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Manufacturing Science

The Manufacturing Science area of leadership spans the application of fundamental science research and development activities to understand the critical steps in manufacturing processes for the purposes of control and optimization. Although manufacturing is an applied area of research, fundamental science underpins our knowledge of both traditional and transformational manufacturing processes. For example, casting, welding, and many modern additive manufacturing processes that see wide use are broadly classified as solidification processes, with material transitioning from liquid to solid phases upon cooling from higher temperature. However, our understanding of the detailed physics involved in such processes is incomplete, and solidification remains a grand challenge for materials science. To enable adoption of transformative fabrication processes or to accelerate development of traditional ones, it is necessary to develop a detailed mechanistic understanding spanning multiple scales, starting with atomic building blocks (defects, interfaces, composition) and extending all the way up to macroscale performance in moderate and/or extreme environments.

36 MATERIALS SCIENCE↗

Manufacturing Science

Despite the decline of traditional manufacturing in the United States, the sector is still responsible for around 12% of the total gross domestic product, with 8% of total employment in 2013, and is the most important part of the U.S. economy according to total output. Los Alamos National Laboratory manufacturing capabilities support our national security customers and the core National Nuclear Security Administration (NNSA) mission. These capabilities support developing innovative and cost-effective manufacturing solutions for our applied energy programs in partnership with other national laboratories and industry.

36 MATERIALS SCIENCE↗

Macromolecules & Manufacturing Science

Outline • SRNL Overview • Mission overview • Polymers enabling the mission • R&D Highlights • Polymers in radiation environments • Tooling in shielded cells • Packaging for nuclear material shipments • Polymers supporting tank waste remediation • Ref electrode • Epoxy and polymer grout • Polymers for fusion energy • Deuterium labelling • Polymers for additive manufacturing • Coalescence and blends: experimental and predictive • Process modelling and sorting through big data (peregrine and latticeJ)

Chatham, Camden [Savannah River National Laborator↗

2019 LDRD Annual Report

This summary report provides an overview of all LDRD projects at Argonne that concluded in Fiscal Year 2019. Many projects are funded for multiple years, the initial fiscal year for each project is indicated by the first four digits of the LDRD project number. Focus areas were: Advanced Computing; Biological and Environmental Science Capability Development; Hard X-ray Sciences; Manufacturing Science and Engineering; Materials and Chemistry; National and Global Security; Photon Sciences; Securing Energy and Critical Resources; and, The Universe as Our Laboratory (ULab).

36 MATERIALS SCIENCE↗

Science, Technology and Applications of Metals in Additive Manufacturing

Science, Technology and Applications of Metal Additive Manufacturing provides a holistic picture of metal Additive Manufacturing (AM) that encompasses the science, technology and applications for the use of metal AM. Users will find design aspects, various metal AM technologies commercially available, a focus on merits and demerits, implications for qualification and certification, applications, cost modeling of AM, and future directions. This book serves as an educational guide, providing a holistic picture of metal AM that encompasses science, technology and applications for the real-life use of metal AM.

Dutta, Bhaskar↗

Sigma Division Capability Strategy

Sigma Division maintains a unique manufacturing science capability at Los Alamos National Laboratory that has made substantial contributions to weapons component process development for more than 70 years. This mission requires the ability to handle a range of radiological and hazardous materials, work with a variety of metallic and non-metallic components, and process materials systems with elements spanning hydrogen to uranium. Today, Sigma serves as a national resource for uranium research and development, provides hardware for experimental campaigns, supports production by demonstrating modern fabrication technologies, and conducts manufacturing science research primarily for customers across the nuclear weapons complex, including the Department of Energy, National Nuclear Security Administration, and Office of Defense Programs.

