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At least 19 records

A Simple Data-Centric Methodology for Producible Geothermal Well Determinations: Preprint

The Bureau of Land Management (BLM) has traditionally lacked a standardized methodology for determining if a newly drilled geothermal well is "producible," a designation essential for deciding whether a lease should be "held by production." This is a straightforward problem to solve in oil and gas: Demonstrate that a well is economically viable, meaning it produces sufficient oil or gas to exceed direct operating costs and lease-related expenses, such as rentals or minimum royalties. In geothermal, the problem is more complex: Geothermal wells are tightly coupled with the downstream infrastructure - specifically, the power plant, which is often not designed until well after a lease is deemed as "held by production." Although this designation is critical for advancing geothermal power plant development on BLM-managed lands, current geothermal well assessments often rely on ad hoc approaches that can be complex, operator-biased, and heavy in assumptions related to economic viability. To address this, we have developed two complementary methodologies: a minimum power requirement-based approach and a productivity index (PI)-based approach. These methods leverage key flow test data - pressure, temperature, flow rate, and specific enthalpy - to provide reliable and standardized producible well determinations. The minimum power requirement-based approach evaluates wells against specific power output thresholds informed by reservoir experts and the associated temperature requirements. The PI-based approach assesses well productivity using widely accepted reservoir engineering metrics, proposing a threshold of 2.5 kg/s/bar. Both methods are data-driven and grounded in empirical production data from operational geothermal wells, avoiding uncertain economic assumptions while maintaining decision-making accuracy. Wells falling below key performance thresholds (i.e., PI, specific power) are deemed non-producible. These methodologies aim to streamline BLM's decision-making process, reduce nontechnical barriers to geothermal energy adoption, and enable regulatory expansion into states lacking geothermal expertise. Preliminary results indicate clear trends and thresholds in production data that provide actionable insights for evaluating well producibility. Validation using well completion report (WCR) data is ongoing, with promising results demonstrating the potential for these standardized methodologies to impact geothermal development significantly.

15 GEOTHERMAL ENERGY↗

History Matching and Performance Prediction of a Polymer Flood Pilot in Heavy Oil Reservoir on Alaska North Slope

The first-ever polymer flood pilot to enhance heavy oil recovery on Alaska North Slope (ANS) is ongoing. After more than 2.5 years of polymer injection, significant benefit has been observed from the decrease in water cut from 65% to less than 15% in the project producers. The primary objective of this study is to develop a robust history-matched reservoir simulation model capable of predicting future polymer flood performance. In this work, the reservoir simulation model has been developed based on the geological model and available reservoir and fluid data. In particular, four high transmissibility strips were introduced to connect the injector-producer well pairs, simulating short-circuiting flow behavior that can be explained by viscous fingering and reproducing the water cut history. The strip transmissibilities were manually tuned to improve the history matching results during the waterflooding and polymer flooding periods, respectively. It has been found that higher strip transmissibilities match the sharp water cut increase very well in the waterflooding period. Then the strip transmissibilities need to be reduced with time to match the significant water cut reduction. The viscous fingering effect in the reservoir during waterflooding and the restoration of injection conformance during polymer flooding have been effectively represented. Based on the validated simulation model, numerical simulation tests have been conducted to investigate the oil recovery performance under different development strategies, with consideration for sensitivity to polymer parameter uncertainties. The oil recovery factor with polymer flooding can reach about 39% in 30 years, twice as much as forecasted with continued waterflooding. Besides, the updated reservoir model has been successfully employed to forecast polymer utilization, a valuable parameter to evaluate the pilot test’s economic efficiency. All the investigated development strategies indicate polymer utilization lower than 3.5 lbs/bbl in 30 years, which is economically attractive.

