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At least 19 records

Solar Fuels Generator

The solar fuels generator includes an ionically conductive separator between a gaseous first phase and a second phase. A photoanode uses one or more components of the first phase to generate cations during operation of the solar fuels generator. A cation conduit is positioned provides a pathway along which the cations travel from the photoanode to the separator. The separator conducts the cations. A second solid cation conduit conducts the cations from the separator to a photocathode.

Lewis, Nathan S.

Solar Fuel Generator

The disclosure provides conductive membranes for water splitting and solar fuel generation. The membranes comprise an embedded semiconductive/photoactive material and an oxygen or hydrogen evolution catalyst. Also provided are chassis and cassettes containing the membranes for use in fuel generation.

Lewis, Nathan S.

Review of solar fuel-producing quantum conversion processes

The status and potential of fuel-producing solar photochemical processes are discussed. Research focused on splitting water to produce dihydrogen and is at a relatively early stage of development. Current emphasis is primarily directed toward understanding the basic chemistry underlying such quantum conversion processes. Theoretical analyses by various investigators predict a limiting thermodynamic efficiency of 31% for devices with a single photosystem operating with unfocused sunlight at 300 K. When non-idealities are included, it appears unlikely that actual devices will have efficiencies greater than 12 to 15%. Observed efficiencies are well below theoretical limits. Cyclic homogeneous photochemical processes for splitting water have efficiencies considerably less than 1%. Efficiency can be significantly increased by addition of a sacrificial reagent; however, such systems are no longer cyclic and it is doubtful that they would be economical on a commercial scale. The observed efficiencies for photoelectrochemical processes are also low but such systems appear more promising than homogeneous photochemical systems. Operating and systems options, including operation at elevated temperature and hybrid and coupled quantum-thermal conversion processes, are also considered.

Peterson, D. B.

Operation of the 25kW NASA Lewis Research Center Solar Regenerative Fuel Cell Tested Facility

Assembly of the NASA Lewis Research Center(LeRC)Solar Regenerative Fuel Cell (RFC) Testbed Facility has been completed and system testing has proceeded. This facility includes the integration of two 25kW photovoltaic solar cell arrays, a 25kW proton exchange membrane (PEM) electrolysis unit, four 5kW PEM fuel cells, high pressure hydrogen and oxygen storage vessels, high purity water storage containers, and computer monitoring, control and data acquisition.

Solar Regenerative Fuel Cell electrolyzer

Design of Long-Endurance Unmanned Airplanes Incorporating Solar and Fuel Cell Propulsion

Preliminary performance analysis and conceptual design are described for a class of unmanned airplanes possessing multi-day endurance capability. A mixed-mode electric power system incorporates solar cells for daytime energy production and a non-regenerative H2-02 fuel cell to supply energy for night flight. The power system provides energy for all onboard systems, including propulsion., payload, and avionics. Excess solar energy is available during significant portions of the day, and may be used for climbing, maneuvering, or payload functions. By jettisoning fuel cell reactant product (water) during flight, vehicle endurance may be increased under certain conditions. Empirical structure sizing algorithms are combined with low-Reynolds number aerodynamics algorithms to estimate airplane size and geometry to meet prescribed mission requirements. Initial calculations for summertime, high-altitude flight (above 40,000 ft (12 km)) at moderate latitude (31 deg N) indicate that mission endurance of several days may be possible for configurations having wing loadings on the order of 0.9 to 1.3 lb/ft(exp 2). These aircraft tend to be somewhat smaller than solar-powered aircraft previously conceived for multi-month endurance utilizing regenerative fuel cell systems for night flight.

Youngblood, James W.

Design of long-endurance unmanned airplanes incorporating solar and fuel cell propulsion

Attention is given to the design features and operational capabilities of a class of unmanned flight vehicles possessing multiday mission endurance capabilities, based on the use of a mixed-mode electric power system which incorporates solar cells for diurnal energy production and a nonregenerative H2-O2 fuel cell for nocturnal energy supply. Energy is thereby provided for not only propulsion, but also the operation of the payload and the vehicle's avionics. The excess solar energy available during high insolation portions of the diurnal period may be used for climb/maneuvering or payload-related functions. Empirical structure scaling algorithms are combined with low Reynolds number aerodynamics algorithms to estimate requisite size and geometry for the chosen mission. Wing loadings will be of the order of 0.9-1.3 lb/sq ft.

Youngblood, J. W.

Advanced development: Fuels

The solar thermal fuels and chemicals program at Jet Propulsion Laboratory are described. High technology is developed and applied to displace fossil fuel (oil) use in the production/processing of valuable fuels and chemicals. The technical and economic feasibility is demonstrated to extent that enables the industry to participate and commercialize the product. A representative process, namely Furfural production with a bottoming of acetone, butanol and ethanol, is described. Experimental data from all solar production of furfural is discussed. Estimates are given to show the attractiveness of this process, considering its flexibility to be adaptable to dishes, troughs or central receivers. Peat, lignite and low rank coal processing, heavy oil stripping and innovative technologies for process diagnostics and control are mentioned as examples of current projects under intensive development.

