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At least 19 records

Sustainable and Inexpensive Polydimethylsiloxane Sponges for Daytime Radiative Cooling

Radiative cooling is an emerging cooling technology that can passively release heat to the environment. To obtain a subambient cooling effect during the daytime, chemically engineered structural materials are widely explored to simultaneously reject sunlight and preserve strong thermal emission. However, many previously reported fabrication processes involve hazardous chemicals, which can hinder a material’s ability to be mass produced. In order to eliminate the hazardous chemicals used in the fabrication of previous works, this article reports a white polydimethylsiloxane (PDMS) sponge fabricated by a sustainable process using microsugar templates. By substituting the chemicals for sugar, the manufacturing procedure produces zero toxic waste and can also be endlessly recycled via methods widely used in the sugar industry. The obtained porous PDMS exhibits strong visible scattering and thermal emission, resulting in an efficient temperature reduction of 4.6 °C and cooling power of 43 W m –2 under direct solar irradiation. In addition, due to the air-filled voids within the PDMS sponge, its thermal conductivity remains low at 0.06 W (m K) –1 . This unique combination of radiative cooling and thermal insulation properties can efficiently suppress the heat exchange with the solar-heated rooftop or the environment, representing a promising future for new energy-efficient building envelope material.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Challenges and Optimization of Mu2e Proton Target Design with Radiative Cooling

Mu2e, the Muon-to-Electron Conversion Experiment, aims to identify physics beyond the Standard Model, namely, the conversion of muons to electrons without the emission of neutrinos. The muons are produced from pions generated in a production target when it is hit by an 8 GeV proton beam from the Fermilab Booster/Main Injector. The proton target design space is strongly constrained by a one-year operating lifetime and the need for radiative cooling in a vacuum environment. Uncertainties in the lifetime of the existing baseline design – a monolithic, segmented tungsten target – are large, particularly due to unknown impacts of radiation damage at the very high proton fluences expected in the experiment. We have begun evaluation of a new design utilizing Inconel 718 over the WL10 used in the existing target design. As a result, the structural design of the target has evolved significantly. This evolution focuses on lowering the target temperature, minimizing obstruction to muons, increasing structural stability, maximizing fatigue lifetime, simplifying the fabrication process, and more. The thermal management, structural stability and fatigue lifetime are emphasized here. These optimizations have led to a promising new target design for the Mu2e experiment.

Liu, Z. [Fermilab]↗

Terrestrial radiative cooling: Using the cold universe as a renewable and sustainable energy source

Photonic materials designed at wavelength scales have enabled a range of emerging energy technologies, from solid-state lighting to efficient photovoltaics that have transformed global energy landscapes. Daytime passive radiative cooling materials shed heat from the ground to the cold universe by taking advantage of the terrestrial thermal radiation that is as large as the renewable solar energy. Newly developed photonic materials permit subambient cooling under direct sunshine, and their applications are expanding rapidly enabled by scalable manufacturing. We review here the recent advancement of daytime subambient radiative cooling materials, which allow energy-efficient cooling and are paving the way toward technologies that harvest the coldness from the universe as a new renewable energy source.

Science & Technology - Other Topics↗

Enhanced Cloud Top Longwave Radiative Cooling Due To the Effect of Horizontal Radiative Transfer in the Stratocumulus to Trade Cumulus Transition Regime

Abstract Recent studies develop the SPeedy Algorithm for Radiative TrAnsfer through CloUd Sides (SPARTACUS) to handle the influence of horizontal RT on vertical radiative fluxes within an atmospheric column. The present study applies SPARTACUS to large eddy simulation (LES)‐generated cloud fields across the stratocumulus to trade cumulus transition (STCT) regime with coarse and fine vertical resolutions. The results show that, as the vertical resolution increases, radiation simulations show increasingly stronger cloud‐top longwave (LW) radiative cooling. Consequently, the sharp radiative heating gradient across the cloud layer in the LES‐like resolution simulations cannot be resolved with the coarse resolution simulations. Including the horizontal RT typically enhances cloud LW radiative cooling rate by less than 10% for all the cloud fields but more significantly in the cloud fields during the STCT. The enhanced cloud LW radiative cooling also occurs in the lower cloud layer in the decoupled cumulus cloud regime.

Geology↗

Coating to cool a surface by passive radiative cooling

Disclosed herein in is a radiative cooling formulation comprising a first component with >55% reflectance in a wavelengths range of 0.3 to 2.5 microns, a second component with >0.85 peak thermal emissivity in a window range of 4 to 35 microns, and a third component to mechanically bind together a mixture of the first and second components.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Coating to cool a surface by passive radiative cooling

Disclosed herein in is a radiative cooling formulation including a first component with >55% reflectance in a wavelengths range of 0.3 to 2.5 microns, a second component with a first thermal emissivity peak value greater than 0.85 at a first wavelength in a range of 8 to 13 microns (μm), and a third component to mechanically bind together a mixture of the first component and second component.

