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At least 19 records

The Corrosion of Magnesium and of the Magnesium Aluminum Alloys Containing Manganese

The extensive use of magnesium and its alloys in aircraft has been seriously handicapped by the uncertainties surrounding their resistance to corrosion. This problem has been given intense study by the American Magnesium Corporation and at the request of the Subcommittee on Materials for Aircraft of the National Advisory Committee for Aeronautics this report was prepared on the corrosion of magnesium. The tentative conclusions drawn from the experimental facts of this investigation are as follows: the overvoltage of pure magnesium is quite high. On immersion in salt water the metal corrodes with the liberation of hydrogen until the film of corrosion product lowers the potential to a critical value. When the potential reaches this value it no longer exceeds the theoretical hydrogen potential plus the overvoltage of the metal. Rapid corrosion consequently ceases. When aluminum is added, especially when in large amounts, the overvoltage is decreased and hydrogen plates out at a much lower potential than with pure magnesium. The addition of small amount of manganese raises the overvoltage back to practically that of pure metal, and the film is again negative.

Boyer, J A

Evidence Connecting Mercury's Magnesium Exosphere to Its Magnesium-Rich Surface Terrane

Mercury is surrounded by a tenuous, collisionless exosphere where the surface of the planet is directly exposed to the space environment. As a consequence, impacts and space weathering processes are expected to eject atoms and molecules from the surface into the exosphere, implying a direct link between the exospheric composition and the planet's regolith material. However, observational evidence demonstrating this link has been elusive. Here we report that exospheric magnesium, a species recently discovered and systematically measured by the Mercury Surface, Space ENvironment, GEochemistry, and Ranging mission, is enhanced when observed over a portion of the planet's surface regolith rich in magnesium. These observations confirm a direct link between Mercury's magnesium exosphere and the underlying crustal surface composition, providing strong evidence supporting theoretical arguments that impact vaporization can directly supply material to the exosphere from the regolith of a rocky, airless body.

Mercury

Nondestructive spot test method for magnesium and magnesium alloys

A method for spot test identification of magnesium and various magnesium alloys commonly used in aerospace applications is described. The spot test identification involves color codes obtained when several drops of 3 M hydrochloric acid are placed on the surface to be tested. After approximately thirty seconds, two drops of this reacted acid is transferred to each of two depressions in a spot plate for additions of other chemicals with subsequent color changes indicating magnesium or its alloy.

Wilson, M. L.

Evidence Connecting Mercury's Magnesium Exosphere to its Magnesium-Rich Surface Terrane

Mercury is surrounded by a tenuous, collisionless exosphere where the surface of the planet is directly exposed to the space environment. As a consequence, impacts and space weathering processes are expected to eject atoms and molecules from the surface into the exosphere, implying a direct link between the exospheric composition and the planet's regolith material. However, observational evidence demonstrating this link has been elusive. Here we report that exospheric magnesium, a species recently discovered and systematically measured by the Mercury Surface, Space ENvironment, GEochemistry, and Ranging mission, is enhanced when observed over a portion of the planet's surface regolith rich in magnesium. These observations confirm a direct link between Mercury's magnesium exosphere and the underlying crustal surface composition, providing strong evidence supporting theoretical arguments that impact vaporization can directly supply material to the exosphere from the regolith of a rocky, airless body.

Mercury atmosphere

Evidence Connecting Mercury's Magnesium Exosphere to Its Magnesium‐Rich Surface Terrane

Mercury is surrounded by a tenuous, collisionless exosphere where the surface of the planet is directly exposed to the space environment. As a consequence, impacts and space weathering processes are expected to eject atoms and molecules from the surface into the exosphere, implying a direct link between the exospheric composition and the planet's regolith material. However, observational evidence demonstrating this link has been elusive. Here we report that exospheric magnesium, a species recently discovered and systematically measured by the Mercury Surface, Space ENvironment, GEochemistry, and Ranging mission, is enhanced when observed over a portion of the planet's surface regolith rich in magnesium. These observations confirm a direct link between Mercury's magnesium exosphere and the underlying crustal surface composition, providing strong evidence supporting theoretical arguments that impact vaporization can directly supply material to the exosphere from the regolith of a rocky, airless body.

