Material-properties analyzers using superconducting resonators
Low temperature material properties analyzer with superconducting microwave resonant cavity
Hartwig, W. H.↗
SEARCH · Engineering Papers
Results for “superconducting properties and materials”
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.
Simple technique determines ac properties of hard superconductive materials
Critical current density of neodymium-titanium alloy samples is analyzed from magnetization curves to determine the ac properties of hard semiconductive materials. A complete family of magnetization curves is obtained, each curve representing performance at a different temperature.
Harper, C. M.↗
Properties of superconducting Nb3Ga materials.
The superconducting-to-normal phase boundary was studied experimentally in several Nb-Ga materials as a function of applied field and superconducting transition temperature. When properly fabricated, the stoichiometric material Nb3Ga yields a superconducting transition temperature of 20.3 K, the highest yet reported for a binary alloy. Preliminary work shows that Nb-Ga materials with a superconducting transition temperature of 19 K can be made by chemical vapor deposition, a process commonly used for producing commercial superconducting tape.
Foner, S.↗
Characterizations of electrical properties of highT(sub c) superconducting materials
The automated data acquisition system developed in the Space Science Laboratory at Marshall Space Flight Center for measuring electrical properties of high temperature superconductors is described. The acquisition system, consisting of a computer and computer-controlled hardware, allows large numbers of voltage, current, temperature, and magnetic measurements to be performed on bulk and thin film samples. Typical results are shown characterizing transition temperature (T sub c), critical current density (J sub c), and magnetic properties of bulk high T(sub c) materials as a function of temperature.
Sisk, R. C.↗
Processing and property evaluation of metal matrix superconducting materials
Metal - superconductor (YBCO) systems have been prepared and characterized by resistivity, ac susceptibility and dc SQUID magnetic moment measurements. The silver composites showed superconducting transition for all the composites processed and the superconducting transition temperature tends to depend upon the concentration of the silver in the composite. Aluminum composites showed an unusual resistivity results with two transitions around 90 K and 120 K. The superconducting property of silver composites can be explained qualitatively in terms of the proximity theory that has been suggested for the low temperature superconductors.
Rao, Appajosula S.↗
A simple method for characterizing the RF properties of high-temperature superconductive materials
A simple method using a resonant strip in a rectangular waveguide has been devised for superconductive material characterization. The method has the advantages of simplicity; and it requires only a small piece of the superconductive material. The resonant frequency of the superconductive strip can be predicted theoretically.
Chang, K.↗
High temperature superconductors
The two principle objectives are to develop materials that superconduct at higher temperatures and to better understand the mechanisms behind high temperature superconductivity. Experiments on the thermal reaction, structure, and physical properties of materials that exhibit superconductivity at high temperatures are discussed.
Wu, Maw-Kuen↗
Metals processing
The metals processing effort is directed towards improvement of performance and usefulness of materials through modification and control of shape and internal structure. Interaction of reactive gases, introduced into a plasma arc, with iron alloys were analyzed. The technology of magnesium production was assessed. The study of fast fluidized bed reactors is continued. Aspects of separation processes are being investigated. The development of high field superconducting composites for use in large magnetic fusion devices is also discussed. Processing, structure, and property relationships of superconducting materials and the substitution of precious metals in standard electrical contact and connector applications are tested. The influence of processing procedures on the structure of zircaloy and nickel base alloys with a goal of improving mechanical properties and performance is investigated. Investigation of the potential of metal insulator semiconductor junctions as photovoltaic devices is reported.
Source record↗
High T(sub c) superconductors fabricated by plasma aerosol mist deposition technique
We report new results on high T(sub c) superconductors fabricated by a plasma aerosol mist deposition technique, in atmospheric environment. Materials fabricated are YBaCuO, BiPbSrCaCuO, BaCaCuO precursor films for TlBaCaCuO, and other buffers such as YSZ. Depending on processing conditions, sizes of crystallites and/or particles are between dozens of nano-meters and several micrometers. Superconductive properties and other material characteristics can also be tailored.