45 MILITARY TECHNOLOGY, WEAPONRY, AND NATIONAL DEF↗

Department of Energy. Jobs and Innovation Accelerator Challenge (JIAC) Program

1.1 NCMS Digital Manufacturing Initiative The people and businesses of Southeast Michigan have long been known for their prowess in the automotive industry, a sector built on the innovation of the assembly line and the rise of mass production as a manufacturing model. Just as the assembly line was the key to a strong manufacturing base a century ago, a digital manufacturing infrastructure is critical to the future of industry. Economic uncertainty has slowed innovation, but access to cutting-edge tools such as high performance modeling, simulation and analysis (MSA) provides a bold path forward, ensuring global competitiveness and transforming our manufacturing processes. Digital manufacturing is, essentially, the virtualization of processes that had been physical. Many larger manufacturers have embraced it, but the majority of small and medium-sized manufacturers (SMMs) have not. The Digital Manufacturing Initiative is a bold, national effort by the National Center for Manufacturing Sciences (NCMS) to put manufacturing innovation on fast forward, and bring the future of industry into the present. SMMs need a broader array of access options, training, support, and guidance. Providing access will supercharge any organization with tomorrow’s tools, as positively disruptive and potential-laden as the assembly line once was. Sustainable success in the State of Michigan requires the development of foundational infrastructure, the exploration of initial inroads with various manufacturers of all sizes, and the initiation of a prototype engagement mechanism applicable for other future regional efforts. To accomplish this NCMS leveraged complimen-tary State and Federal funding opportunities (shown in Figure 1) along with a coupled voice of industry market research study. A brief summary of each opportunity is found in Appendix A. At the heart of the Michigan effort was the development of an access portal (www.doitindigital.com) and the development of partnerships with local large manufacturers (OEMs) who could provide pull to encourage SMMs (current and future suppliers) to participate. Central to this entire effort was the opportunity that this Final Report documents corresponding to the specific tasks associated with the U.S. Department of Energy (DOE) funded component of the InnoState Jobs Innovation Accelerator Challenge (JIAC) Program.

99 GENERAL AND MISCELLANEOUS↗

2018 LDRD Annual Report (Argonne National Laboratory)

Argonne National Laboratory’s Laboratory Directed Research and Development (LDRD) program encourages the development of novel technical concepts, enhances the Laboratory’s research and development (R&D) capabilities, and enables pursuit of strategic laboratory goals. Argonne’s LDRD projects are proposal based and peer reviewed, supporting ideas that require advanced exploration so they can be sufficiently developed to pursue support through normal programmatic channels. Among the aims of the projects supported by the LDRD program are the establishment of engineering proofs of principle, assessment of design feasibility for prospective facilities, development of instrumentation or computational methods or systems, and discoveries in fundamental science and exploratory development. All LDRD projects have demonstrable ties to one or more of the science, energy, environment, and national security missions of the U.S. Department of Energy (DOE) and its National Nuclear Security Administration (NNSA), and many are also relevant to the missions of other federal agencies that sponsor work at Argonne. A natural consequence of the more “applied” type projects is their concurrent relevance to industry. The LDRD program is managed in overarching portfolios, each containing multiple projects each fiscal year. The LDRD Prime portfolio is further divided into strategic focus areas aligned with Argonne’s strategic plan. The largest component of Argonne’s program is LDRD Prime, which emphasizes R&D explicitly aligned with Laboratory major initiatives in support of Argonne’s strategic plan. The choice of Focus Areas under the LDRD Prime component reflects the major initiatives; the state of development of relevant technical fields; the potential value of advancing those fields to DOE/NNSA and the nation; and the compatibility of the fields with existing facilities, capabilities, and staff expertise at Argonne. Focus Areas with projects that ended in FY18 are: Advanced Computing, Biological and Environmental Science Capability Development, Energy Manufacturing Science and Engineering, Hard X-ray Sciences, Materials and Chemistry, Securing Energy and Critical Resources, and The Universe as Our Laboratory (ULab).

99 GENERAL AND MISCELLANEOUS↗

Demonstration and Validation of Additively Manufactured Intensified Device for Enhanced Carbon Capture

In FY 2018 and 2019, ORNL personnel designed, prototyped, characterized, and tested the enhancement of amine-based carbon capture using additively manufactured intensified devices, i.e., devices combining multiple thermodynamic and kinetic processes into one unit operation. State of the art scrubbing technology often employs inter-stage cooling which requires multiple stages of single-purpose unit operations, leading to larger equipment size, higher capital cost, and sometimes less than optimal operating conditions for each piece of equipment. It was proposed that integrating multiple thermodynamic and kinetic operations into one unit could mitigate or negate these drawbacks. Heat and mass transfer studies demonstrated that an additively manufactured intensified device could significantly improve capture efficiency at bench scale. This project is a continuation of FEAA130 and aims at (1) demonstration and validation of enhanced CO 2 capture with 3D printed intensified devices (i.e., mass exchanger packing with internal cooling channels), for low-aqueous-solvent (LAS) based capture at the ORNL-constructed laboratory-scale (4.5-feet tall) column, namely Column A, with built-in cooling and (2) computational scoping on the conceptual design of a flexible and modular larger column, namely Column B, at ORNL for further demonstration of enhanced capture for aqueous solvent. To execute this multi-faceted project scope, an integrated project team from ORNL’s Manufacturing Science Division is tasked with applying capabilities in computational fluid dynamics (CFD), additive manufacturing, and absorber-scale demonstration/validation experiments.