Aimee W. Merkel

Isotopically pure magnesium isotope-24 is prepared from magnesium-24 oxide

Apparatus is used to prepare isotopically pure magnesium isotope-24, suitable for use in neutron scattering and polarization experiments. The apparatus permits thermal reduction of magnesium-24 oxide with aluminum and calcium oxide, and subsequent vaporization of the product metal in vacuum. It uses a resistance-heated furnace tube and cap assembly.

Chellew, N. R.

High resolution observations of magnesium II 2800 A in Alpha Centauri A - The density of interstellar magnesium II and the stellar chromospheric profiles

The profiles are virtually identical with the solar profiles except for the presence of an absorption feature near line center in the h and k lines of Alpha Centauri A. It is found that this absorption feature can be explained by interstellar absorption of Mg II along the line of sight. The average density of Mg II is found to be 2.75 plus or minus 0.7 x 10 to the -7th/cu cm, in good agreement with the previously determined values in the solar vicinity in the direction of Alpha CMa and Alpha Lyr.

Oegerle, W. R.

Physicochemical action of potassium-magnesium citrate in nephrolithiasis

Effect of potassium-magnesium citrate on urinary biochemistry and crystallization of stone-forming salts was compared with that of potassium citrate at same dose of potassium in five normal subjects and five patients with calcium nephrolithiasis. Compared to the placebo phase, urinary pH rose significantly from 6.06 +/- 0.27 to 6.48 +/- 0.36 (mean +/- SD, p less than 0.0167) during treatment with potassium citrate (50 mEq/day for 7 days) and to 6.68 +/- 0.31 during therapy with potassium-magnesium citrate (containing 49 mEq K, 24.5 mEq Mg, and 73.5 mEq citrate per day). Urinary pH was significantly higher during potassium-magnesium citrate than during potassium citrate therapy. Thus, the amount of undissociated uric acid declined from 118 +/- 61 mg/day during the placebo phase to 68 +/- 54 mg/day during potassium citrate treatment and, more prominently, to 41 +/- 46 mg/day during potassium-magnesium citrate therapy. Urinary magnesium rose significantly from 102 +/- 25 to 146 +/- 37 mg/day during potassium-magnesium citrate therapy but not during potassium citrate therapy. Urinary citrate rose more prominently during potassium-magnesium citrate therapy (to 1027 +/- 478 mg/day from 638 +/- 252 mg/day) than during potassium citrate treatment (to 932 +/- 297 mg/day). Consequently, urinary saturation (activity product) of calcium oxalate declined significantly (from 1.49 x 10(-8) to 1.03 x 10(-8) M2) during potassium-magnesium citrate therapy and marginally (to 1.14 x 10(-8) M2) during potassium citrate therapy.(ABSTRACT TRUNCATED AT 250 WORDS).

Non-NASA Center

Influence of corrosive solutions on microhardness and chemistry of magnesium oxide /001/ surfaces

X-ray photoelectron spectroscopy analyses and hardness experiments were conducted on cleaved magnesium oxide /001/ surfaces. The magnesium oxide bulk crystals were cleaved to specimen size along the /001/ surface, and indentations were made on the cleaved surface in corrosive solutions containing HCl, NaOH, or HNO3 and in water without exposing the specimen to any other environment. The results indicated that chloride (such as MgCl2) and sodium films are formed on the magnesium oxide surface as a result of interactions between an HCl-containing solution and a cleaved magnesium oxide surface. The chloride films soften the magnesium oxide surface. In this case microhardness is strongly influenced by the pH value of the solution. The lower the pH, the lower the microhardness. Sodium films, which are formed on the magnesium oxide surface exposed to an NaOH containing solution, do not soften the magnesium oxide surface.

Ishigaki, H.

Lightweight Heat Pipes Made from Magnesium

Magnesium has shown promise as a lighter-weight alternative to the aluminum alloys now used to make the main structural components of axially grooved heat pipes that contain ammonia as the working fluid. Magnesium heat-pipe structures can be fabricated by conventional processes that include extrusion, machining, welding, and bending. The thermal performances of magnesium heat pipes are the same as those of equal-sized aluminum heat pipes. However, by virtue of the lower mass density of magnesium, the magnesium heat pipes weigh 35 percent less. Conceived for use aboard spacecraft, magnesium heat pipes could also be attractive as heat-transfer devices in terrestrial applications in which minimization of weight is sought: examples include radio-communication equipment and laptop computers.

Rosenfeld, John N.