Ramohalli, K.

Solar Airplanes and Regenerative Fuel Cells

A solar electric aircraft with the potential to "fly forever" has captured NASA's interest, and the concept for such an aircraft was pursued under Aeronautics Environmental Research Aircraft and Sensor Technology (ERAST) project. Feasibility of this aircraft happens to depend on the successful development of solar power technologies critical to NASA's Exploration Initiatives; hence, there was widespread interest throughout NASA to bring these technologies to a flight demonstration. The most critical is an energy storage system to sustain mission power during night periods. For the solar airplane, whose flight capability is already limited by the diffuse nature of solar flux and subject to latitude and time of year constraints, the feasibility of long endurance flight depends on a storage density figure of merit better than 400-600 watt-hr per kilogram. This figure of merit is beyond the capability of present day storage technologies (other than nuclear) but may be achievable in the hydrogen-oxygen regenerative fuel cell (RFC). This potential has led NASA to undertake the practical development of a hydrogen-oxygen regenerative fuel cell, initially as solar energy storage for a high altitude UAV science platform but eventually to serve as the primary power source for NASAs lunar base and other planet surface installations. Potentially the highest storage capacity and lowest weight of any non-nuclear device, a flight-weight RFC aboard a solar-electric aircraft that is flown continuously through several successive day-night cycles will provide the most convincing demonstration that this technology's widespread potential has been realized. In 1998 NASA began development of a closed cycle hydrogen oxygen PEM RFC under the Aeronautics Environmental Research Aircraft and Sensor Technology (ERAST) project and continued its development, originally for a solar electric airplane flight, through FY2005 under the Low Emissions Alternative Power (LEAP) project. Construction of the closed loop system began in 2002 at the NASA Glenn Research Center in Cleveland, Ohio. System checkout was completed, and testing began, in July of 2003. The initial test sequences were done with only a fuel cell or electrolyzer in the test rig. Those tests were used to verify the test apparatus, procedures, and software. The first complete cycles of the fully closed loop, regenerative fuel cell system were successfully completed in the following September. Following some hardware upgrades to increase reactant recirculation flow, the test rig was operated at full power in December 2003 and again in January 2004. In March 2004 a newer generation of fuel cell and electrolyzer stacks was substituted for the original hardware and these stacks were successfully tested at full power under cyclic operation in June of 2004.

Bents, David J.

Two-Step Laser Ranging for Precise Tracking of a Spacecraft

A document proposes a two-step laser ranging technique for precise tracking of a coasting interplanetary spacecraft to determine the degree to which leakage of fuel, solar wind, and/or solar-radiation pressure causes it to deviate from a purely gravitational trajectory. Such a determination could contribute to the precision of a test of a theory of gravitation. In the technique, a proof mass would be released from the spacecraft. By use of laser ranging equipment on the spacecraft and retroreflectors attached to the proof mass, the relative position of the spacecraft and proof mass would be determined. Meanwhile, the position of the spacecraft relative to the Earth would be determined by ranging by use of a laser transponder. The vector sum of the two sets of ranging measurements would be the position of the proof mass relative to the Earth. Unlike the acceleration of the spacecraft, the acceleration of the proof mass should not include a residual component attributable to leakage of fuel. In addition, the effects of solar radiation and solar wind on the proof mass could be minimized by releasing the proof mass into the shadow of the spacecraft.

Chui, Talso

High temperature solid oxide regenerative fuel cell for solar photovoltaic energy storage

A hydrogen-oxygen regenerative fuel cell energy storage system based on high temperature solid oxide fuel cell technology is discussed which has application to darkside energy storage for solar photovoltaics. The forward and reverse operating cycles are described, and heat flow, mass, and energy balance data are presented to characterize the system's performance and the variation of performance with changing reactant storage pressure. The present system weighs less than nickel hydrogen battery systems after 0.7 darkside operation, and it maintains a specific weight advantage over radioisotope generators for discharge periods up to 72 hours.

Bents, David J.

High temperature solid oxide regenerative fuel cell for solar photovoltaic energy storage

A hydrogen-oxygen regenerative fuel cell (RFC) energy storage system based on high temperature solid oxide fuel cell (SOFC) technology is described. The reactants are stored as gases in lightweight insulated pressure vessels. The product water is stored as a liquid in saturated equilibrium with the fuel gas. The system functions as a secondary battery and is applicable to darkside energy storage for solar photovoltaics.

Bents, David J.

Space Shuttle orbiter power system requirements and design.

This paper is the third in a series discussing space station-shuttle power systems. The power requirements of the orbiter and a tradeoff study of several possible power system concepts are presented. The power sources considered are fuel cells, solar array/battery, radioisotope Brayton, and cryogenic fueled turboalternators. A fuel cell power source is chosen as the best candidate for the orbiter power system. A baseline power system is defined using four fuel cells, secondary batteries, primary emergency batteries, and constant speed drive-alternator units for ferrying power. A weight and cost summary is included.

Lombard, J. W.

