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At least 19 records

In-situ Nanoscale Ablation

An understanding of the ablation of carbon-based materials is crucial to modeling the behavior of atmospheric entry spacecrafts equipped with thermal protection systems (TPS).Carbon is the backbone of TPS systems such as PICA (phenolic-impregnated carbon ablator).Therefore in the present work we study ablation of highly oriented pyrolytic graphite (HOPG)in oxygen at temperatures up to 1000°C done within a gas reaction cell housed in a scanning transmission electron microscope (STEM). Observation of the HOPG oxidation on specimens sectioned parallel and normal to the carbon basal planes in the presence of oxygen are reported.Pitting caused by residual oxygen and/or platinum particles from the sectioning process was observed before oxygen gas flow was established at 750°C in the specimen sectioned with the carbon basal planes parallel to the beam direction. Introduction of oxygen flow caused rapid oxidation moving in a uniform front that completely consumed the HOPG in approximately 1.5minutes. The specimen sectioned with the carbon basal planes normal to the beam direction did not show the same pitting phenomenon but exhibited rapid oxidation at 1000°C that proceeded in a uniform front and completed in approximately 1 minute. All specimens tested had a husk resembling the original specimen shape left over after oxidation. It is concluded that this husk is most likely ash impurity from the HOPG or impurities from the sectioning process or E-chip. A residual gas analyszer (RGA) was successfully used to monitor gas flows during the experiments but was yet unsuccessful in monitoring oxidation gas products produced during the experiment.Future studies will optimize the RGA setup in order to maximize the potential for detecting these species. These in-situ studies successfully show how this highly ordered carbon ablates on a nano- and micro-scopic length scale and can be used to provide fundamental understanding of carbon ablation that can be used to design the next-generation of TPS systems.

Nanoscale Ablation↗

Surface Tensions and Their Variations with Temperature and Impurities

The surface tensions in this work were determined using the sessile drop technique. This method is based on a comparison of the profile of a liquid drop with the profile calculated by solving the Young-Laplace equation. The comparison can be made in several ways; the traditional Bashforth-Adams procedure was used in conjunction with recently calculated drop shape tables which virtually eliminate interpolation errors. Although previous study has found little difference in measurements with pure and oxygen doped silicon, there is other evidence suggesting that oxygen in dilute concentrations severely depresses the surface tension of silicon. The surface tension of liquid silicon in purified argon atmospheres was measured. A temperature coefficient near -0.28 mJ/square meters K was found. The experiments show a high sensitivity of the surface tension to what is believed are low concentrations of oxygen. Thus one cannot rule out some effect of low levels of oxygen in the results. However, the highest surface tension values obtained in conditions which minimized the residual oxygen pressure are in good agreement with a previous measurement in pure hydrogen. Therefore, depression of the surface tension by oxygen is insignificant in these measurements.

Hardy, S. C.↗

Evaluation and Improvement of Liquid Propellant Rocket Chugging Analysis Techniques. Part 2: a Study of Low Frequency Combustion Instability in Rocket Engine Preburners Using a Heterogeneous Stirred Tank Reactor Model

During the shutdown of the space shuttle main engine, oxygen flow is shut off from the fuel preburner and helium is used to push the residual oxygen into the combustion chamber. During this process a low frequency combustion instability, or chug, occurs. This chug has resulted in damage to the engine's augmented spark igniter due to backflow of the contents of the preburner combustion chamber into the oxidizer feed system. To determine possible causes and fixes for the chug, the fuel preburner was modeled as a heterogeneous stirred tank combustion chamber, a variable mass flow rate oxidizer feed system, a constant mass flow rate fuel feed system and an exit turbine. Within the combustion chamber gases were assumed perfectly mixed. To account for liquid in the combustion chamber, a uniform droplet distribution was assumed to exist in the chamber, with mean droplet diameter determined from an empirical relation. A computer program was written to integrate the resulting differential equations. Because chamber contents were assumed perfectly mixed, the fuel preburner model erroneously predicted that combustion would not take place during shutdown. The combustion rate model was modified to assume that all liquid oxygen that vaporized instantaneously combusted with fuel. Using this combustion model, the effect of engine parameters on chamber pressure oscillations during the SSME shutdown was calculated.

