuracy of 0.5% or better. A Mathematica notebook that demonstrates the calculations used here is available from the lead author.
Raman lidar↗
Application of a Temperature-Dependent Load Prediction Method to a RUAG Six-Component Block-Type Balance
Temperature-dependent data of a RUAG six-component block-type balance was analyzed to assess the accuracy of two load prediction methods for temperature-dependent balance data. The supplied data was prepared for the analysis by splitting it into calibration and check load data subsets. The first calibration data subset was obtained at a temperature of 294 Kelvin. The second calibration data subset was obtained at a temperature of 315 Kelvin. A subset of 38 points was extracted from the second data set and used as check loads so that the accuracy of the two load prediction methods could be tested. First, the Iterative Method in combination with an extended independent and dependent variable set was used for the balance load prediction. This approach fits electrical outputs as a function of loads and the temperature and, afterwards, constructs a load iteration scheme from the regression coefficients so that loads can be predicted from outputs and the temperature during a wind tunnel test. The Non-Iterative Method was also used for the load prediction. This alternate method can more easily be implemented in a data system as loads are directly fitted as a function of electrical outputs and the temperature. Analysis results for the axial force are only discussed in the paper as similar results were obtained for the other five load components. Results for both methods clearly show that the cross-product term constructed from either a primary gage load or a primary gage output and the temperature explains the majority of the temperature-dependent part of the predicted balance load. This term models the temperature dependent nature of the gage sensitivity. Therefore, it is recommended to apply primary gage loadings at different temperatures during a balance calibration whenever temperature effects need to be described. These loadings will contain information about the temperature-dependent nature of the gage sensitivities that can be quantified by related cross-product terms in regression models of the data.
strain-gage balance↗
Spectral Line Parameters Including Temperature Dependences of Self- and Air-Broadening in the 2 (left arrow) 0 Band of CO at 2.3 micrometers
Temperature dependences of pressure-broadened half-width and pressure-induced shift coefficients along with accurate positions and intensities have been determined for transitions in the 2<--0 band of C-12 O-16 from analyzing high-resolution and high signal-to-noise spectra recorded with two different Fourier transform spectrometers. A total of 28 spectra, 16 self-broadened and 12 air-broadened, recorded using high- purity (greater than or equal to 99.5% C-12-enriched) CO samples and CO diluted with dry air(research grade) at different temperatures and pressures, were analyzed simultaneously to maximize the accuracy of the retrieved parameters. The sample temperatures ranged from 150 to 298K and the total pressures varied between 5 and 700 Torr. A multispectrum nonlinear least squares spectrum fitting technique was used to adjust the rovibrational constants (G, B, D, etc.) and intensity parameters (including Herman-Wallis coefficients), rather than determining individual line positions and intensities. Self-and air-broadened Lorentz half-width coefficients, their temperature dependence exponents, self- and air-pressure-induced shift coefficients, their temperature dependences, self- and air-line mixing coefficients, their temperature dependences and speed dependence have been retrieved from the analysis. Speed-dependent line shapes with line mixing employing off-diagonal relaxation matrix element formalism were needed to minimize the fit residuals. This study presents a precise and complete set of spectral line parameters that consistently reproduce the spectrum of carbon monoxide over terrestrial atmospheric conditions.
Devi, V. Malathy↗
Temperature-Dependent Changes in the Normal Albedo of the Lunar Surface at 1064 nm
Over the extreme temperature variations experienced in a single lunar day (∆T≈300 K), particular minerals common to the lunar surface show spectral changes at near-infrared wavelengths in laboratory settings (Singer and Roush, 1985; Roush and Singer, 1986, 1987). Variations in temperature can cause variations in the size and shape of crystallographic sites, which control the position, shape, and depth of crystal field absorptions. At an observation wavelength of 1064 nm, the Lunar Orbiter Laser Altimeter (LOLA) should be highly sensitive to temperature-dependent changes of orthopyroxene. Here we analyze temperature-dependent spectral changes of the lunar surface as measured from orbit by LOLA. We couple LOLA measurements of normal albedo with measurements of surface temperature from the Diviner Lunar Radiometer Experiment, analyzing the maria and highlands terranes between ±50° in 1°x1° spatial bins. We provide the first evidence of temperature-dependent spectral changes on the lunar surface from orbital observations, finding that the majority of the lunar surface between 50°N and 50°S demonstrates a small, yet measurable, negative change in normal albedo at 1064 nm with temperature (-∆R/∆T). The measurable effect is on the order of a few percent change in reflectance per ~80 K, indicating temperature changes do not have a large effect on measurements of albedo at the sensitivity of the LOLA instrument. Stronger -∆R/∆T values tend to be associated with the maria, and regions with elevated orthopyroxene levels. Our results suggest that single-wavelength lasers may be powerful tools for understanding the distribution of particular minerals on the lunar surface.