Wang, Xindan↗

Technical and Economic Evaluation of the First Ever Polymer Flood Field Pilot to Enhance the Recovery of Heavy Oils on Alaska's North Slope via Machine Assisted History Matching

Polymer flooding has become globally established as a potential enhanced oil recovery method for heavy oils. To determine whether this technology may be useful in developing the substantial heavy oil resources on the Alaska North Slope, a polymer flood field pilot commenced at the Milne Point Unit in August 2018. This study seeks to evaluate the results of the field pilot on a technical and economic basis. A reservoir simulation model is constructed and calibrated to predict the oil recovery performance of the pilot through machine-assisted reservoir simulation techniques. To replicate the early water breakthrough observed during waterflooding, transmissibility contrasts are introduced into the simulation model, forcing viscous fingering effects. In the ensuing polymer flood, these transmissibility contrasts are reduced to replicate the restoration of injection conformance during polymer flooding. Transmissibility contrasts are later reinstated to replicate fracture overextension interpreted in one of the producing wells. The calibrated simulation models produced at each stage of the history matching process are used to forecast oil recovery. These forecasts are used as input for economic analysis, incremental to waterflooding expectations. The simulation forecasts indicate that polymer flooding significantly increases the heavy oil production for this field pilot compared to waterflooding alone, yielding attractive project economics. However, meaningful variations between simulation scenarios demonstrate that a simulation model is only valid for prediction if flow behavior in the reservoir remains consistent with that observed during the history matched period. Critically, this means that a simulation model calibrated for waterflooding may not fully capture the technical and economic benefits of an enhanced oil recovery process such as polymer flooding. Subsequently, the simulation model and economic model are used in conjunction to conduct a sensitivity analysis for polymer flood design parameters, from which recommendations are provided for both the continued operation of the current field pilot and future polymer flood designs. The results demonstrate that a higher polymer concentration can be injected due to the development of fractures in the reservoir. The throughput rate should remain high without exceeding operating constraints. A calculated point-forward polymer utilization parameter demonstrates the decreasing efficiency of the polymer flood at later times in the pattern life. Future projects will benefit from starting polymer injection earlier in the pattern life. A pattern with tighter horizontal well spacing will observe a greater incremental benefit from polymer flooding.

Keith, Cody↗

Utah FORGE: Neubrex Well 16B(78)-32 DAS Data - April, 2024

This dataset comprises Distributed Acoustic Sensing (DAS) data collected from the Utah FORGE monitoring well 16B(78)-32 (the producer well) during hydraulic fracture stimulation operations conducted in April 2024. The data were acquired continuously over the stimulation period at a temporal sampling rate of 10,000 Hz (10 kS/s) and a spatial resolution of approximately 3.35 feet (1.02109 meters). The measurements were captured using a Neubrex NBX-S4100 Time Gated Digital DAS interrogator unit connected to a single-mode fiber optic cable, which was permanently installed within the casing string. All recorded channels correspond to downhole segments of the fiber optic cable, from a measured depth (MD) of 5,369.35 feet to 10,352.11 feet. The DAS data reflect raw acoustic energy generated by physical processes within and surrounding the well during stimulation activities at wells 16A(78)-32 and 16B(78)-32. These data have potential applications in analyzing cross-well strain, far-field strain rates (including microseismic activity), induced seismicity, and seismic imaging. Metadata embedded in the attributes of the HDF5 files include detailed information on the measured depths of the channels, interrogation parameters, and other acquisition details. The dataset also includes a recording of a seminar held on September 19, 2024, where Neubrex's Chief Operating Officer presented insights into the data collection, analysis, and preliminary findings. The raw data files, stored in HDF5 format, are organized chronologically according to the recording intervals from April 9 to April 24, 2024, with each file corresponding to a 12-second recording interval.

15 GEOTHERMAL ENERGY↗

PRIMO - The P&A Project Optimizer

In support of the Methane Emissions Reduction Program (MERP) and under the National Methane Emissions Reduction Initiative (NEMRI), the National Energy Technology Laboratory (NETL) and NETL site support contractors are developing and releasing an open-source decision-support tool (“PRIMO”) to help organizations determine which marginal conventional wells (MCWs) or other low-producing wells make the best candidates for plugging utilizing MERP funds, while also optimizing subsequent plugging and abandonment (P&A) campaigns for both program impact and efficiency. The framework—which is fully customizable—provides three main capabilities: 1. Ranking candidate wells (based on user preferences) 2. Identifying high-impact, high-efficiency P&A project candidates (with transparently computed scores for relevant metrics) 3. Comparing competing P&A projects quantitatively (through transparently computed project impact and efficiency scores) As such, PRIMO is a versatile, fully customizable tool that is meant to support organizations in making data-based, transparent, and defensible well selection and P&A project design decisions. For questions, comments or feedback, please contact primo@netl.doe.gov.