Bartrand, Timothy A.↗

Lunar Outpost Life Support Architecture Study Based on a High Mobility Exploration Scenario

As scenarios for lunar surface exploration and habitation continue to evolve within NASA s Constellation program, so must studies of optimal life support system architectures and technologies. This paper presents results of a life support architecture study based on a 2009 NASA scenario known as Scenario 12. Scenario 12 represents a consolidation of ideas from earlier NASA scenarios and includes an outpost near the Lunar South Pole comprised of three larger fixed surface elements and four attached pressurized rovers. The scenario places a high emphasis on surface mobility, with planning assuming that all four crewmembers spend roughly 50% of the time away from the outpost on 3-14 day excursions in two of the pressurized rovers. Some of the larger elements can also be mobilized for longer duration excursions. This emphasis on mobility poses a significant challenge for a regenerative life support system in terms of cost-effective waste collection and resource recovery across multiple elements, including rovers with very constrained infrastructure resources. The current study considers pressurized rovers as part of a distributed outpost life support architecture in both stand-alone and integrated configurations. A range of architectures are examined reflecting different levels of closure and distributed functionality. Different lander propellant scavenging options are also considered involving either initial conversion of residual oxygen and hydrogen propellants to water or initial direct oxygen scavenging. Monte Carlo simulations are used to assess the sensitivity of results to volatile high-impact mission variables, including the quantity of residual lander propellants available for scavenging, the fraction of crew time away from the outpost on excursions, total extravehicular activity hours, and habitat leakage. Architectures are evaluated by estimating surpluses or deficits of water and oxygen per 180-day mission and differences in fixed and 10-year-total equivalent system mass (ESM) relative to a reference case. Results are presented based on current assumptions for Scenario 12 and based on Monte Carlo simulations with assumed probability distributions for the high-impact mission variables. The calculated probability of no water or oxygen resupply from Monte Carlo simulations provides a quantitative measure of system robustness that can be used for cost/benefit analyses to identify leading architecture candidates. Areas of technology improvement that are likely to have a significant impact are also suggested.

Lange, Kevin E.↗

Effect of Molding and Machining on Neoflon CTFE M400H Polychlorotrifluoroethylene Rod Stock and Valve Seat Properties

Since 1997 numerous fires have been reported to the Food and Drug Administration involving cylinder valves installed on medical use oxygen cylinders sold and operated within the United States. All of the cylinder valves in question had polychlorotrifluoroethylene (PCTFE) valve seats. Subsequent failure analysis showed that the main seat was the primary source of ignition. A review of the incidents involving cylinder valve fires indicated three possible ignition mechanisms: contaminant promotion, flow friction, and resonance. However, gas purity analysis showed that uncombusted, residual oxygen was within specification. Infrared and energy dispersive spectroscopy further showed that no contaminants or organic compounds were present in the remaining, uncombusted valve seat material or on seat plug surfaces. Therefore, contaminant-promoted ignition did not appear to be responsible for the failures. Observations of extruded material along the outer edge of the coined or loaded seat area produced by cylinder overuse or poppet overload led to concerns that accelerated gas flow across a deformed seat surface could generate enough localized heating to ignite the polymeric seat. Low molecular weight or highly amorphous quick-quenched PCTFE grades might be expected to be especially prone to this type of deformation. Such a failure mechanism has been described as flow friction; however, the corresponding mechanistic parameters are poorly understood. Subsequent revelation of low-temperature dimensional instability by thermomechanical analysis (TMA) in a variety of PCTFE sheet and rod stock samples led to new concerns that PCTFE valve seats could undergo excessive expansion or contraction during service. During expansion, additional extrusion and accompanying flow friction could occur. During contraction, a gap between the seal and adjacent metal surfaces could form. Gas flowing past the gap could, in turn, lead to resonance heating and subsequent ignition as described in ASTM Guide for Evaluation Nonmetallic Materials for Oxygen Service (G 63). Attempts to uncover the origins of the observed dimensional instability were hindered by uncertainties about resin grade, process history, and post-process heat history introduced by machining, annealing, and sample preparation. An approach was therefore taken to monitor property changes before and after processing and machining using a single, well-characterized lot of Neoflon CTFE.1 M400H resin. A task group consisting of the current PCTFE resin supplier, two molders, and four valve seat manufacturers was formed, and phased testing on raw resin, intermediate rod stock, and finished valve seats initiated. The effect of processing and machining on the properties of PCTFE rod stock and oxygen gas cylinder valve seats was then determined. Testing focused on two types of extruded rod stock and one type of compression-molded rod stock. To accommodate valve seat manufacturer preferences for certain rod stock diameters, two representative diameters were used (4.8 mm (0.1875 in.) and 19.1 mm (0.75 in.)). To encompass a variety of possible sealing configurations, seven different valve seat types with unique geometries or machining histories were tested. The properties investigated were dimensional stability as determined by TMA, specific gravity, differential scanning calorimetry (DSC), compressive strength, zero strength time, and intrinsic viscosity. Findings are discussed in the context of polymer structure-process-property relationships whenever possible.