High altitude solar power platform

Solar power is a preeminent alternative to conventional aircraft propulsion. With the continued advances in solar cells, fuel cells, and composite materials technology, the solar powered airplane is no longer a simple curiosity constrained to flights of several feet in altitude or minutes of duration. A high altitude solar powered platform (HASPP) has several potential missions, including communications and agriculture. In remote areas, a HASPP could be used as a communication link. In large farming areas, a HASPP could perform remote sensing of crops. The impact of HASPP in continuous flight for one year on agricultural monitoring mission is presented. This mission provides farmers with near real-time data twice daily from an altitude which allows excellant resolution on water conditions, crop diseases, and insect infestation. Accurate, timely data will enable farmers to increase their yield and efficiency. A design for HASPP for the foregoing mission is presented. In the design power derived from solar cells covering the wings is used for propulsion, avionics, and sensors. Excess power produced midday will be stored in fuel cells for use at night to maintain altitude and course.

Bailey, M. D.

Aluminum-26 in the early solar system - Fossil or fuel

The isotopic composition of Mg was measured in different phases of a Ca-Al-rich inclusion in the Allende meteorite. Large excesses of Mg-26 of up to 10% were found. These excesses correlate strictly with the Al-27/Mg-24 ratio for four coexisting phases with distinctive chemical compositions. Models of in situ decay of Al-26 within the solar system and of mixing of interstellar dust grains containing fossil Al-26 with normal solar system material are presented. The observed correlation provides definitive evidence for the presence of Al-26 in the early solar system. This requires either injection of freshly synthesized nucleosynthetic material into the solar system immediately before condensation and planet formation, or local production within the solar system by intense activity of the early sun. Planets promptly produced from material with the inferred Al-26/Al-27 would melt within about 300,000 years.

Lee, T.

High Altitude Long Endurance UAV Analysis of Alternatives and Technology Requirements Development

An Analysis of Alternatives and a Technology Requirements Study were conducted for two mission areas utilizing various types of High Altitude Long Endurance (HALE) Unmanned Aerial Vehicles (UAV). A hurricane science mission and a communications relay mission provided air vehicle requirements which were used to derive sixteen potential HALE UAV configurations, including heavier-than-air (HTA) and lighter-than-air (LTA) concepts with both consumable fuel and solar regenerative propulsion systems. A HTA diesel-fueled wing-body-tail configuration emerged as the preferred concept given near-term technology constraints. The cost effectiveness analysis showed that simply maximizing vehicle endurance can be a sub-optimum system solution. In addition, the HTA solar regenerative configuration was utilized to perform both a mission requirements study and a technology development study. Given near-term technology constraints, the solar regenerative powered vehicle was limited to operations during the long days and short nights at higher latitudes during the summer months. Technology improvements are required in energy storage system specific energy and solar cell efficiency, along with airframe drag and mass reductions to enable the solar regenerative vehicle to meet the full mission requirements.

Nickol, Craig L.

High Altitude Long Endurance Air Vehicle Analysis of Alternatives and Technology Requirements Development

The objective of this study was to develop a variety of High Altitude Long Endurance (HALE) Unmanned Aerial Vehicle (UAV) conceptual designs for two operationally useful missions (hurricane science and communications relay) and compare their performance and cost characteristics. Sixteen potential HALE UAV configurations were initially developed, including heavier-than-air (HTA) and lighter-than-air (LTA) concepts with both consumable fuel and solar regenerative (SR) propulsion systems. Through an Analysis of Alternatives (AoA) down select process, the two leading consumable fuel configurations (one each from the HTA and LTA alternatives) and an HTA SR configuration were selected for further analysis. Cost effectiveness analysis of the consumable fuel configurations revealed that simply maximizing vehicle endurance can lead to a sub-optimum system solution. An LTA concept with a hybrid propulsion system (solar arrays and a hydrogen-air proton exchange membrane fuel cell) was found to have the best mission performance; however, an HTA diesel-fueled wing-body-tail configuration emerged as the preferred consumable fuel concept because of the large size and technical risk of the LTA concept. The baseline missions could not be performed by even the best HTA SR concept. Mission and SR technology trade studies were conducted to enhance understanding of the potential capabilities of such a vehicle. With near-term technology SR-powered HTA vehicles are limited to operation in favorable solar conditions, such as the long days and short nights of summer at higher latitudes. Energy storage system specific energy and solar cell efficiency were found to be the key technology areas for enhancing HTA SR performance.

Nickol, Craig L.

Propulsion System Models for Rotorcraft Conceptual Design

The conceptual design code NDARC (NASA Design and Analysis of Rotorcraft) was initially implemented to model conventional rotorcraft propulsion systems, consisting of turboshaft engines burning jet fuel, connected to one or more rotors through a mechanical transmission. The NDARC propulsion system representation has been extended to cover additional propulsion concepts, including electric motors and generators, rotor reaction drive, turbojet and turbofan engines, fuel cells and solar cells, batteries, and fuel (energy) used without weight change. The paper describes these propulsion system components, the architecture of their implementation in NDARC, and the form of the models for performance and weight. Requirements are defined for improved performance and weight models of the new propulsion system components. With these new propulsion models, NDARC can be used to develop environmentally-friendly rotorcraft designs.

Propulsion System Models