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At least 19 records

Standoff Detection of Chemical Plumes Using Swept-ECQCL Remote Detection Technology: Results from EMRTC Complex Terrain Dual Tracer Experiment

As part of the Complex Terrain Dual Tracer Experiments performed in support of the LYNM program, a swept-wavelength external cavity quantum cascade laser (swept-ECQCL) remote detection system was deployed to measure chemical plume propagation with high temporal resolution. The swept-ECQCL remote detection technology was initially developed at PNNL, and is now under further development at Opticslah, LLC under SBIR funding from DOE (DOE SBIR Phase I Project DE-SC0019855, Remote Detection Technologies, Program Manager Chris Ramos). The swept-ECQCL technology provides a single-frequency infrared laser source which is rapidly scanned over a large wavelength range to measure the infrared absorption of gases, liquids, or solids. Analysis of the measured infrared absorption spectrum is used to detect, identify, and quantify the chemical species which are present. While most previous laser-based techniques used small wavelength tuning ranges to measure only a few isolated spectral lines of a few species, the swept-ECQCL provides the large tuning range needed to measure multiple species simultaneously, and to detect broad absorption features from large molecules or condensed phase materials. In addition, the swept-ECQCL systems have high enough spectral resolution and sensitivity to measure narrow lines of small molecules and determine isotope ratios. The remote detection system for gas plumes is based on the swept-ECQCL technology, and consists of a swept-ECQCL source, infrared detector, control electronics, and beam transmitting and alignment optics. The remote detection system directs the infrared output of the swept-ECQCL to a target retro reflector typically located at ~10-10,000 m distance. The swept-ECQCL wavelength is varied continuously over a large wavelength range (>1000 nm) at rates up to 1000 Hz. The swept ECQCL light reflected from the remote target is collected and focused onto an infrared photodetector. By measuring the detector signal continuously as the swept-ECQCL wavelength is varied, a time-series of absorption spectra are measured for the gases along the beam line of-sight. Based on analysis and fitting of the measured absorption spectra, the time-dependent chemical concentrations of species are determined. Multiple species and mixtures can be detected simultaneously, for all species with absorption features above the sensor noise floor. The sensor output is thus a continuous, high-speed record of identified chemicals along with their concentrations and isotope ratios of interest. The high-speed operation enables low-noise operation in conditions of atmospheric turbulence and allows tracking of fluctuating concentrations in transient chemical plumes as needed for reliable remote detection applications. All components operate with minimal cooling requirements and no cryogens are needed. In addition, the output infrared light is invisible with an intensity below the maximum permissible exposure (MPE) threshold of 100 mW/cm2 for these infrared wavelengths and thus eye safe. The measurement concept for plume detection using the swept-ECQCL remote detection system is as follows. The ECQCL beam is directed toward a remote retro-reflector, which reflects the beam back to the ECQCL system where it is focused onto an infrared photodetector. The line-of-sight from the ECQCL system to the retro-reflector defines the measurement path. The detected infrared signal is recorded continuously and detects the absorption of molecular species along the measurement path. Before a plume release, the system measures absorption from atmospheric constituents, which in this LWIR band consist primarily of lines from H 2 O and CO 2 , with additional weaker absorption from N 2 O, NH 3 , and O 3 possibly contributing. The system then measures any changes in absorption due to the tracer compounds when they enter the measurement path. The shape of absorption features is used to distinguish and identify the different tracer compounds, and the strength of the absorption is used to determine the path-integrated concentration – also called the column density.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Remote detectability from entanglement bootstrap I: Kirby’s torus trick