Wang, X. W.↗
A Study of Production of Miscibility Gap Alloys with Controlled Structures
Composite materials were directionally solidified using a new technique to align the constituents longitudinally along the length of the specimen. In some instances a tin coating was applied and diffused into the sample to form a high transition temperature superconducting phase. The superconducting properties were measured and compared with the properties obtained for powder composites and re-directionally solidified powder compacts. The samples which were compacted and redirectionally solidified showed the highest transition temperature and wildest transition range. This indicates that both steps, powder compaction and resolidification, determine the final superconducting properties of the material.
Parr, R. A.↗
Superconducting tensor gravity gradiometer
The employment of superconductivity and other material properties at cryogenic temperatures to fabricate sensitive, low-drift, gravity gradiometer is described. The device yields a reduction of noise of four orders of magnitude over room temperature gradiometers, and direct summation and subtraction of signals from accelerometers in varying orientations are possible with superconducting circuitry. Additional circuits permit determination of the linear and angular acceleration vectors independent of the measurement of the gravity gradient tensor. A dewar flask capable of maintaining helium in a liquid state for a year's duration is under development by NASA, and a superconducting tensor gravity gradiometer for the NASA Geodynamics Program is intended for a LEO polar trajectory to measure the harmonic expansion coefficients of the earth's gravity field up to order 300.
Paik, H. J.↗
Superconductive magnetic-field-trapping device
An apparatus which enables the establishment of a magnetic field in air that has the same intensity as the ones in ferromagnetic materials is described. The apparatus is comprised of a core of ferromagnetic material and is surrounded by a cylinder made of a material that has superconducting properties when cooled below a critical temperature. A method is provided for producing a magnetic field through the ferromagnetic core. The core can also be split and pulled apart when it is required that the center of the cavity be left empty.
Hildebrandt, A. F.↗
The effects of shock wave compaction on the transition temperatures of A15 structure superconductors
Several superconductors with the A15 structure exhibit a positive pressure coefficient, indicating that their transition temperatures increase with applied pressure. Powders of the composition Nb3Al, Nb3Ge, Nb3(Al0.75Ge0.25), and V3Si were compacted by explosive shock waves. The superconducting properties of these materials were measured before and after compaction and it was found that regardless of the sign of the pressure coefficient, the transition temperature is always lowered. The decrease in transition temperature is associated with a decrease in the particle diameter. The shock wave passage through a 3Nb:1Ge powder mixture leads to the formation of at least one compound (probably Nb5Ge3). However, the formation of the A15 compound Nb3Ge is not observed. Elemental niobium powder can be compacted by converging shock waves close to the expected value of the bulk density. Under special circumstances a partial remelting in the center of the sample is observed.
Otto, G. H.↗
Superconductivity devices: Commercial use of space
The processing and screen printing of the superconducting BSCCO and 123 YBCO materials on substrates is described. The resulting superconducting properties and the use of these materials as possible electrode materials for ferroelectrics at 77 K are evaluated. Also, work performed in the development of solid-state electromechanical actuators is reported. Specific details include the fabrication and processing of high strain PBZT and PLZT electrostrictive materials, the development of PSZT and PMN-based ceramics, and the testing and evaluation of these electrostrictive materials. Finally, the results of studies on a new processing technology for preparing piezoelectric and electrostrictive ceramic materials are summarized. The process involves a high temperature chemical reduction which leads to an internal pre-stressing of the oxide wafer. These reduced and internally biased oxide wafers (RAINBOW) can produce bending-mode actuator devices which possess a factor of ten more displacement and load bearing capacity than present-day benders.
Haertling, Gene↗
Development and testing of a superconducting link for an IR detector
The development and testing of a ceramic superconducting link for an infrared detector is summarized. Areas of study included the materials used, the electrical contacts, radiation and temperature cycling effects, aging, thermal conductivity, and computer models of an ideal link. Materials' samples were processed in a tube furnace at temperatures of 840 C to 865 C for periods up to 17 days and transition temperatures and critical current densities were recorded. The project achieved better quality high superconducting transition temperature material through improved processing and also achieved high quality electrical contacts. Studies on effects of electron irradiation, temperature cycling, and aging on superconducting properties indicate that the materials will be suitable for space applications. Various presentations and publications on the study's results are reported.