MERP↗

Development of a forced advection sampling technique (FAST) for quantification of methane emissions from orphaned wells

Abstract. Orphaned wells, meaning unplugged and non-producing wells lacking responsible owners, pose a significant and undersampled environmental challenge due to their vast number and unknown associated emissions. We propose, develop and test an alternative method for estimating emissions from orphaned wells using a forced advection sampling technique (FAST) that can overcome many of the limitations in current methods (cost, accuracy, safety). In contrast to existing ambient Gaussian plume methods, our approach uses a fan-generated flow to force advection between the emission source and a point methane (CH4) sensor. The fan flow field is characterized using a colocated sonic anemometer to measure the 3D wind profile generated by the fan. Using time-series measurements of CH4 concentration and wind, a simple estimate of the CH4 emission rate of the source can be inferred. The method was calibrated using outdoor controlled-release experiments and then tested on four orphaned wells in Lufkin, TX, and Osage County, OK. Our results suggest that the FAST method can provide a low-cost, portable, fast and safe alternative to existing methods with reasonable estimates of orphaned well emissions over a range of leak rates below 40 g h−1 and within certain geometric and atmospheric constraints.

Dubey, Mohit L↗

Overview of Hydraulic Fracturing Test Site 2 in the Permian Delaware Basin (HFTS-2)

Here, the Hydraulic Fracturing Test Site 2 (HFTS-2) is a large collaborative field-based R&D program in the Permian Delaware Basin, funded by the US Department of Energy through the National Energy Technology Laboratory (NETL) and the E&P industry, with support from academia. The projects' main objective is to improve the understating of the hydraulic fracturing process through utilization of advanced diagnostics and collection of through-fracture cores to provide undisputable evidence and attributes of the created hydraulic fractures. At the HFTS-2, in excess of $30 million was used to perform hydraulic fracturing research focusing on the Wolfcamp formation at a field site hosted and operated by Occidental. In addition to the research data collected by the project, Occidental provided a significant amount of background data for about a dozen existing wells in the test area as well as access to previously collected core. Additional technical and laboratory support was provided by the program members. Building on learnings and unanswered questions from HFTS-1 in the Permian Midland basin, the HFTS-2 used eight new producing wells and two existing (parent) wells to perform hydraulic fracturing research. Multiple science wells were drilled to sample and characterize the subsurface, including the collection of 540 feet of core in a vertical pilot hole and 948 feet of high-angle through-fracture core. The project installed permanent fiber optic cables in 3 wells to monitor near wellbore signals during fracturing and to collect cross-well strain measurements. Additional advanced diagnostics included a significant formation evaluation program on the vertical whole core, multi array moment tensor inversion capable microseismic survey, multi-well time-lapse geochemistry analysis, analysis of proppant distribution in producing child and slant core well, and others. We will provide an overview of the HFTS-2 project, including list of the consortium members, details of the test site, experiments performed, and technologies tested.

58 GEOSCIENCES↗

New Fracture Diagnostic Tool for Unconventionals: High-Resolution Distributed Strain Sensing via Rayleigh Frequency Shift during Production in Hydraulic Fracture Test 2

