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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records
All sourcesNASA NTRSDOE OSTI
DOE OSTI2017

Rechargeable Aluminum-Ion Batteries Based on an Open-Tunnel Framework

Rechargeable batteries based on an abundant metal such as aluminum with a three-electron transfer per atom are promising for large-scale electrochemical energy storage. Aluminum can be handled in air, thus offering superior safety, easy fabrication, and low cost. But, the development of Al-ion batteries has been challenging due to the difficulties in identifying suitable cathode materials. This study presents the use of a highly open framework Mo 2.5 + y VO 9 + z as a cathode for Al-ion batteries. The open-tunnel oxide allows a facile diffusion of the guest species and provides sufficient redox centers to help redistribute the charge within the local host lattice during the multivalent-ion insertion, thus leading to good rate capability with a specific capacity among the highest reported in the literature for Al-based batteries. Our study also presents the use of Mo 2.5 + y VO 9 + z as a model host to develop a novel ultrafast technique for chemical insertion of Al ions into host structures. The microwave-assisted method employing diethylene glycol and aluminum diacetate (Al(OH)(C 2 H 3 O 2 ) 2 ) can be performed in air in as little as 30 min, which is far superior to the traditional chemical insertion techniques involving moisture-sensitive organometallic reagents. The Al-inserted Al x Mo 2.5 + y VO 9 + z obtained by the microwave-assisted chemical insertion can be used in Al-based rechargeable batteries.

25 ENERGY STORAGE↗
DOE OSTI2018

Ion-Sieving Carbon Nanoshells for Deeply Rechargeable Zn-Based Aqueous Batteries

As an alternative to lithium-ion batteries, Zn-based aqueous batteries feature nonflammable electrolytes, high theoretical energy density, and abundant materials. However, a deeply rechargeable Zn anode in lean electrolyte configuration is still lacking. Different from the solid-to-solid reaction mechanism in lithium-ion batteries, Zn anodes in alkaline electrolytes go through a solid-solute-solid mechanism (Zn-Zn(OH) 4 2- -ZnO), which introduces two problems. First, discharge product ZnO on the surface prevents further reaction of Zn underneath, which leads to low utilization of active material and poor rechargeability. Second, soluble intermediates change Zn anode morphology over cycling. In this work, an ion-sieving carbon nanoshell coated ZnO nanoparticle anode is reported, synthesized in a scalable way with controllable shell thickness, to solve the problems of passivation and dissolution simultaneously. The nanosized ZnO prevents passivation, while microporous carbon shell slows down Zn species dissolution. Under extremely harsh testing conditions (closed cell, lean electrolyte, no ZnO saturation), this Zn anode shows significantly improved performance compared to Zn foil and bare ZnO nanoparticles. The deeply rechargeable Zn anode reported is an important step toward practical high-energy rechargeable aqueous batteries (e.g., Zn-air batteries). And the ion-sieving nanoshell concept demonstrated is potentially beneficial to other electrodes such as sulfur cathode for Li-S batteries.

catalysis (heterogeneous), defects, membrane, carb↗
NASA NTRS2017

Enhanced Groundwater Recharge Rates and Altered Recharge Sensitivity to Climate Variability Through Subsurface Heterogeneity

Our environment is heterogeneous. In hydrological sciences, the heterogeneity of subsurface properties, such as hydraulic conductivities or porosities, exerts an important control on water balance. This notably includes groundwater recharge, which is an important variable for efficient and sustainable groundwater resources management. Current large-scale hydrological models do not adequately consider this subsurface heterogeneity. Here we show that regions with strong subsurface heterogeneity have enhanced present and future recharge rates due to a different sensitivity of recharge to climate variability compared with regions with homogeneous subsurface properties. Our study domain comprises the carbonate rock regions of Europe, Northern Africa, and the Middle East, which cover 25 of the total land area. We compare the simulations of two large-scale hydrological models, one of them accounting for subsurface heterogeneity. Carbonate rock regions strongly exhibit karstification, which is known to produce particularly strong subsurface heterogeneity. Aquifers from these regions contribute up to half of the drinking water supply for some European countries. Our results suggest that water management for these regions cannot rely on most of the presently available projections of groundwater recharge because spatially variable storages and spatial concentration of recharge result in actual recharge rates that are up to four times larger for present conditions and changes up to five times larger for potential future conditions than previously estimated. These differences in recharge rates for strongly heterogeneous regions suggest a need for groundwater management strategies that are adapted to the fast transit of water from the surface to the aquifers.