Waller, Jess M.↗

Aether drift and the isotropy of the universe

An experiment is proposed which will detect and map the large-angular-scale anisotropies in the 3 deg K primordial black-body radiation with a sensitivity of .0002 deg K and an angular resolution of about 10 deg . It will detect the motion of the earth with respect to the distant matter of the Universe ("Aether Drift"), and will probe the homogeneity and isotropy of the Universe (the "Cosmological Principle"). The experiment will use two Dicke radiometers, one at 33 GHz to detect the cosmic anisotropy, and one at 54 GHz to detect anisotropies in the residual oxygen above the detectors. An upper hatch for the NASA-AMES Earth Survey Aircraft (U-2) is being modified to accept the dual-radiometer system. A few hours of observation should be sufficient to detect an anisotropy.

Muller, R. A.↗

Aether drift and the isotropy of the universe: a measurement of anisotropies in the primordial black-body radiation

This experiment detected and mapped large-angular-scale anisotropies in the 3 K primordial black-body radiation with a sensitivity of 2x.0001k and an angular resolution of about 10 degs. It measured the motion of the Earth with respect to the distant matter of the Universe (Aether Drift), and probed the homogeneity and isotropy of the Universe (the Cosmological Principle). The experiment used two Dicke radiometers, one at 33 GHz to detect the cosmic anisotropy, and one at 54 GHz to detect anisotropies in the residual oxygen above the detectors. The system was installed in the NASA-Ames Earth Survey Aircraft (U-2), and operated successfully in a series of flights.

Muller, R. A.↗

Aether Drift and the isotropy of the universe: A measurement of anisotropes in the primordial black-body radiation

Large-angular-scale anisotropies in the 3 K primordial black-body radiation were detected and mapped with a sensitivity of 2 x to the minus 4 power K and an angular resolution of about 10 deg. The motion of the Earth with respect to the distant matter of the Universe ("Aether Drift") was measured and the homogeneity and isotropy of the Universe (the "Cosmological Principle") was probed. The experiment uses two Dicke radiometers, one at 33 GHz to detect the cosmic anisotropy, and one at 54 GHz to detect anisotropies in the residual oxygen above the detectors. The system was installed in the NASA-Ames Earth survey aircraft (U-2), and operated successfully in a series of flights in both the Northern and Southern Hemispheres. Data taking and analysis to measure the anisotropy were successful.

Smoot, G. F.↗

Studies of Thermophysical Properties of Metals and Semiconductors by Containerless Processing Under Microgravity

Electromagnetic levitation under microgravity provides unique opportunities for the investigation of liquid metals, alloys and semiconductors, both above and below their melting temperatures, with minimized disturbances of the sample under investigation. The opportunity to perform such experiments will soon be available on the ISS with the EML payload which is currently being integrated. With its high-performance diagnostics systems EML allows to measure various physical properties such as heat capacity, enthalpy of fusion, viscosity, surface tension, thermal expansion coefficient, and electrical conductivity. In studies of nucleation and solidification phenomena the nucleation kinetics, phase selection, and solidification velocity can be determined. Advanced measurement capabilities currently being studied include the measurement and control of the residual oxygen content of the process atmosphere and a complementary inductive technique to measure thermophysical properties.