Fiber Optic monitoring in unconventional reservoirs has proven to be an invaluable diagnostic tool for assessing both near-wellbore stimulation effectiveness and to help describe the far-field frac geometries created by hydraulic fracture stimulation. Unfortunately, gaining any detailed qualitative and quantitative understanding of the near-wellbore frac geometry or cluster/stage productivity during production via Fiber Optic (FO) has proven to be more difficult, particularly in wells producing liquids. A new FO diagnostic method, Distributed Strain Sensing based on Rayleigh Frequency Shift (DSS-RFS), first demonstrated for oil and gas applications in the Hydraulic Test Site 2 (HFTS2) provides new insights about the characteristics of near-wellbore-region (NWR) during production. DSS-RFS is different from other FO strain measurements because it relies on accurate measurement of frequency shifts of Rayleigh backscattered spectrum obtained by scanning the fiber with a coherent optical time-domain reflectometer with a range of laser frequencies using a tunable-wavelength laser system. Changes in strain are measured with an extremely high spatial resolution of 20 cm and with high signal-to-noise ratios over long distances. In HFTS2, strain changes for the entire wellbore have been measured twice during scheduled shut-in and reopening operations (February 2020 and September 2020). After removing temperature effects, consistent strain changes have been observed at the location of most perforation clusters. These are caused by near wellbore fracture aperture changes due to pressure increases during shut-in within the near-wellbore fracture network. The strain-change patterns from the DSS-RFS during shut-in correlate very well with the location of clusters and allow for the definition of extending intervals with positive strain signals at each cluster and slightly compressing intervals with negative strain signals between the clusters and in the non stimulated intervals. The locations of the measured positive strain peaks also show good correspondence to DAS acoustic intensity measurements acquired during the stimulation. The geometry and magnitude of the strain changes differ significantly between the two tested completion designs in the same well. During shut in and reopening each cluster exhibit its own strain-change / pressure path. In addition, the September 2020 dataset also revealed the existence of small but measurable strain changes as consequence of pressure decline during production. These strain changes also correlate well with the presence of producing clusters, but the strain-rate signals are opposite to that obtained during shut-in and reopening operations. Although Downloaded from http://onepetro.org/URTECONF/proceedings-pdf/21URTC/2-21URTC/D021S031R002/2477551/urtec-2021-5408-ms.pdf/1 by Carol Worster on 28 February 2022 URTeC 5408 2 we are still in the early stages of exploring the potential of this novel FO technique, we believe that the highly detailed information contained in the measurement of strain changes using DSS-RFS during production can significantly improve our understanding of near-wellbore hydraulic fracture characteristics and the relationships between stimulation and production from unconventional oil and gas wells.

04 OIL SHALES AND TAR SANDS↗

Risk matrix for legacy wells within the Area of Review (AoR) of Carbon Capture & Storage (CCS) projects

The success of CCS depends on the capacity, injectivity, and confinement by the storage medium. Thousands of wells drilled over the past century with the intention to find the trapped oil and gas may penetrate the containment seals. These wells may provide leakage pathways for the CO 2 to escape and contaminate the underground sources of drinking water (USDW) or reach the surface in the worst-case scenario. Identifying the risky wells penetrating the containment seals and predicting their current as well as future well integrity is the most challenging task when limited data is available. Here, this paper proposes a unique methodology for risk assessment of the wells penetrating the containment seals based on the proximity of these wells from the proposed injection location, mechanical integrity, and accessibility of these wells over the lifecycle of the CCS project. This helps in identifying the wells which need immediate attention from the wells that need little to no attention. It also highlights the corrective actions necessary for the success of the CCS project as well as help estimate the approximate cost required to perform the corrective actions. This methodology focuses on all wells (producers, injectors, orphan, abandoned, water, stratigraphic, etc) while the majority of the studies found in literature focused on wells with sustained casing pressure (SCP) reports and cement bond logs (CBL). The proposed risk matrix, if applied to future CCS projects across the globe, will uniformly categorize the wells within the Area of Review (AoR).

