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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records

Hydrogen Storage System Modeling: Public Access, Maintenance, and Enhancements

This presentation summarizes the Fiscal Year 2020 status and accomplishments for the Hydrogen Storage System Modeling project, a collaborative effort to manage, update, and enhance hydrogen storage system models developed under the Hydrogen Storage Engineering Center of Excellence (HSECoE). The project goal is to provide validated modeling tools that will be used by researchers to evaluate the performance of their new materials in engineered systems relative to the DOE technical targets.

AMR↗

Imaging the Phase Evolution of the Li-N-H Hydrogen Storage System

Complex metal hydrides provide high-density hydrogen storage, which is essential for vehicular applications. However, the utility of these materials has been limited by thermodynamic and kinetic barriers present during the dehydrogenation and rehydrogenation processes as new phases form inside parent phases. Better understanding of the mixed-phase mesostructures and their interfaces may assist in improving cyclability. In this work, the evolution of the phases during hydrogenation of lithium nitride and dehydrogenation of lithium amide with lithium hydride are probed with scanning-transmission X-ray microscopy at the nitrogen K edge. With this technique, intriguing core-shell structures were observed in particles of both partially hydrogenated Li 3 N and partially dehydrogenated LiNH 2 + 2 LiH. The potential contributions of both internal hydrogen mobility and interfacial energies on the generation of these structures are discussed.

08 HYDROGEN↗

Gaseous hydrogen storage system with cryogenic supply

A gaseous hydrogen storage and distribution system with a cryogenic supply and a method for the cryogenic conversion of liquid hydrogen into high-pressure gaseous hydrogen are provided. The gaseous hydrogen storage and distribution system includes pressuring liquid hydrogen from a cryogenic tank using a low pressure liquid pump before vaporization within a relatively small vaporizer. The resulting high pressure gaseous hydrogen is transferred to a plurality of storage tanks at ambient temperature according to a desired fill sequence. The high pressure hydrogen gas is subsequently distributed from the storage tanks through a hydrogen fueling dispenser according to a desired dispensing sequence. The present system and method provide improvements in operational safety, eliminates the use of high pressure gas compressor, and minimizes boiling off and ventilation losses at a reduced cost when compared to existing thermal compression storage systems.

Feng, Zhili↗

Hydrogen Storage System Modeling: Public Access, Maintenance, and Enhancements

The hydrogen storage system modeling project aims to develop new and enhance existing material-based hydrogen storage system models and make them accessible to the research community through a public web page. Updating existing storage systems models supports material developers in evaluating the performance of their new materials in mobile and stationary applications relative to the available DOE Technical Targets. Developing new tools helps researchers evaluate the performance of hydrogen storage materials developed under HyMARC activities or other fundamental hydrogen storage materials discovery research. New models will also work for validating alternatives to material-based systems (liquefied & gaseous hydrogen), comparing various mobile and stationary use cases, and expand to include medium-, heavy-duty, and mining vehicles and stationary application(s).

AMR↗

Hydrogen Storage System Cost Analysis (2017-2021) (Final Report)

This final technical report summarizes hydrogen storage system cost analysis results from 2017-2021. Results include onboard hydrogen storage system costs for light-duty vehicles, medium-duty vehicles, heavy-duty vehicles, class 8 long haul trucks, and passenger buses. Multiple storage systems are included, primarily focusing on compressed and cryo-compressed hydrogen in Type 3 and Type 4 storage systems. Additional analysis includes large-scale gaseous and liquid hydrogen storage at refueling stations in tube trailers and Dewars; advanced materials-based storage systems such as metal organic frameworks and metal hydrides; and a baseline setting analysis of compressed natural gas storage systems in support of the Institute for Advanced Composites Manufacturing Initiative (IACMI). Analyses were primarily conducted using a Design for Manufacture and Assembly ® methodology, which is a bottom-up process-based approach to estimating factory costs. Multiple annual production rates are reported to project high-volume costs relevant to mature markets.