Ariel N Deutsch↗
Effects of a temperature-dependent rheology on large scale continental extension
The effects of a temperature-dependent rheology on large-scale continental extension are investigated using a thin viscous sheet model. A vertically-averaged rheology is used that is consistent with laboratory experiments on power-law creep of olivine and that depends exponentially on temperature. Results of the calculations depend principally on two parameters: the Peclet number, which describes the relative rates of advection and diffusion of heat, and a dimensionless activation energy, which controls the temperature dependence of the rheology. At short times following the beginning of extension, deformation occurs with negligible change in temperature, so that only small changes in lithospheric strength occur due to attenuation of the lithosphere. However, after a certain critical time interval, thermal diffusion lowers temperatures in the lithosphere, strongly increasing lithospheric strength and slowing the rate of extension. This critical time depends principally on the Peclet number and is short compared with the thermal time constant of the lithosphere. The strength changes cause the locus of high extensional strain rates to shift with time from regions of high strain to regions of low strain. Results of the calculations are compared with observations from the Aegean, where maximum extensional strains are found in the south, near Crete, but maximum present-day strain rates are largest about 300 km further north.
Sonder, Leslie J.↗
Temperature dependence of elastic and strength properties of T300/5208 graphite-epoxy
Experimental results are presented for the elastic and strength properties of T300/5208 graphite-epoxy at room temperature, 116K (-250 F), and 394K (+250 F). Results are presented for unidirectional 0, 90, and 45 degree laminates, and + or - 30, + or - 45, and + or - 60 degree angle-ply laminates. The stress-strain behavior of the 0 and 90 degree laminates is essentially linear for all three temperatures and that the stress-strain behavior of all other laminates is linear at 116K. A second-order curve provides the best fit for the temperature is linear at 116K. A second-order curve provides the best fit for the temperature dependence of the elastic modulus of all laminates and for the principal shear modulus. Poisson's ratio appears to vary linearly with temperature. all moduli decrease with increasing temperature except for E (sub 1) which exhibits a small increase. The strength temperature dependence is also quadratic for all laminates except the 0 degree - laminate which exhibits linear temperature dependence. In many cases the temperature dependence of properties is nearly linear.
Milkovich, S. M.↗
Photodissociation in the atmosphere of Mars - Impact of high resolution, temperature-dependent CO2 cross-section measurements
We have investigated the impact of high resolution, temperature-dependent CO2 cross-section measurements, reported by Lewis and Carver (1983), on calculations of photodissociation rate coefficients in the Martian atmosphere. We find that the adoption of 50 A intervals for the purpose of computational efficiency results in errors in the calculated values for photodissociation of CO2, H2O, and O2 which are generally not above 10 percent, but as large as 20 percent in some instances. These are acceptably small errors, especially considering the uncertainties introduced by the large temperature dependence of the CO2 cross section. The inclusion of temperature-dependent CO2 cross sections is shown to lead to a decrease in the diurnally averaged rate of CO2 photodissociation as large as 33 percent at some altitudes, and increases of as much as 950 percent and 80 percent in the photodissociation rate coefficients of H2O and O2, respectively. The actual magnitude of the changes depends on the assumptions used to model the CO2 absorption spectrum at temperatures lower than the available measurements, and at wavelengths longward of 1970 A.