58 GEOSCIENCES↗

AGR-5/6/7 Fuel Fabrication Report

The U.S. Department of Energy Office of Nuclear Energy (DOE NE) and the Idaho National Laboratory (INL) Advanced Reactor Technologies (ART) Advanced Gas Reactor (AGR) Fuel Development and Qualification program (referred to as AGR Fuel program hereafter) are pursuing qualification of tristructural isotropic (TRISO) coated particle fuel for use in high temperature gas cooled reactors (HTGRs). The AGR Fuel program was established to provide a fuel qualification data set in support of the licensing and operation of an HTGR. BWX Technologies Nuclear Operations Group (BWXT-NOG) was subcontracted to fabricate the fuel for the AGR program. Several investments and innovations were realized in preparation to fabricate fuel for the AGR-5/6/7 irradiation experiments that brought fuel fabrication fully out of the laboratory and into engineering-scale operations. These included: • Increased the kernel fabrication line capacity and uniformity • Upgraded ancillary support equipment and processes for the tristructural isotropic (TRISO) coating furnace • Demonstrated efficient production of the matrix precursor powder by dry jet milling of co mingled components • Demonstrated an engineering-scale method for quick and efficient overcoating TRISO particles with the matrix precursor • Demonstrated an automated, multi cavity compacting system with a volumetric feed system • Demonstrated a combined-cycle thermal treatment furnace These changes increased production rates of some of these processes by an order of magnitude or more while eliminating the use of flammable solvents, multiple grinding and sorting operations, and the weighing out of individual die charges. Three fuel kernel lots were fabricated for production of the fuel for AGR-5/6/7. The initial lot (J52R-16-39316) was certified to fuel specifications but was not used because the kernels had a high fraction of internal fissures that caused an unacceptable fraction of the kernels to fragment when charged to the coating furnace where the TRISO coating would be deposited. Fragmented kernels increased the dispersed uranium in the particles and produced a worrisome fraction of dimpled particles with an elevated probability of in-pile failure. After some efforts to identify the cause of the fissure formation, two additional lots were produced with much lower fissure fractions, J52R-16-69317 and 69318. The latter kernel lot was a backup to the first and was not needed. Multiple kernel batches were composited to form each of the lots so as to simulate a commercial-scale operation where kernel batches would also be composited. Multiple TRISO coating runs were performed and the product characterized so that several could be composited into a TRISO lot. TRISO lot J52R-16-98005 conformed to all fuel specifications except the mean outer pyrocarbon (OPyC) layer thickness was thinner than specified. Furthermore, it was determined that the TRISO lot had a dispersed uranium fraction (DUF) that might result in the compacts not meeting the DUF specification. A review of the role of the OPyC layer and consequences of the DUF by the Technical Coordination Team and INL concluded that the fuel was acceptable for use in the AGR-5/6/7 irradiation experiment. The TRISO particles were overcoated with the matrix precursor that had been produced in a jet-milling operation. The overcoating was performed in equipment originally designed to coat pharmaceuticals. The overcoating process performed well; producing highly spherical and uniform overcoats requiring little upgrading and no recycle or rework. TRISO particles were overcoated with the matrix precursor to achieve nominal volumetric packing fractions (PFs) of TRISO particles of 25% and 40% for the irradiation experiments. The 40% PF compacts occupy the first and fifth test capsule in the test train while the inner three capsules are loaded with 25% PF compacts. The resinated graphite matrix precursor powder was a derivative of the German A3-27 matrix formulation, which differs from previous AGR irradiation campaigns that used an A3-3 formulation. Jet milling of the matrix powder precursor produced a finer mean graphite particle size than the milling operations used for the A3-3 matrix powder precursor. Changes made in the matrix formula and equipment yielded compacts with significantly higher matrix density than was attained in previous AGR irradiation campaigns. The changes in the matrix formulation and the means of milling the powders also complicated resolution of the three fuel compact defect fractions, DUF, exposed kernel fraction (EKF), and the silicon carbide defect fraction (SDF). Characterization data from BWXT-NOG had some anomalous results, so samples of the fuel compacts and overcoated TRISO particles were also analyzed by Oak Ridge National Laboratory (ORNL) to ensure that the defect fractions were accurately characterized.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

An Integrated View of Hydraulic Induced Fracture Geometry in Hydraulic Fracture Test Site 2