Van Overmeere, Quentin↗

Effective properties of semitransparent radiative cooling materials with spectrally variable properties

Radiative cooling is a promising solid-state, non-vapor-compression technology for passive refrigeration and air conditioning. Although this phenomenon occurs naturally, achieving a significant amount of cooling to make it a technically and economically viable technology requires highly engineered, spectrally selective radiative surfaces. These characteristics make radiative cooling difficult to estimate, particularly when it is integrated with other systems such as photovoltaic panels or building envelopes. The complexity further increases when the substrate also participates in the radiative cooling (along with the radiative coating). Energy estimation is becoming increasingly critical because of the recent focus on the semitransparent radiative coatings that transmit a variety of colors to enhance the aesthetic appeal of the system. In this work, we propose an iterative method to calculate the effective radiative properties, which provides the same net radiative cooling that would be observed using the spectral properties at both the coating and substrate surfaces. Compared to traditional methods that rely on either computationally expensive full spectral analysis or methods for averaging each radiative surface parameter locally, our proposed method focuses on calculating effective properties that provide the same the net cooling effect as a full spectral analysis by accounting the emissivity, absorptivity, and transmissivity collectively, thereby providing an overall estimation error of less than 0.2%. We believe that this study will be beneficial to the engineering communities that employ complex simulation codes and require lumped solar and thermal radiation related parameters.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Eco-friendly passive radiative cooling using recycled packaging plastics

Passive daytime radiative cooling, requiring zero external energy consumption, is a promising cooling strategy achieved by simultaneously reflecting solar irradiance and thermally radiating heat into the cold outer space (~3 K) through the atmospheric transparency window. However, current materials for passive radiative cooling face huge challenges, such as complicated fabrication approaches, expensive raw materials, and environmental requirements for practical applications. In line with the urgent need for plastic recycling to curb global environmental pollution, the recycled plastics are used to fabricate a passive radiative cooling material. Herein, the foam-paper composite (FPC) with excellent self-cooling capability is fabricated by a simple crushing-and-mixing procedure using recycled polystyrene (PS) foam and printer paper. The superhydrophobic PS foam particles not only protect the FPC from water damage for field applications but also reinforce its solar reflectivity via their porous structure. The cellulose fibers in printer paper can efficiently emit infrared thermal radiation into the cold outer space and bond dispersed PS foam particles together, further increasing its mechanical strength. The combination of highly diffusely reflective PS foam particles and fiber-based printer paper results in a reflectivity of 96% in the solar spectrum, a sub-ambient cooling performance of 8.4 degrees C, and a maximum radiative cooling power of 90 W/m2 during a 24-h cycle. Meanwhile, the FPC with high humidity can maintain its high solar reflectivity, which promotes its application in humid subtropical areas. Further, the low material cost and ease of fabrication will provide a path for effective daytime radiative cooling, especially in less developed areas.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Radiative cooling structures and systems

Polymer-based selective radiative cooling structures are provided which include a selectively emissive layer of a polymer or a polymer matrix composite material. Exemplary selective radiative cooling structures are in the form of a sheet, film or coating. Also provided are methods for removing heat from a body by selective thermal radiation using polymer-based selective radiative cooling structures, and a cold collection system comprising a plurality of the polymer-based selective radiative cooling structures.

Yang, Ronggui↗

Radiative cooling structures and systems

Polymer-based selective radiative cooling structures are provided which include a selectively emissive layer of a polymer or a polymer matrix composite material. Exemplary selective radiative cooling structures are in the form of a sheet, film or coating. Also provided are methods for removing heat from a body by selective thermal radiation using polymer-based selective radiative cooling structures.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Systems and methods for radiative cooling and heating

Systems and methods for radiative cooling and heating are provided. For example, systems for radiative cooling can include a top layer including one or more polymers, where the top layer has high emissivity in at least a portion of the thermal spectrum and an electromagnetic extinction coefficient of approximately zero, absorptivity of approximately zero, and high transmittance in at least a portion of the solar spectrum, and further include a reflective layer including one or more metals, where the reflective layer has high reflectivity in at least a portion of the solar spectrum.