Anbar, A. D.↗
Effects of a temperature-dependent rheology on large-scale continental extension
The effects of a temperature-dependent rheology on large-scale continental extension are investigated using a thin viscous sheet model. A vertically-averaged rheology is used that is consistent with laboratory experiments on power-law creep of olivine and that depends exponentially on temperature. Results of the calculations depend principally on two parameters: the Peclet number, which describes the relative rates of advection and diffusion of heat, and a dimensionless activation energy, which controls the temperature dependence of the rheology. At short times following the beginning of extension, deformation occurs with negligible change in temperature, so that only small changes in lithospheric strength occur due to attenuation of the lithosphere. However, after a certain critical time interval, thermal diffusion lowers temperatures in the lithosphere, strongly increasing lithospheric strength and slowing the rate of extension. This critical time depends principally on the Peclet number and is short compared with the thermal time constant of the lithosphere. The strength changes cause the locus of high extensional strain rates to shift with time from regions of high strain to regions of low strain. Results of the calculations are compared with observations from the Aegean, where maximum extensional strains are found in the south, near Crete, but maximum present-day strain rates are largest about 300 km further north.
Sonder, Leslie J.↗
Investigation of temperature dependence of development and aging
Temperature dependence of maturation and metabolic rates in insects, and the failure of vital processes during development were investigated. The paper presented advances the general hypothesis that aging in biological systems is a consequence of the production of entropy concomitant with metabolic activity.
Sacher, G. A.↗
Concept for a high-resolution thermometer utilizing the temperature dependence of the magnetic penetration depth
A thermometer using the temperature dependence of the magnetic penetration depth in superconductors is described which has the potential for temperature resolution, when using a dc SQUID readout, on the order of 1 pK. One such device has been fabricated and characterized to demonstrate proof of concept. It consists of primary and secondary coils of NbTi wire wound on a copper toroidal core on which a thin layer of In (Tc = 3.4 K) has been deposited. The temperature dependence of the mutual inductance, M(T), or self-inductance, is used to detect changes in temperature. Measurements of M(T) have been made with an ac excitation of the primary for various frequencies and peak magnetic field strengths. Estimates of ultimate temperature resolution are given.
Shirron, P. J.↗
Temperature dependence of the reaction O/3P/ + OH/2 Pi/ yields O2 + H
Measurements of the absolute rate and temperature dependence of the rate constant for the reaction of ground state atomic oxygen with hydroxyl radicals to yield molecular oxygen and hydrogen atoms over the temperature range 211-499 K are presented. The reaction was monitored in a low-pressure discharge flow resonance fluorescence apparatus under pseudo-first-order conditions in which the oxygen concentration was greater than the hydroxyl concentration. An expression for the temperature dependence of the rate constant is derived from a least-squares fit to the observed bimolecular rate constants, which were found to range from 3.21 to 2.77 x 10 to the -11th cu cm/molecule per sec for temperatures from 211 to 499 K, indicative of a slight negative temperature dependence. Results are compared with those of previous workers, and the significance of the lower value of the rate constant obtained in the present study to models of HO(x) in the upper stratosphere is indicated.
Lewis, R. S.↗
Temperature dependence of optically dumped far-infrared (FIR) laser output power
The temperature dependence of the small signal gain and saturation power are derived using temperature-dependent rates in a four-level model. An expression is developed for the output power of a far-infrared oscillator as a function of temperature for both fixed pressure and fixed density. The results are valid in the regime of homogeneous broadening of the rotational transition and Doppler broadening of the pump transition. It is shown that, for most lasers, both the small signal gain and the saturation power decrease with increasing temperature. These effects have the overall result of increasing output power with decreasing temperatures.
Lawandy, N. M.↗
Temperature dependence of optically pumped far-infrared /FIR/ laser output power
The temperature dependence of the small signal gain and saturation power are derived using temperature-dependent rates in a four-level model. An expression is developed for the output power of a far-infrared oscillator as a function of temperature for both fixed pressure and fixed density. The results are valid in the regime of homogeneous broadening of the rotational transition and Doppler broadening of the pump transition. It is shown that, for most lasers, both the small signal gain and the saturation power decrease with increasing temperature. These effects have the overall result of increasing output power with decreasing temperatures.
Lawandy, N. M.↗