Until relatively recently, most of our understanding about the geometry of hydraulically induced fractures in unconventional reservoirs has been inferred by patterns observed via microseismic monitoring. Important information, such as fracture-azimuth, fracture-length, height-growth and other geometric data has been determined from microseismic “event clouds”, which in turn has been used to interpret a stimulated reservoir volume (SRV). It is important to note that relatively limited microseismic results have been acquired in conjunction with other diagnostics and validated in a consistent manner. The Hydraulic Fracture Test Site 2 (HFTS2) in the Permian Delaware Basin provides a unique opportunity to compare the frac geometry interpretations derived from multiple frac diagnostic tools and at multiple scales. The integrated view that emerges from all the frac diagnostic tools is that in HFTS2 the geometries of hydraulically induced fractures are not random and with a highly complex branching architecture. In fact, the fracs are mostly vertical, parallel plana domains, and both vertically and horizontally asymmetrical. The hydraulically induced fractures have a very consistent azimuth with a strike that matches SHmax. At the distance corresponding to the spacing between nearby wells in HFTS2, ~ 660 ft, the pattern of strain interceptions observed from Low Frequency Distributed Acoustic Sensing (LF-DAS) shows far-field dimensions that are consistent with the stage length dimensions at the stimulated well. In general, larger stages with higher number of clusters create larger number of interceptions and wider stimulated intervals than that of shorter stages with the same cluster to cluster spacing and fewer clusters. The hydraulically induced fractures also show a clear tendency to preferentially grow upwards as shown by the microseismic data, by the relative lower number of LF-DAS interceptions in nearby deeper wells and finally by the observed LF-DAS strain patterns in the vertical observation well. In the near field, the geometries of the fracture domains are also consistent. As shown by the distributed strain measurements obtained during production via the monitoring of Rayleigh Frequency Shift (RFS), each cluster has a separate, non-overlapping, frac-zone-domain that are generally centered around the locations of each perforation cluster. Overall, the hydraulically induced fractures in HFTS2 are interpreted as occurring in swarms associated with individual clusters, each with its own unique geometry but with similar predictable geometric and propagation tendencies. The comprehensive frac diagnostic program in HFTS2, the well-pad layout that permits the investigation of the Downloaded from http://onepetro.org/URTECONF/proceedings-pdf/21URTC/1-21URTC/D011S018R003/2477511/urtec-2021-5396-ms.pdf/1 by Carol Worster on 28 February 2022 URTeC 5396 2 impact that nearby producing wells has on frac geometry, together with an innovative Design of Experiment (DofE) that includes sequential-fracing, consistent cluster-to-cluster distances and few single-perforation cluster stages, has allowed us to gain a unique perspective about the geometry of the induced hydraulic fractures on this pad. Finally, the HFTS2 dataset has also provided us with a better understanding of the applicability and limitations of the different diagnostic tools.

58 GEOSCIENCES↗

Oil Recovery Prediction for Polymer Flood Field Test of Heavy Oil on Alaska North Slope Via Machine Assisted Reservoir Simulation

The first ever polymer flood field pilot to enhance the recovery of heavy oils on the Alaska North Slope is ongoing. This study constructs and calibrates a reservoir simulation model to predict the oil recovery performance of the pilot through machine-assisted reservoir simulation techniques. To replicate the early water breakthrough observed during waterflooding, transmissibility contrasts are introduced into the simulation model, forcing viscous fingering effects. In the ensuing polymer flood, these transmissibility contrasts are reduced to replicate the restoration of injection conformance during polymer flooding, as indicated by a significant decrease in water cut. Later, transmissibility contrasts are reinstated to replicate a water surge event observed in one of the producing wells during polymer flooding. This event may represent decreased injection conformance from fracture overextension; its anticipated occurrence in the other production well is included in the final forecast. The definition of polymer retention in the simulator incorporates the tailing effect reported in laboratory studies; this tailing effect is useful to the simultaneous history match of producing water cut and produced polymer concentration. The top 24 best-matched simulation models produced at each stage of the history matching process are used to forecast oil recovery. The final forecast clearly demonstrates that polymer flooding significantly increases the heavy oil production for this field pilot compared to waterflooding alone. This exercise displays that a simulation model is only valid for prediction if flow behavior in the reservoir remains consistent with that observed during the history matched period. Critically, this means that a simulation model calibrated for waterflooding may not fully capture the benefits of an enhanced oil recovery process such as polymer flooding. Therefore, caution is recommended in using basic waterflood simulation models to scope potential enhanced oil recovery projects.