Yu, Nanfang↗

Systems and methods for radiative cooling and heating

Systems and methods for radiative cooling and heating are provided. For example, systems for radiative cooling can include a top layer including one or more polymers, where the top layer has high emissivity in at least a portion of the thermal spectrum and an electromagnetic extinction coefficient of approximately zero, absorptivity of approximately zero, and high transmittance in at least a portion of the solar spectrum, and further include a reflective layer including one or more metals, where the reflective layer has high reflectivity in at least a portion of the solar spectrum.

Yu, Nanfang↗

Concentrated radiative cooling and its constraint from reciprocity

Concentrated radiative cooling, an analogous concept of the concentrated solar power technology, has the potential of amplifying both the cooling power and the temperature reduction. However, concentrators have not yet been systematically optimized. Moreover, a widely used theoretical approach to analyze such systems has neglected a fundamental constraint from reciprocity, which can lead to an overestimate of cooling performance and unclarified limits of amplification factors. Here we develop a theoretical framework addressing these shortcomings. Modeling suggests the optimized shape and geometric dimensions of concentrators, as well as the limiting cooling power and temperature reduction. Using an electroplated Al 2 O 3 emitter and an optimized conical concentrator, we experimentally amplify the nighttime radiative cooling by 26%.

Dong, Minghao↗

Radiative cooling and thermoregulation in the earth’s glow

Efficient passive radiative cooling of buildings requires an unimpeded view of the sky. However, vertical facades of buildings mostly see terrestrial features that become broadband-radiative heat sources in the summer and heat sinks in the winter. The resulting summertime terrestrial heat gain by buildings negates or overwhelms their narrowband longwave infrared (LWIR) radiative cooling to space, while the wintertime terrestrial heat loss causes overcooling. We show that selective LWIR emitters on vertical building facades can exploit the differential transmittance of the atmosphere toward the sky and between terrestrial objects to achieve higher summertime cooling and wintertime heating than conventionally used broadband emitters. The impact of this novel and passive thermoregulation is comparable to that of painting dark roofs white and is achievable with both novel and commonplace materials. Our findings represent new and remarkable opportunities for materials design and untapped thermoregulation of entities ranging from buildings to human bodies.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Super-Large-Scale Hierarchically Porous Films Based on Self-Assembled Eye-Like Air Pores for High-Performance Daytime Radiative Cooling

Metal-free polymer daytime radiative cooling coatings with hierarchical eye-like air pores are proposed and fabricated with a super-large-scale film-stretching method. The hierarchically porous film (HPF) can be further coated with polymethyl methacrylate (PMMA) micro-hemispheres, forming coated HPF (cHPF), which do not dramatically change the optical or thermal properties. The cHPF is slightly better with a lower solar absorptivity (2.4%) and a higher thermal emissivity over the atmospheric transparency window (90.1%). The low solar absorptivity is due to the strong scattering of the hierarchical eye-like air pores, while the molecular vibrations and the focusing effect of the PMMA micro-hemispheres contribute to the high emissivity. Further, an average mid-day temperature reduction of 7.92 °C is achieved relative to the air temperature, and the average cooling power reaches 116.0 W m -2 , which are much better than the cooling performances of the commercial cooling cushion. During the day, the cHPF-covered simulated building is up to 6.47 and 4.84 °C cooler than the ambient and the white painted counterpart, respectively. The film is durable and resistant to chemical etching, and very promising to use globally, especially in warm and tropical regions.

36 MATERIALS SCIENCE↗

Energy Impact of Radiative Cooling Paints in Warehouses Under Various United States Climates

Although radiative cooling research is widely found in the literature, no comprehensive study has yet been conducted on the impact of novel radiant cooling (>0.91 reflectance) on the energy efficiency of warehouses. Here, in this work, we develop three building models based on a Department of Energy prototype warehouse model using trnsys, representing a typical warehouse with a black roof, a typical warehouse with a white roof, and a warehouse with novel radiative cooling (RC) paint on its roof. These models are run for 15 different cities, each representative of a different ASHRAE climate zone, to better understand the impact of RC in many different climates. It was found that an RC-coated roof in a warehouse could reduce the building's annual heating, ventilation, and air conditioning (HVAC) loads by up to 14.11 kWh/m 2 of the roof area compared to a black roof, resulting in a maximum reduction in energy costs of 0.55 $\$$/m 2 or $\$$2646/year for a large 4835 m 2 warehouse. Similarly, replacing the typical white roof coating with an RC coating could reduce the warehouse's energy consumption by up to 8.17 kWh/ m 2 of roof area, thus reducing energy costs by as much as 0.29 $\$$/m 2 or $\$$1386/year for a 4835 m 2 warehouse. In addition, applying RC paint to an unconditioned warehouse could reduce the building's ASHRAE Standard 55 indoor temperature exceedance by up to 1330 h/year compared to a black roof and up to 532 h/year compared to a white roof.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