Caton, R.↗
Superconducting tensor gravity gradiometer for satellite geodesy and inertial navigation
A sensitive gravity gradiometer can provide much needed gravity data of the earth and improve the accuracy of inertial navigation. Superconductivity and other properties of materials at low temperatures can be used to obtain a sensitive, low-drift gravity gradiometer; by differencing the outputs of accelerometer pairs using superconducting circuits, it is possible to construct a tensor gravity gradiometer which measures all the in-line and cross components of the tensor simultaneously. Additional superconducting circuits can be provided to determine the linear and angular acceleration vectors. A tensor gravity gradiometer with these features is being developed for satellite geodesy. The device constitutes a complete package of inertial navigation instruments with angular and linear acceleration readouts as well as gravity signals.
Paik, H. J.↗
Analysis of Yttrium-Barium-Copper-Oxide by x ray diffraction and mechanical characterization
The efforts in developing high-temperature superconductor (HTSC) YBa2Cu3O7 electrical leads are to benefit future NASA missions that will carry payloads with sensitive instruments operating at cryogenic temperatures. Present-day leads made of copper or magnesium are responsible for as much as 50 percent of the parasitic heat load on cryogenic systems. A reduction of this load could be achieved by replacing the conventional materials with HTSC ceramic electrical leads. Superconductor quality has become a concern in the industry, as has the development of effective evaluation methods. The factors that need to be examined for these materials include material purity, mechanical properties, and superconducting ability below the critical temperature. We applied several methods to study these factors: thermogravimetric analysis, x-ray diffraction, tensile testing, and laser-generated ultrasound. Our objectives were to determine the average tensile strength and Young's modulus of the HTSC material and to compare them to those values for copper and manganin.
Arsenovic, Petar↗
Reaction of YBa2Cu3O(7-beta) with Gold, Silver, Bismuth and Lead: Substitution Chemistry and Composite Fabrication
The reaction of YBa2Cu3O(7-beta) with Au, Ag, Bi, and Ph ions or metal is described. Three types of materials were produced: a well-defined series of homogeneous superconductors was obtained for Au ion substitution with little effect on T(sub c); attempted Ag and Bi ion substitution resulted in multi-phase samples with slightly enhanced T(sub c); finally, attempts to produce superconducting metal/superconducting ceramic composites with Pb and Bi powders resulted in multi-phase samples with drastically diminished superconducting properties. For Au- substituted superconductors, YBa2(Cu(l-x)Au(x))3O(7-beta), a substitution series (x = 0 - 0.1) has been synthesized. For x = 0.1 there was no change in the a and b lattice parameters (a = 3.826 A and b = 3.889 A) but a 0.06 A c axis expansion to 11.75 A was observed. The valence of Cu and Au in YBa2Au(0.3)Cu(2.7)O(7-beta) was investigated using X-ray Absorption Near-Edge Structure (XANES). X-ray studies indicate that Au goes into the Cu(l) site and Cu K edge XANES shows that this has little effect on the oxidation state of the remaining copper. A small effect on T(sub c) is observed (T(sub c) = 89 K for x = 0.10). Ag and Bi addition results in a rise in T(sub c) and a decrease in (delta)T(sub c) at low levels (x = 0.10 Ag, T(sub c) = 94 K and (delta)T(sub c) = 0.5 K; x = 0.02 Bi, T(sub c) = 94 K and (delta)T(sub c) = 1K) relative to typical values for YBa2Cu3O(7-beta) (T(sub c) = 91 K, (delta)T(sub c) = 2 K). Attempts at fabrication of Pb- and Pb(1-x)Bi(x)-superconductor composites are described. Cold pressing followed by low temperature (200 C) sintering resulted in a composite which excluded flux below 90 K but did not show zero electrical resistance until the metal (alloy) superconducting transition. X-ray diffraction showed the presence of pervoskite and metal. Processing at moderate (450 C) or high (950 C) temperatures resulted in oxygen-depleted pervoskite and/or metal oxides. These materials displayed greatly degraded superconducting properties. Processing at 800 C resulted in high T(sub c) only for composites containing greater than 90% weight fraction ceramic. Reaction of metal with YBa2Cu3O(7-beta) formed superconducting lead/bismuth-based oxides and other binary oxides.
Hepp, Aloysius F.↗