08 HYDROGEN↗

Opportunities and data requirements for data-driven prognostics and health management in liquid hydrogen storage systems

During the past decade, Prognostics and Health Management (PHM) has become an important set of tools in various areas of industry and academic reliability engineering. PHM consists of a variety of mathematical and computational methods used to support data-driven decision-making to increase the safety, availability, and reliability of complex engineering systems. In particular, PHM can provide crucial insight into reliability and safety design improvements for developing technologies where historical performance and failure data are limited. This is the case of hydrogen fueling and storage technologies. This work presents a high-level approach for designing data-driven PHM applications for bulk liquid hydrogen (LH 2 ) storage systems for hydrogen fueling stations. This paper addresses core aspects of the design, development, and implementation of data-driven PHM applications that can improve the reliability assessment of hydrogen components. The analysis focuses on the relationship between data availability and diagnostic/prognostic capabilities; potential challenges; and integration schemes for current risk mitigation measures. We identify potential condition-monitoring data sources for key components in an LH 2 storage system, including storage tanks, piping, and pumps. Further, we determine that the short-term goals for the implementation of data-driven models in PHM frameworks in hydrogen systems should focus on developing adequate data collection and analysis strategies, as well as exploring the effect on reliability, safety, and regulations for hydrogen systems.

08 HYDROGEN↗

Experimental Study of Thermal Management and Enhancement of Adsorption-Based Onboard Hydrogen Storage System

Abstract Although hydrogen has one of the highest specific energies, its energy density in terms of volume is very poor compared to liquid fuels. Thus, to achieve attractive energy density for hydrogen, either high-pressure compression or a storage method is needed. For onboard (vehicles) hydrogen storage, up to 700 bars are needed for commercial fuel cell vehicles. This creates extreme requirements for material strength and thus safety concerns. A new metal-organic framework 5 (MOF-5) was selected as the adsorbent for H2 storage, as it provides promising storage capacity and is commercially available. Under the same H2 storage capacity and tank volume, the adsorption system is expected several folds reduction in pressure. Under the current study, a unique thermal management design using Modular Adsorbing Tank Insert (MATI) is paired with conduction-enhanced compressed MOF-5 beds. Compared to bare beds without conduction enhancement, all beds with conduction enhancement using either aluminum pins or expanded natural graphite (ENG) have shown various levels of improvement on bed thermal response, which can potentially help expedite system charge and discharge cycle times for real applications.

Electrochemistry↗

Design Tool for Estimating Adsorbent Hydrogen Storage System Characteristics for Light-Duty Fuel Cell Vehicles

This work combines materials development with hydrogen storage technology advancements to address onboard hydrogen storage challenges in light-duty vehicle applications. These systems are comprised of the vehicle requirements design space, balance of plant requirements, storage system components, and materials engineering culminating in the development of an Adsorbent System Design Tool that serves as a preprocessor to the storage system and vehicle-level models created within the Hydrogen Storage Engineering Center of Excellence. Computational and experimental efforts were integrated to evaluate, design, analyze, and scale potential hydrogen storage systems and their supporting components against the Department of Energy 2020 and Ultimate Technical Targets for Hydrogen Storage Systems for Light Duty Vehicles. Ultimately, the Adsorbent System Design Tool was created to assist material developers in assessing initial design parameters that would be required to estimate the performance of the hydrogen storage system once integrated with the full fuel cell system.

08 HYDROGEN↗

Safety Hazards of Batteries and Hydrogen Storage Systems in Proximity

This report addresses the safety concerns and mitigations for battery failures and their impact on hydrogen storage systems. Through an analysis of failure modes, this report highlights the risks posed by thermal runaway and chemical emissions caused by batteries. Although rare, battery thermal failure events may prompt the opening of the relief valve on the hydrogen tank. Strategies such as battery management systems, thermal management systems, and multiple thermally activated pressure relief devices can mitigate these risks. Potential simulations and experiments to better quantify the unique risks posed by lithium-ion batteries near tanks are suggested. Improving safety standards will enable integration of batteries and hydrogen storage systems in various energy storage technologies.