42 ENGINEERING↗

Material Stream Strategy for Lithium and Inorganics (U)

Design Agency Responsibilities: Manufacturing Support to meet Stockpile Stewardship goals for maintaining the nuclear stockpile through experimental and predictive modeling capability. Development and maintenance of Manufacturing Science expertise to assess material specifications and performance boundaries, and their relationship to processing parameters. Production Engineering Evaluations with competence in design requirements, material specifications, and manufacturing controls. Maintenance and enhancement of Aging Science expertise to support Stockpile Stewardship predictive science capability.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Operation, Manufacturing, and Supply Chain of Lithium-ion Batteries for Electric Vehicles

The US Department of Energy (DOE) has a rich history of funding key innovations in batteries through multiple programs, including the Energy Efficiency and Renewable Energy programs sponsored by the Vehicle Technologies Office and Advanced Manufacturing Office. These DOE-sponsored innovations have been critical in lowering the cost of lithium-ion batteries to less than $160/kWh and increasing their energy density to more than 250 Wh/kg, enhancing the nation’s electrification system and achieving higher degrees of decarbonization. These investments continue to be crucial for positioning the United States as the hub for the most cumulative battery R&D programs worldwide. However, major breakthroughs in battery manufacturing are still needed to enable an electrified future evolving to predominantly incorporate rechargeable lithium-ion batteries. This will require a strong battery manufacturing base that will not only enable cutting-edge advancements in materials and manufacturing sciences but will also allow the United States to become a world leader in this fast-growing area. This review aims at supporting DOE’s Advanced Technology Vehicle Manufacturing Loan Program to give technology background and information that can be used to develop the basis for loan topics and evaluate battery applications. Such a program can represent a significant stride toward reinforcing the US position in advanced manufacturing by introducing artificial intelligence, machine learning, and sensing and smart controls to facilitate, expedite, and lead the battery industry by 2030.

25 ENERGY STORAGE↗

Lightweighting Automotive Materials for Increased Fuel Efficiency and Delivering Advanced Modeling and Simulation Capabilities to U.S. Manufacturers

The National Center for Manufacturing Sciences (NCMS) worked with the U.S. Department of Energy (DOE), National Energy Technology Laboratory (NETL), to bring together research and development (R&D) collaborations to develop and accelerate the knowledgebase and infrastructure for lightweighting materials and manufacturing processes for their use in structural and applications in the automotive sector.

33 ADVANCED PROPULSION SYSTEMS↗

MST e-News October 2019

Don Brown (Materials Science in Radiation and Dynamics Extremes, MST-8) has received a 2019 Los Alamos Distinguished Mentor Award. Presented by the Student Programs Advisory Committee, the awards recognize outstanding performance by Lab mentors. Brown was nominated by his current student, Tom Stockman (Finishing Manufacturing Science, Sigma-2), with support from current and previous students, including Nathan Johnson, Nicholas Bachus, and Nicholas Ferreri, and former postdoctoral researchers Maria Strantza and Eloisa Zepeda-Alarcon (all MST-8).

36 MATERIALS SCIENCE↗

Sustainable LED Fluorescent Light Replacement Technology

Ilumisys and the National Center for Manufacturing Sciences (NCMS) partnered on a three-year project awarded by the United States (U.S.) Department of Energy (DOE), to quantify the impacts of LED lamps, incandescent lamps and fluorescent benchmark lamps over a product lifecycle – i.e. to develop a sustainable design and manufacturing strategy that addresses product manufacturing, use, recycling and disposal scenarios for LED-based lighting. Based on the knowledge gained from extensive product tear-down studies of fluorescent and screw-in lighting products, lifecycle assessment tools, and accelerated lifecycle testing protocols, an interactive Sustainable LED Design Guide has been developed to aid architectural and lighting designers and engineers in making design decisions that consider three important environmental impacts (greenhouse gas emissions, energy use and mercury emission) across all phases of the life of an LED lighting product. Critical information developed for the lifecycle analysis and product feature comparisons is the useful life of the lighting product as well as its performance. The Design Guide is available at www.ncms.org, and was developed based on operational and durability testing of a variety of lighting products including power consumption, light output, and useful life of a lamp in order to allow a more realistic comparison of lamp designs. This report describes the main project tasks, results and innovative features of the lifecycle assessment (LCA)-based design tools, and the key considerations driving the sustainable design of LED lighting systems. The Design Guide incorporates the following three novel features for efficiently evaluating LED lighting features in value-chains: Bill-of-Materials (BOM) Builder – Designers may import process data for each component and supply functional data for the product, including power, consumption, lumen output and expected useful life: Environmental Impact Review – Designs are comparable across lifecycle phases, subsystems, and environmental impact category, and can be normalized to a user-defined functional unit: Drill-down Review – These provide an in-depth look at individual lamp designs with the ability to review across subsystem or lifecycle phase.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