water resources↗
DOE OSTI2020

Application of the Recharge Estimation Tool (RET) to Prepare Spatially and Temporally Variable Recharge Boundary Conditions for Hanford Site Composite Analysis Vadose Zone Models

This environmental calculation file (ECF) describes the development of a tool for translating recharge estimates into readable input for STOMP© (Subsurface Transport Over Multiple Phases) vadose zone models primarily supporting the vadose zone (VZ) facets of the updated Hanford Site Composite Analysis (CA) and the Hanford Site Cumulative Impact Evaluation (CIE). The recharge estimates are spatiotemporally variable and are produced by the Recharge Evolution Tool (RET) described in Hanford Site-wide Natural Recharge Boundary Condition for Groundwater Models (ECF-HANFORD-15-0019). Outputs from the RET are given in Esri’s™ feature class format with yearly estimates and associated metadata encapsulated in file geodatabase objects. For STOMP models, the translated output is a text file in the format of an input boundary condition card, consistent with STOMP software requirements. The text file contains assimilated spatiotemporal recharge estimates produced by the RET. The tool discussed in this document will be referred to as the “RET2STOMP” tool.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2012

Within-Day Recharge of Plug-In Hybrid Electric Vehicles: Energy Impact of Public Charging Infrastructure

This paper examines the role of public charging infrastructure in increasing the share of driving on electricity that plug-in hybrid electric vehicles might exhibit, thus reducing their gasoline consumption. Vehicle activity data obtained from a global positioning system tracked household travel survey in Austin, Texas, is used to estimate gasoline and electricity consumptions of plug-in hybrid electric vehicles. Drivers within-day recharging behavior, constrained by travel activities and public charger availability, is modeled. It is found that public charging offers greater fuel savings for hybrid electric vehicles s equipped with smaller batteries, by encouraging within-day recharge, and providing an extensive public charging service is expected to reduce plug-in hybrid electric vehicles gasoline consumption by more than 30% and energy cost by 10%, compared to the scenario of home charging only.

Dong, Jing↗
DOE OSTI2019

Rechargeable-Liquid Fuel Cells with a Novel Recharging Method: Exploratory Results with IPA and V II /V III Solutions

Rechargeable-liquid fuel cells (RLFCs) have the potential to be utilized in a wide variety of applications, if the performance of RLFCs can be substantially improved. Two of the major historical barriers have been the relatively poor performance of RLFCs compared to conventional polymer electrolyte fuel cells operating on hydrogen and the irreversibility of the oxygen electrode. This work demonstrates a new recharging concept and improved liquid-electrode designs, which help address both of these issues. These two concepts are demonstrated using two different types of rechargeable liquids: 1) an alcohol (isopropanol) that is reversibility dehydrogenated to the corresponding ketone (acetone), and 2) a flow-battery vanadium electrolyte (V II /V III dissolved in H 2 SO 4 ). The liquid electrodes utilize interdigitated flow fields, which enable relatively good power densities for a RLFC during discharge with air: 0.14 W/cm 2 at 0.6 V with 2 M IPA and 0.42 W/cm 2 at 0.7 V with 1.5 M V II /V III . It is also shown that the liquids can be efficiently recharged using the same cell that was used for the discharge, by supplying hydrogen to the gas electrode to generate protons via the hydrogen-oxidation reaction instead of splitting water, which requires a different catalyst or a bidirectional catalyst.

36 MATERIALS SCIENCE↗
DOE OSTI2016

A Rechargeable Al/S Battery with an Ionic‐Liquid Electrolyte

Abstract Aluminum metal is a promising anode material for next generation rechargeable batteries owing to its abundance, potentially dendrite‐free deposition, and high capacity. The rechargeable aluminum/sulfur (Al/S) battery is of great interest owing to its high energy density (1340 Wh kg −1 ) and low cost. However, Al/S chemistry suffers poor reversibility owing to the difficulty of oxidizing AlS x . Herein, we demonstrate the first reversible Al/S battery in ionic‐liquid electrolyte with an activated carbon cloth/sulfur composite cathode. Electrochemical, spectroscopic, and microscopic results suggest that sulfur undergoes a solid‐state conversion reaction in the electrolyte. Kinetics analysis identifies that the slow solid‐state sulfur conversion reaction causes large voltage hysteresis and limits the energy efficiency of the system.

Gao, Tao↗