Keith, Cody Douglas↗

Stress-sensitivity of fracture conductivity of Tuscaloosa Marine Shale cores

Production decline from wells producing from shale rocks is typically quite rapid. One possible factor responsible for such decline is loss in fracture conductivity. This is true in the case of the Tuscaloosa Marine shale reservoir. In this work, the stress-dependent fracture conductivity of TMS core samples is investigated using five propped cores under varying stress conditions. In addition, the effects of static rock mechanical properties and rock mineralogy on conductivity decline are investigated. The mineralogy of each core sample was determined by X-ray Diffraction analysis. Fracture conductivity was measured using a Hassler-type pressure core holder with a pressure rating of 15,000 psi (103.42 MPa). Estimated rock mechanical properties showed that shale anisotropy could affect fracture conductivity. The time decline in conductivity revealed two possible decline trends, a) decline from the reduction in induced fracture width, and b) decline from the healing of developed micro-cracks. An exponential decline in fracture conductivity with increasing confinement pressure was observed with an average decline rate constant of 3.15 x 10 -10 mPa -1 . While rock mineralogy did not have any clear relationship with conductivity decline, the effects of rock mechanical properties were only important at 10.34 MPa confinement pressure and above. The observation showed that a high Young's modulus correlate to high conductivity, whereas a high Poisson's ratio correlate to low conductivity. This study provides useful observations for optimizing fracture design to enhance well productivity in the TMS.

02 PETROLEUM↗

Deformation of pores in response to uniaxial and hydrostatic stress cycling in Marcellus Shale: Implications for gas recovery

One of the main challenges during gas production from shale reservoirs is low recovery rate. One contributing factor to this outcome is an insufficient understanding of pore systems, especially pore behaviour following changes in reservoir conditions or resulting from gas production practices. Because the pressure in the producing well can be controlled, understanding the effects of pressure variation on the pore size distribution and methane trapping is necessary to help design optimal conditions to improve the gas recovery rate. This work is the first systematic study of sub-millimeter pore deformation in shale caused by uniaxial and hydrostatic stress up to 100 MPa. Overmature samples from the Middle Devonian Marcellus Shale were analyzed using neutron scattering (SANS and USANS) techniques to interpret the response of nanopores to stress cycling of magnitude and duration compatible with the hydraulic fracturing treatments. Experiments reported here are performed at a series of uniaxial pressures up to 100 MPa and at hydrostatic pressures of deuterated methane 0 and 50 MPa. Since at the original depth of the shale samples’ burial of 2184 m the hydrostatic pressure is approximately 27 MPa and the lithostatic pressure is about 55 MPa, the experimental conditions reasonably well simulate the reservoir pressure regime. Our SANS and USANS results show that different pore sizes are affected by uniaxial stress in different ways. Specifically, in the pore size range from 1 nm to 800 nm, a decrease of pore density with pressure is observed, with the most depleted being mesopores of about 100 nm in diameter. The observed decrease is likely related to deformation of kerogen, followed by a loss of pore nano-volume, as well as methane trapped in the micropores. For pores larger than 5 μm, USANS data suggest that the negative trend is reversed at above 74 MPa, and the number density of large macropores may increase with increased stress even above the original value. The increased number of macropores at high pressure may create new interconnected conduits for gas migration, resulting in a better recovery rate. Another important finding of this study is an irreversible rearrangement of pore size distribution taking place after pressure cycling. Furthermore, this irreversible reorganization of pore size distribution should be taken into account during management of well production to maximize recovery rate.

