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The paper describes an internal CW parametric upconverter which uses a lithium iodate crystal and a CW argon laser. The upconversion reported demonstrates a noise equivalent power (NEP) of 5 x 10 to the -14th W/Hz to the 1/2th at 3.39-micron wavelength. Noise properties of the upconverter are outlined.
During an evaluation of the use of iodine as a water disinfectant and the development of methods for measuring various iodine species in water onboard Space Freedom, it became necessary to compute the concentration of the various species based on equilibrium principles alone. Of particular concern was the case when various amounts of iodine, iodide, strong acid, and strong base are added to water. Such solutions can be used to evaluate the performance of various monitoring methods being considered. The authors of this paper present an overview of aqueous iodine chemistry, a set of nonlinear equations which can be used to model the above case, and a computer program for solving this system of equations using the Newton-Raphson method. The program was validated by comparing results over a range of concentrations and pH values with those previously presented by Gottardi for a given pH. Use of this program indicated that there are multiple roots to many cases and selecting an appropriate initial guess is important. Comparison of program results with laboratory results for the case when only iodine is added to water indicates the program gives high pH values for the iodine concentrations normally used for water disinfection. Extending the model to include the effects of iodate formation results in the computer pH values being closer to those observed, but the model with iodate does not agree well for the case in which base is added in addition to iodine to raise the pH. Potential explanations include failure to obtain equilibrium conditions in the lab, inaccuracies in published values for the equilibrium constants, and inadequate model of iodine chemistry and/or the lack of adequate analytical methods for measuring the various iodine species in water.
Electrochemistry of iodine oxidation states from voltammetry of iodine chloride, iodine and iodate at rotated platinum disk and ring disk electrodes
Quantitative determination of nitrogen in titanium nitride involves dissolution of TiN in 10M hydrofluoric acid containing an oxidant. Released nitrogen is determined as ammonia. Best oxidizers are ferric chloride, potassium iodate, and potassium dichromate.
Controllable pulse length Q switched Nd-YAG laser using lithium iodate doubling crystal
An upconverter has been used to convert infrared photons from astronomical sources to higher frequency quanta that were detected with a pulse-counting photomultiplier photometer. It is pointed out that these observations represent the first successful astronomical demonstration of infrared upconversion. Upconversion is carried out in an optically nonlinear medium, which in the upconverter described is a lithium iodate crystal. A 0.6943-micrometer high peak power ruby laser pump was developed for the demonstration.
A new approach to seeing in the dark is described which is based on the principles of nonlinear optics employing a crystal such as lithium iodate. A nonlinear optical device capable of producing photons at higher frequencies from lower-frequency incident light is shown to upconvert infrared light directly into visible light. The major advantages of the infrared upconversion process is that it permits the infrared signal to be detected by photon-counting devices presently available for the visible spectral region, and that it can provide sensitivity to infrared radiation without the need for cryogenic cooling of the detector used. Early works on infrared upconversion are reviewed. The development of applications is discussed as to astronomical spectroscopy and infrared image upconversion involving either angular or positional resolution elements. The demonstration of infrared upconversion in rectangular waveguides of single-crystal GaAs by Anderson et al. (1971) indicates future possibilities in upconversion by the use of integrated optics devices.
Photoinduced polarization is achieved in a lithium iodate single crystal by the simultaneous application of a dc field and illumination from a uv source. The dark depolarization and photodepolarization current decay characteristics of the polarized samples have been studied in detail in this paper.
The possibility of space disposal of iodine waste from nuclear power reactors is investigated. The space transportation system utilized relies upon the space shuttle, a liquid hydrogen/liquid oxygen orbit transfer vehicle, and a solid propellant final stage. The iodine is assumed to be in the form of either an iodide or an iodate, and calculations assume that the final destination is either solar orbit or solar system escape. It is concluded that space disposal of iodine is feasible.
The transverse beam shape of the signal output from a three-frequency parametric upconverter was investigated both theoretically and experimentally. A Green's function approach was used to predict the near- and far-field signal profiles in an upconverter where Poynting vector walkoff is significant. The measured output beam profiles from a lithium iodate-argon intracavity upconverter agreed well with those predicted. In the near field, walkoff caused an elongation of the beam profile. In the far field, walkoff was observed to limit the angular acceptance of the upconversion process.
This review paper on the structure and stability of laminar flames considers such phenomena as heterogeneous mixtures, acoustic instabilities, flame balls and related phenomena, radiation effects, the iodate oxidation of arsenous acid and 'liquid flame fronts', approximate kinetic mechanisms and asymptotic approximations, and tribrachial or triple flames. The topics examined here indicate three themes that may play an important role in laminar flame theory in the coming years: microgravity experiments, kinetic modeling, and turbulence modeling. In the discussion of microgravity experiments it is pointed out that access to drop towers, the Space Shuttle and, in due course, the Space Station Freedom will encourage the development of experiments well designed to isolate the fundamental physics of combustion.