Remote detectability is often taken as a physical assumption in the study of topologically ordered systems, and it is a central axiom of mathematical frameworks of topological quantum field theories. We show under the entanglement bootstrap approach that remote detectability is a necessary property; that is, we derive it as a theorem. Starting from a single wave function on a topologically-trivial region satisfying the entanglement bootstrap axioms, we can construct states on closed manifolds. The crucial technique is to immerse the punctured manifold into the topologically trivial region and then heal the puncture. This is analogous to Kirby’s torus trick. We then analyze a special class of such manifolds, which we call pairing manifolds. For each pairing manifold, which pairs two classes of excitations, we identify an analog of the topological S S -matrix. This pairing matrix is unitary, which implies remote detectability between two classes of excitations. These matrices are in general not associated with the mapping class group of the manifold. As a by-product, we can count excitation types (e.g., graph excitations in 3+1d). The pairing phenomenon occurs in many physical contexts, including systems in different dimensions, with or without gapped boundaries. We provide a variety of examples to illustrate its scope.

Shi, Bowen (ORCID:0000000206899964)↗

Remote Detection of Radioactive Materials Using Long Wavelength Infrared Laser Driven Avalanche Breakdown [Slides]

The yearly goals of the "Remote Detection of Radioactive Materials Using Long Wavelength Infrared Laser Driven Avalanche Breakdown" experiment are broken into two parts. Year 1: Perform proof-of-concept scaling experiments for detection of radioactive materials at 10m standoff distance, characterizing avalanche breakdowns with the 9.2μm long pulse beam line and optimizing diagnostics. Years 2-3: Extend technique to 30m detection distance, characterizing the effect of long propagation paths on sensitivity, improving diagnostic sensitivity and resolution, and characterizing the effects of turbulence and aerosols.

61 RADIATION PROTECTION AND DOSIMETRY↗

Atmospheric effects on the laser-driven avalanche-based remote detection of radiation

Here, the effect of realistic atmospheric conditions on mid-IR (λ = 3.9 µm) and long-wave-IR (λ = 10 µm) laser-induced avalanche breakdown for the remote detection of radioactive material is examined experimentally and with propagation simulations. Our short-range in-lab mid-IR laser experiments show a correlation between increasing turbulence level and a reduced number of breakdown sites associated with a reduction in the portion of the focal volume above the breakdown threshold. Simulations of propagation through turbulence are in excellent agreement with these measurements and provide code validation. We then simulate propagation through realistic atmospheric turbulence over a long range (0.1–1 km) in the long-wave-IR regime (λ = 10 µm). The avalanche threshold focal volume is found to be robust even in the presence of strong turbulence, only dropping by ~50% over a propagation length of ~0.6 km. We also experimentally assess the impact of aerosols on avalanche-based detection, finding that, while background counts increase, a useful signal is extractable even at aerosol concentrations 10 5 times greater than what is typically observed in atmospheric conditions. Our results show promise for the long-range detection of radioactive sources under realistic atmospheric conditions.

54 ENVIRONMENTAL SCIENCES↗

Remote detection of radioactive material using a short-pulse CO 2 laser

Detection of radioactive material at distances greater than the radiated particle range is an important goal with applications in areas such as national defense and disaster response. Here, we demonstrate avalanche-breakdown-based remote detection of a 3.6 mCi α-particle source at a standoff distance of 10 m, using 70 ps, long-wave infrared (λ = 9.2 µm) CO 2 laser pulses. This is ∼10 times longer than our previous results using a mid-IR laser. The primary detection method is direct backscatter from microplasmas generated in the laser focal volume. The backscatter signal is amplified as it propagates back through the CO 2 laser chain, enhancing sensitivity by >100 times. Here we also characterize breakdown plasmas with fluorescence imaging, and present a simple model to estimate backscattered signals as a function of the seed density profile in the laser focal volume. All of this is achieved with a relatively long-drive laser focal geometry (f/200) that is readily scalable to >100 m.