Seidel, A.↗

Analysis of low-g heat transfer for a cryogenic oxygen pressurization heater

After the external tank separates from the Orbiter about 2000 pounds of residual liquid oxygen remain in the main propulsion system lines. The pressurization of liquid oxygen from a subcritical to a supercritical state by the use of the heaters of the PRSA tanks while in a low-g environment is investigated. The performance of the heaters while bringing the state of the substance from the subcritical state to the supercritical one is studied, with particular emphasis on the time the pressurization process takes, and the temperature of the heater as the process proceeds.

Rios, J.↗

Low earth orbit environmental effects on osmium and related optical thin-film coatings

A number of samples of optical thin film materials were flown on Shuttle flight STS-8 as part of an experiment to evaluate their interaction with residual atomic oxygen in low earth orbit. Osmium was selected because of its usefulness as a reflective optical coating for far-UV instruments and for confirmation of results from previous Shuttle flights in which such coatings disappeared. Reflectance data and photographic evidence are presented to support the hypothesis that the osmium disappearance is due to reaction with oxygen to form a volatile oxide. Platinum and iridium, which were included for comparison, fared much better.

Gull, T. R.↗

Space Shuttle Main Engine fuel preburner augmented spark igniter shutdown detonations

Detonations were experienced in the Space Shuttle Main Engine fuel preburner (FPB) augmented spark igniter (ASI) during engine cutoff. Several of these resulted in over pressures sufficient to damage the FPB ASI oxidizer system. The detonations initiated in the FPB ASI oxidizer line when residual oxidizer (oxygen) in the line mixed with backflowing fuel (hydrogen) and detonated. This paper reviews the damage history to the FPB ASI oxidizer system, an engineering assessment of the problem cause, a verification of the mechanisms, the hazards associated with the detonations, and the solution implemented.

Dexter, C. E.↗

Effects of the LDEF orbital environment on the reflectance of optical mirror materials

Specimens of eight different optical mirror materials were flown in low earth orbit as part of the Long Duration Exposure Facility (LDEF) manifest to determine their ability to withstand exposure to the residual atomic oxygen and other environmental effects at those altitudes. Optical thin films of aluminum, gold, iridium, osmium, platinum, magnesium fluoride-overcoated aluminum and reactively deposited, silicon monoxide-protected aluminum, all of which were vacuum deposited on polished fused silica substrates, were included as part of Experiment S0010, Exposure of Spacecraft Coatings. Two specimens of polished, chemical vapor deposited (CVD) silicon carbide were installed in sites available in Experiment A0114, Interaction of Atomic Oxygen with Solid Surfaces at Orbital Altitudes, which included trays in two of the spacecraft bays, one on the leading edge and the other on the trailing edge. One of the silicon carbide samples was located in each of these trays. This paper will compare specular reflectance data from the preflight and postflight measurements made on each of these samples and attempt to explain the changes in light of the specific environments to which the experiments were exposed.

Herzig, Howard↗

Lunar Outpost Life Support Architecture Study Based on a High-Mobility Exploration Scenario

This paper presents results of a life support architecture study based on a 2009 NASA lunar surface exploration scenario known as Scenario 12. The study focuses on the assembly complete outpost configuration and includes pressurized rovers as part of a distributed outpost architecture in both stand-alone and integrated configurations. A range of life support architectures are examined reflecting different levels of closure and distributed functionality. Monte Carlo simulations are used to assess the sensitivity of results to volatile high-impact mission variables, including the quantity of residual Lander oxygen and hydrogen propellants available for scavenging, the fraction of crew time away from the outpost on excursions, total extravehicular activity hours, and habitat leakage. Surpluses or deficits of water and oxygen are reported for each architecture, along with fixed and 10-year total equivalent system mass estimates relative to a reference case. System robustness is discussed in terms of the probability of no water or oxygen resupply as determined from the Monte Carlo simulations.