03 NATURAL GAS↗

Reservoir-scale model of geologic hydrogen production from serpentinization: Cyclic injection in a dual-permeability fracture-matrix system

Geologic hydrogen (GeoH 2 ) from serpentinization is a promising low-carbon resource, but its reservoir-scale behavior remains poorly understood. We develop a dual-permeability reactive transport model for an injector–producer well pair in ultramafic rock that couples multiphase flow, heat transfer, geochemistry, and porosity–permeability evolution. Here, the model is calibrated to olivine flow-through experiments and upscaled to two-year long simulations with continuous injection and cyclic injection with shut-in-to-injection ratios (SIR = 1, 0.5, 0.1). Olivine reacts along high-flux pathways to form lizardite and magnetite, increasing pH; H 2 (aq) and H 2 (g) peak early and then decline as exsolution and advective export outpace local generation. Continuous injection yields the highest cumulative H 2 but the lowest water-use efficiency (1.138 x 10 –6 mol/kgw). Cyclic injection increases this ratio to 1.35 x 10 –6 , 1.377 x 10 –6 , and 1.182 x 10 –6 mol/kgw for SIR = 1, 0.5, and 0.1, respectively; SIR = 0.5 provides a ~20% improvement over continuous injection and the best compromise for pilot design.

08 HYDROGEN↗

Environmental impact of solution pH on the formation and migration of iron colloids in deep subsurface energy systems

Deep subsurface stimulation processes often promote fluid-rock interactions that can lead to the formation of small colloidal particles that are suspected to migrate through the rock matrix, partially or fully clog pores and microfractures, and promote the mobilization of contaminants. Thus, the goal of this work is to understand the geochemical changes of the host rock in response to reservoir stimulation that promote the formation and migration of colloids. Two different carbonate-rich shales were exposed to different solution pHs (pH = 2 and 7). In this study, iron and other mineral transformations at the shale-fluid interface were first characterized by synchrotron-based XRF mapping. Then, colloids that were able to migrate from the shale into the bulk fluid were characterized by synchrotron-based extended X-ray absorption structure (EXAFS), scanning electron microscopy (SEM), and single-particle inductively coupled plasma time-of-flight mass spectrometry (sp-icpTOF-MS). When exposed to the pH = 2 solution, extensive mineral dissolution and secondary precipitation was observed; iron-(oxyhydr)oxide colloids colocated with silicates were observed by SEM at the fluid-shale interfaces, and the mobilization of chromium and nickel with these iron colloids into the bulk fluid was detected by sp-icpTOF-MS. Iron EXAFS spectra of the solution at the shale-fluid interface suggests the rapid (within minutes) formation of ferrihydrite-like nanoparticles. Thus, we demonstrate that the pH neutralization promotes the mobilization of existing silicate minerals and the rapid formation of new iron colloids. These Fe colloids have the potential to migrate through the shale matrix and mobilize other heavy metals (such as Cr and Ni, in this study) and impacting groundwater quality, as well produced waters from these hydraulic fracturing operations.

54 ENVIRONMENTAL SCIENCES↗

3D velocity map imaging of electrons with TPX3CAM

In this report we demonstrate three-dimensional velocity map imaging of low energy electrons using a TPX3CAM, where the three-dimensional momentum information [$p_x, p_y, p_z$] is encoded in position and timing [x, y, t] of hits on the camera sensor. We make use of the camera sensor for the [x, y] information and a constant fraction discriminator and fast time to digital converter in the camera for the time information. We illustrate the capabilities of our apparatus by presenting above threshold ionization measurements of xenon, which produces well defined structures in the momentum resolved photoelectron yield.

79 ASTRONOMY AND ASTROPHYSICS↗

Process Intensification by One-Step, Plasma-Assisted Catalytic Synthesis of Liquid Chemicals from Light Hydrocarbons

In this project, we present a plasma-assisted, catalytic process that can handle variations in production rates and gas compositions of producing wells and reliably converts the hydrocarbons to gas phase olefins, high molecular weight alkanes, and liquid chemicals. The low-temperature plasma serves as a reactive chemical environment that activates and converts the light hydrocarbons to these valuable products. We present results from the integration of a catalyst into the low-temperature plasma zone to improve reaction efficiency and product selectivity. We show that the gas composition, bulk gas temperature, and input power of the plasma, with and without catalysts, influence the production rates of liquids from natural gas feeds.

03 NATURAL GAS↗