43 PARTICLE ACCELERATORS↗

Remote Detection of Uranium Using Self-Focusing Intense Femtosecond Laser Pulses

Optical measurement techniques can address certain important challenges associated with nuclear safety and security. Detection of uranium over long distances presents one such challenge that is difficult to realize with traditional ionizing radiation detection, but may benefit from the use of techniques based on intense femtosecond laser pulses. When a high-power laser pulse propagates in air, it experiences collapse and confinement into filaments over an extended distance even without external focusing. In our experiments, we varied the initial pulse chirp to optimize the emission signal from the laser-produced uranium plasma at an extended distance. While the ablation efficiency of filaments formed by self-focusing is known to be significantly lower when compared to filaments produced by external focusing, we show that filaments formed by self-focusing can still generate luminous spectroscopic signatures of uranium detectable within seconds over a 10-m range. The intensity of uranium emission varies periodically with laser chirp, which is attributed to the interplay among self-focusing, defocusing, and multi-filament fragmentation along the beam propagation axis. Grouping of multi-filaments incident on target is found to be correlated with the uranium emission intensity. The results show promise towards long-range detection, advancing the diagnostics and analytical capabilities in ultrafast laser-based spectroscopy of high-Z elements.

42 ENGINEERING↗

System and method for remote detection and location of gas leaks

A system for monitoring for a gas leak from a gas containing structure is disclosed. The system includes a lens that directs an image of a scene of interest through an optical filter onto a detector. The filter is associated with the lens and the filter has one or more passbands that passes wavelengths which match one or more emission or reflectively wavelengths of the gas being monitored. A detector receives the image after the image passes through the lens and the filter. The detector generates image data representing the scene including the gas containing structure. A processor is configured to process the image data by executing machine executable code stored on a memory. The machine executable code processes the image data to identify turbulence flows in the image data such that turbulence flow indicates a gas leak, and generate and send an alert in response to the identification of a turbulence flow.

O'Neill, Mary D.↗

Remote sensing detection enhancement

Big Data in the area of Remote Sensing has been growing rapidly. Remote sensors are used in surveillance, security, traffic, environmental monitoring, and autonomous sensing. Real-time detection of small moving targets using a remote sensor is an ongoing, challenging problem. Since the object is located far away from the sensor, the object often appears too small. The object’s signal-to-noise-ratio (SNR) is often very low. Occurrences such as camera motion, moving backgrounds (e.g., rustling leaves), low contrast and resolution of foreground objects makes it difficult to segment out the targeted moving objects of interest. Due to the limited appearance of the target, it is tough to obtain the target’s characteristics such as its shape and texture. Without these characteristics, filtering out false detections can be a difficult task. Detecting these targets, would often require the detector to operate under a low detection threshold. However, lowering the detection threshold could lead to an increase of false alarms. In this paper, the author will introduce a new method that improves the probability to detect low SNR objects, while decreasing the number of false alarms as compared to using the traditional baseline detection technique.

47 OTHER INSTRUMENTATION↗

Remote-sensing detectability of airborne Arctic dust

Remote-sensing (RS)-based estimates of Arctic dust are oftentimes overestimated due to a failure in separating out the dust contribution from that of spatially homogeneous clouds or low-altitude cloud-like plumes. A variety of illustrations are given with a particular emphasis on questionable claims of using brightness temperature differences (BTDs) as a signature indicator of Arctic dust transported from mid-latitude deserts or generated by local Arctic sources. While there is little dispute about the presence of both Asian and local dust across the Arctic, the direct RS detectability of airborne dust, as ascribed to satellite (MODIS and AVHRR) measurements of significantly negative brightness temperature differences at 11 and 12 µm (BTD 11–12 ), has been misrepresented in certain cases. While it is difficult to account for all examples of strongly negative BTD 11–12 values in the Arctic, it is unlikely that airborne dust plays a significant role. One much more likely contributor would be water clouds in the Arctic inversion layer. The RS detectability of the impact of Arctic dust (notably due to Arctic dust from local sources) can, however, be of significance. Sustained dust deposition can substantially decrease (visible to shortwave IR) snow and ice reflectance albedo (pan-chromatic reflectance) and the signal measured by satellite sensors. Significantly negative BTD 11–12 values would, however, only represent a limited area near the drainage basin sources according to our event-level case studies. The enhanced ice-nucleating particle (INP) role of local Arctic dust can, for example, induce significant changes in the properties of low-level mixed-phase clouds (cloud optical depth changes <~ 1) that can readily be detected by active and passive RS instruments. It is critical that the distinction between the RS detectability of airborne Arctic dust versus the RS detectability of the impacts of that dust be understood if we are to appropriately parameterize, for example, the radiative forcing influence of dust in this climate-sensitive region.