Lange, Kevin E.↗

An Improved Approach for Analyzing the Oxygen Compatibility of Solvents and other Oxygen-Flammable Materials for Use in Oxygen Systems

Solvents used to clean oxygen system components must be assessed for oxygen compatibility, as incompatible residue or fluid inadvertently left behind within an oxygen system can pose a flammability risk. The most recent approach focused on solvent ignition susceptibility to assess the flammability risk associated with these materials. Previous evaluations included Ambient Pressure Liquid Oxygen (LOX) Mechanical Impact Testing (ASTM G86) and Autogenous Ignition Temperature (AIT) Testing (ASTM G72). The goal in this approach was to identify a solvent material that was not flammable in oxygen. As environmental policies restrict the available options of acceptable solvents, it has proven difficult to identify one that is not flammable in oxygen. A more rigorous oxygen compatibility approach is needed in an effort to select a new solvent for NASA applications. NASA White Sands Test Facility proposed an approach that acknowledges oxygen flammability, yet selects solvent materials based on their relative oxygen compatibility ranking, similar to that described in ASTM G63-99. Solvents are selected based on their ranking with respect to minimal ignition susceptibility, damage and propagation potential, as well as their relative ranking when compared with other solvent materials that are successfully used in oxygen systems. Test methods used in this approach included ASTM G86 (Ambient Pressure LOX Mechanical Impact Testing and Pressurized Gaseous Oxygen (GOX) Mechanical Impact Testing), ASTM G72 (AIT Testing), and ASTM D240 (Heat of Combustion (HOC) Testing). Only four solvents were tested through the full battery of tests for evaluation of oxygen compatibility: AK-225G as a baseline comparison, Solstice PF, L-14780, and Vertrel MCA. Baseline solvent AK-225G exhibited the lowest HOC and highest AIT of solvents tested. Nonetheless, Solstice PF, L-14780, and Vertrel MCA HOCs all fell well within the range of properties that are associated with proven oxygen system materials. Tested AITs for these solvents fell only slightly lower than the AIT for the proven AK-225G solvent. Based on these comparisons in which solvents exhibited properties within those ranges seen with proven oxygen system materials, it is believed that Solstice PF, L-14780, and Vertrel MCA would perform well with respect to oxygen compatibility.

Harper, Susan A.↗

Effect of Reactant Pressure on Proton Exchange Membrane Fuel Cell Performance

It is an objective of the National Aeronautics and Space Administration (NASA) to return to the moon and to create sustained lunar operations. Since many applicable lander and upper stage vehicles utilize cryogenic hydrogen and oxygen propellants, it is appealing to incorporate fuel cells into potential mission concepts. A fuel cell could generate electricity, heat, and water from the residual hydrogen and oxygen propellants. Such a concept depends on the capability of the fuel cell to utilize dry, propellant-grade reactants at reduced pressures compared to typical fuel cell operating conditions. This report describes a NASA evaluation of two passive water removal, non-flow-through proton exchange membrane (PEM) fuel cells: a twelve-cell 50 sq. cm active area stack and a seven-cell 150 sq. cm active area stack. Both stacks operated on research grade hydrogen and oxygen reactants supplied at pressures ranging from 20 psia up to the 45-48 psia design operating point, reliably supporting current densities of at least 450 mA/sq. cm at reduced pressures. Polarization curves, fitted with a semi-empirical equation for overpotential, show an increase in effective ohmic resistance and decrease in reversible cell potential, hydrogen crossover current, and Tafel slope when operating at lower pressures, resulting in a reduction in cell voltage at all current densities. Fitted parameters are compared to published values and rationalized with first principles explanations.

fuel cells↗

Preliminary assessment of power-generating tethers in space and of propulsion for their orbit maintenance

The concept of generating power in space by means of a conducting tether deployed from a spacecraft was studied. Using hydrogen and oxygen as the rocket propellant to overcome the drag of such a power-generating tether would yield more benefit than if used in a fuel cell. The mass consumption would be 25 percent less than the reactant consumption of fuel cells. Residual hydrogen and oxygen in the external tank and in the orbiter could be used very effectively for this purpose. Many other materials (such as waste from life support) could be used as the propellant. Electrical propulsion using tether generated power can compensate for the drag of a power-generating tether, half the power going to the useful load and the rest for electric propulsion. In addition, the spacecraft's orbital energy is a large energy reservoir that permits load leveling and a ratio of peak to average power equal to 2. Critical technologies to be explored before a power-generating tether can be used in space are delineated.