08 HYDROGEN↗

Hydrogen Storage System Modeling: Public Access, Maintenance, and Enhancements

The overall vision of this project is to provide ownership and support for maintaining existing material-based hydrogen storage systems models. This includes making models accessible to the research community through a public web page and updating and enhancing storage systems models to support material developers in assessing their materials relative to DOE vehicle-level targets. Key elements for FY24: Continue to update and enhance existing models for broader application and user-friendliness. Develop tools to evaluate the performance of hydrogen storage materials developed under HyMARC activities or other fundamental hydrogen storage materials discovery research. Expand the application of current hydrogen storage models beyond light-duty vehicles to include medium-, heavy-duty, and mining vehicles and stationary application(s). Develop models for alternatives, such as LOHCs, to material-based systems (liquefied & gaseous H2) and compare for various mobile and stationary use cases.

ENERGY STORAGE,HYDROGEN↗

Data requirements for improving the Quantitative Risk Assessment of liquid hydrogen storage systems

Quantitative Risk Assessment (QRA) supports the development of risk-informed safety codes and standards which are employed to enable the safe deployment of hydrogen technologies essential to decarbonize the transportation sector. System reliability data is a necessary input for rigorous QRA. Here, the lack of reliability data for bulk liquid hydrogen (LH 2 ) storage systems located on site at fueling stations limits the use of QRAs. In turn, this hinders the ability to develop the necessary safety codes and standards that enable worldwide deployment of these stations. Through a QRA-based analysis of a LH 2 storage system, this work focuses on identifying relevant scenario and probability data currently available and ascertaining future data collection requirements regarding risks specific to liquid hydrogen releases. The work developed consists of the analysis of a general bulk LH 2 storage system design located at a hydrogen fueling station. Failure Mode and Effect Analysis (FMEA) and traditional QRA modeling tools such as Event Sequence Diagrams (ESD) and Fault Tree Analysis (FTA) are employed to identify, rank, and model risk scenarios related to the release of LH 2 . Based on this analysis, scenario and reliability data needs to add LH 2 -related components to QRA are identified with the purpose of improving the future safety and risk assessment of these systems.

08 HYDROGEN↗

Experimental Investigation of a Physisorption-Based Hydrogen Storage System

This study discusses a practical system utilizing the principle of physisorption where hydrogen is weakly bound to the surface of a nanoporous silica aerogel blanket as an alternative to high-pressure and cryogenic hydrogen storage. Three different experiments are conducted to simulate various scenarios of such a storage method: change in pressure and change of scale. Transient responses of the charging and discharging cycles are of particular interest. It is observed that hydrogen uptake can be increased by up to 36-38 % at ambient conditions and 77 K when utilizing the aerogel blankets. Packing density, or the artificial increase of surface per volume, increases storage capacity as it is a mainly surface-driven phenomenon. High-pressure testing up to 50 bar showed benefits of the aerogel addition whereas the maximum uptake improvement was observed for 2 bar with a 105.3 % improvement over an empty vessel at identical conditions corresponding to 6.43 wt%. The scale-up of the system is highly sensitive to the design of the internal cooling design as aerogels are poor thermal conductors reducing the transient response of such systems. Furthermore, the high mass of metal-based pressure vessels further delays the thermal response. This makes the system suitable for day to week-long hydrogen storage but not for peak-shaving or load balancing.

Marcel Otto↗

Liquid hydrogen storage system for heavy duty trucks: Configuration, performance, cost, and safety

In this work, we investigate the potential of liquid hydrogen storage (LH 2 ) on-board Class-8 heavy duty trucks to resolve many of the range, weight, volume, refueling time and cost issues associated with 350 or 700-bar compressed H 2 storage in Type-3 or Type-4 composite tanks. We present and discuss conceptual storage system configurations capable of supplying H 2 to fuel cells at 5-bar with or without on-board LH 2 pumps. Structural aspects of storing LH 2 in double walled, vacuum insulated, and low-pressure Type-1 tanks are investigated. Structural materials and insulation methods are discussed for service at cryogenic temperatures and mitigation of heat leak to prevent LH 2 boiloff. Failure modes of the liner and shell are identified and analyzed using the regulatory codes and detailed finite element (FE) methods. The conceptual systems are subjected to a Failure modes and effects analysis (FMEA) and a safety, codes, and standards (SCS) review to rank failures and identify safety gaps. The results indicate that the conceptual systems can reach 19.6% usable gravimetric capacity, 40.9 g-H 2 /L usable volumetric capacity and $174-183/kg-H 2 cost (2016 USD) when manufactured 100,000 systems annually.

08 HYDROGEN↗