54 ENVIRONMENTAL SCIENCES↗

Common practices for quantifying methane emissions from plumes detected by remote sensing

This document provides a set of community-accepted practices for quantifying methane emissions based on plumes detected via spectroscopic remote sensing. Its primary goal is to promote consistency in the generation, validation, reporting, and quality assessment of methane emission estimates derived from remote sensing radiances. Developed by subject matter experts with deep experience across all stages of the measurement process, this guidance reflects a critical evaluation of current methodologies and highlights key practices needed to produce reliable, interoperable, and traceable products. The focus is specifically on methane emissions quantified from distinct plumes originating from localized sources, rather than diffuse emissions spread over large regions, which are beyond the scope of this work. This document is intended to serve both data producers and users. For producers, it offers a framework for aligning with field-recognized standards to ensure their outputs meet rigorous quality and transparency criteria. For users, it provides a reference to assess dataset fitness-for-purpose by highlighting essential metadata, assumptions, and methodological choices that underpin emission estimates. By fostering a shared understanding of best practices, this work aims to enhance comparability, confidence, and utility of remotely sensed methane emission products.

54 ENVIRONMENTAL SCIENCES↗

Remote isotope detection and quantification using femtosecond filament-laser ablation molecular isotopic spectrometry

We demonstrate the detection and quantification of isotopes from solid samples remotely at a distance of 36 m. This was accomplished through the combination of femtosecond filaments and laser ablation molecular isotopic spectrometry (F 2 -LAMIS). Isotopically enriched graphite samples with varying 13 C concentration were used and the F 2 -LAMIS emission was measured remotely using a portable spectrometer system. A standardless quantification approach was used to determine the corresponding isotopic ratios. The use of F 2 -LAMIS for the detection and quantification of isotopes at atmospheric pressure without the use of calibration standards opens the possibility to implement this technology for remote sensing of isotopes in field applications

07 ISOTOPE AND RADIATION SOURCES↗

Interactive Rotated Object Detection for Novel Class Detection in Remotely Sensed Imagery

In this paper we propose IRTR-DETR an Interactive and Real-Time Rotated DEtection TRansformer that extends IRTDETR to predict rotated bounding boxes. IRTR-DETR maintains the Human-In-The-Loop (HIL) workflow of IRTDETR but introduces rotation-aware heads for improved detection of objects with arbitrary orientations. Similarly to IRTDETR IRTR-DETR can be trained with a small labeled sample set in an interactive setting but we show that it can also be pretrained on related but not identical data--such as a building damage dataset--before being applied to tasks like identifying buildings under construction. We demonstrate the efficacy of our approach on the publicly available Tiny-DOTA and xBD dataset as well as two study-cases on proprietary datasets of greenhouses and houses under construction ("waffle homes"). Detecting greenhouses is highly relevant in the context of damage assessment while "waffle homes" aid understanding typical floorplans and building codes in different areas both thereby supporting population modeling emergency response and policy planning. Our method outperforms the state of the art in interactive rotated object detection on the Tiny-DOTA dataset by 5.7 percent and improves upon the non interactive RTDETR by 7.85 to 19.39 percent (depending on the number of provided samples) while maintaining its real-time efficiency.

Burges, Marvin [ORNL] (ORCID:0000000312690769)↗