English, R. E.↗

Current Ground Test Options for Nuclear Thermal Propulsion (NTP)

About 20 different NTP engines/ reactors were tested from 1959 to 1972 as part of the Rover and Nuclear Engine for Rocket Vehicle Application (NERVA) program. Most were tested in open air at test cell A or test cell C, at the Nevada Test Site (NTS). Even after serious engine breakdowns of the reactor (e.g., Phoebus 1A), the test cells were cleaned up for other engine tests. The engine test stand (ETS) was made for high altitude (approximately 1 psia) testing of an NTP engine with a flight configuration, but still had the exhaust released to open air. The Rover/NERVA program became aware of new environmental regulations which would prohibit the release of any significant quantity of radioactive particulates and noble gases into the open air. The nuclear furnace (NF-1) was the last reactor tested before the program was cancelled in 1973, but successfully demonstrated a scrubber concept on how to filter the NTP exhaust. The NF-1 was demonstrated in the summer of 1972. The NF-1 used a 44MW reactor and operated each run for approximately 90 minutes. The system cooled the hot hydrogen exhaust from the engine with a water spray before entering a particle filter. The exhaust then passed through a series of heat exchangers and water separators to help remove water from the exhaust and further reduce the exhaust temperatures. The exhaust was next prepared for the charcoal trap by passing through a dryer and effluent cooler to bring exhaust temperatures close to liquid nitrogen. At those low temperatures, most of the noble gases (e.g., Xe and Kr made from fission products) get captured in the charcoal trap. The filtered hydrogen is finally passed through a flare stack and released to the air. The concept was overall successful but did show a La plating on some surfaces and had multiple recommendations for improvement. The most recent detailed study on the NTP scrubber concept was performed by the ARES Corporation in 2006. The concept is based on a 50,000 lbf thrust engine (approximately 1 GW) with a maximum burn time of 1 hour. The concept utilized lessons learned from NF-1. The strategy breaks down the exhaust into parallel paths to allow flexibility with engine size and mass flow of exhaust. Similar to NF-1, the exhaust is slowed down, cooled, filtered of particulates, filtered of noble gases, and then the clean hydrogen is flared to open air. Another concept proposed by Steve Howe (currently Director of the Center for Space Nuclear Research) to simplify the NTP exhaust filtering is to run the hydrogen exhaust into boreholes underground to filter the exhaust. The two borehole site locations proposed are at the NTS and at the Idaho National Laboratory (INL). At NTS, the boreholes are 8' diameter and 1200' deep. The permeability of hydrogen through the soil and its buoyancy will allow it to rise up through the soil and allow the filtering of noble gases and radioactive particulates. The exhaust needs to be cooled to 600C before entering the borehole to avoid soil glazing. Preliminary analysis shows a small buildup of back pressure with time which depends on permeability. Noble gases entering the borehole walls deep can take a long time before reaching the surface. Other factors affecting permeability include borehole pressure, water saturation, and turbulence. Also, a possible need to pump out contaminated water collected at the bottom of the borehole. At INL, the borehole concept is slightly different. The underground borehole has openings to the soil at special depths which have impermeable interbeds above the water table and below the surface to allow the exhaust to travel horizontal between the impermeable layers. Preliminary results indicate better permeability than at NTS. The last option is total containment of the exhaust during the test run. The concept involves slowing down the flow to subsonic in a water cooled diffuser. The hydrogen is burned off in an oxygen rich afterburner with the only products being steam, oxygen, and some noble gases. A heat exchanger and water spray pulls heat from the steam and lowers the temperature for condensation. The optimum ratio between the two is being investigated, with a goal to minimize the total volume of the water hold tanks. A water tank farm collects the contaminated water. The amount of water produced from burning the hydrogen is approximately 100,000 gallons (not including cooling water) for a 25k lbf engine operating for 50 minutes. Residual gases (e.g., oxygen and some noble gases) can be captured at cryogenic levels with a liquid nitrogen cooled dewar. After a few weeks post-test, the radiation levels can drop to more favorable levels before slowly draining each capture tank and using existing filters. With today's environmental regulations, the NTP exhaust is filtered to meet 10 mrem/year exposure to the general public (at a DOE site) or 100 mrem/year (via NRC when tested elsewhere), when natural background radiation exposure to the general public is 300- 600 mrem per year. The current society feels more comfortable with filtering even lower to as low as reasonably achievable (ALARA).

Gerrish, Harold P., Jr.↗