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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS1976

Processing FeB03 glass-ceramics in space

The possibility of preparing FeBO3 glass-ceramic in space is explored. A transparent glass-ceramic of FeBO3, due to its unique properties could be an excellent material for magneto-optic applications which currently utilize high price materials such as single crystals of Ga-YIG. The unique magneto-optic properties of FeBO3 were found to come from glass-ceramic but not from the glass form. It was anticipated and later confirmed that the FeBO3 glass-ceramics could not be prepared on earth. Phase separation and iron valence reduction, were identified as the two terrestrial manufacturing obstacles. Since the phase separation problem could be overcome by space processing, the preparation of FeBO3 glass-ceramic in space appears attractive.

Li, C. T.↗
NASA NTRS1982

Dynamic fatigue of a machinable glass-ceramic

To assess the stress corrosion susceptibility of a machinable glass-ceramic, its dynamic fatigue behavior was investigated by measuring its strength as a function of stress rate. Fracture mechanics techniques were used to analyse the results for the purpose of making lifetime predictions for components of this material. This material was concluded to have only moderate resistance to stress in ambient conditions. The effects of specimen size on strength were assessed for the material used in this study: it was concluded that the Weibull edge-flaw scaling law adequately describes the observed strength-size relationship.

Smyth, K. K.↗
NASA NTRS1983

Dynamic fatigue of a machinable glass-ceramic

To assess the stress-corrosion susceptibility of a machinable glass-ceramic, its dynamic fatigue behavior was investigated by measuring its strength as a function of stress rate. Fracture mechanics techniques were used to analyze the results for the purpose of making lifetime predictions for components of this material. This material was concluded to have only moderate resistance (N = 30) to stress corrosion in ambient conditions. The effects of specimen size on strength were assessed for the material used in this study; it was concluded that the Weibull edge-flaw scaling law adequately describes the observed strength-size relation.

Smyth, K. K.↗
NASA NTRS1972

Exploratory evaluation of ceramics for automobile thermal reactors

An exploratory evaluation of ceramics for automobile thermal reactors was conducted. Potential ceramic materials were evaluated in several reactor designs using both engine dynamometer and vehicle road tests. Silicon carbide contained in a corrugated metal support structure exhibited the best performance lasting over 800 hours in engine dynamometer tests and over 15,000 miles (24,200 km) of vehicle road tests. Reactors containing glass-ceramic components did not perform as well as silicon carbide. But the glass-ceramics still offer good potential for reactor use. The results of this study are considered to be a reasonable demonstration of the potential use of ceramics in thermal reactors.

Stone, P. L.↗
NASA NTRS1974

Design and evaluation of experimental ceramic automobile thermal reactors

The results obtained in an exploratory evaluation of ceramics for automobile thermal reactors are summarized. Candidate ceramic materials were evaluated in several reactor designs by using both engine-dynamometer and vehicle road tests. Silicon carbide contained in a corrugated-metal support structure exhibited the best performance, lasting 1100 hr in engine-dynamometer tests and more than 38,600 km (24000 miles) in vehicle road tests. Although reactors containing glass-ceramic components did not perform as well as those containing silicon carbide, the glass-ceramics still offer good potential for reactor use with improved reactor designs.

Stone, P. L.↗
NASA NTRS1974

Design and evaluation of experimental ceramic automobile thermal reactors

The paper summarizes the results obtained in an exploratory evaluation of ceramics for automobile thermal reactors. Candidate ceramic materials were evaluated in several reactor designs using both engine dynamometer and vehicle road tests. Silicon carbide contained in a corrugated metal support structure exhibited the best performance, lasting 1100 hours in engine dynamometer tests and for more than 38,600 kilimeters (24,000 miles) in vehicle road tests. Although reactors containing glass-ceramic components did not perform as well as silicon carbide, the glass-ceramics still offer good potential for reactor use with improved reactor designs.

Stone, P. L.↗
NASA NTRS1977

Improved ceramic heat exchange material

Improved corrosion resistant ceramic materials that are suitable for use as regenerative heat exchangers for vehicular gas turbines is reported. Two glass-ceramic materials, C-144 and C-145, have superior durability towards sulfuric acid and sodium sulfate compared to lithium aluminosilicate (LAS) Corning heat exchange material 9455. Material C-144 is a leached LAS material whose major crystalline phase is silica keatite plus mullite, and C-145 is a LAS keatite solid solution (S.S.) material. In comparison to material 9455, material C-144 is two orders of magnitude better in dimensional stability to sulfuric acid at 300 C, and one order of magnitude better in stability to sodium sulfate at 1000 C. Material C-145 is initially two times better in stability to sulfuric acid, and about one order of magnitude better in stability to sodium sulfate. Both C-144 and C-145 have less than 300 ppm delta L/L thermal expansion from ambient to 1000 C, and good dimensional stability of less than approximately 100 ppm delta L/L after exposure to 1000 C for 100 hours. The glass-ceramic fabrication process produced a hexagonal honeycomb matrix having an 85% open frontal area, 50 micrometer wall thickness, and less than 5% porosity.

Mccollister, H. L.↗
NASA NTRS1978

Study of iron-borate materials systems processed in space

It was calculated that an FeBO3B2O3 glass-ceramic containing only 1 mole% FeBO3 would be equivalent for magnetooptic application to a YIG crystal of equal thickness. An Fe2O3B2O3 composition containing 2 mole% FeBO3 equivalent (98B) could be converted largely to a dense green, though opaque, FeBO3 glass-ceramic through suitable heat treatments. However, phase separation (and segregation) and Fe+3 reduction could not be entirely avoided with the various procedures that were employed. From light scattering calculations, it was estimated that about 100 A to allow 90% light transmission through a 1 cm thick sample. However, the actual FeBO3 crystallite sizes obtained in 98B were of the order of 1 micron or greater.

Neilson, G. F.↗
NASA NTRS1972

Mechanically and thermally stable maser cavity resonator

New type cavity resonator is designed for hydrogen maser. Resonator consists of three pieces of glass-ceramic material having extremely low thermal coefficient of expansion and provides very stable mechanical tuning.

Vessot, R. F. C.↗
NASA NTRS1972

Research study to determine critical optical/mechanical properties of materials considered for selection as substrates for the primary mirror on a large telescope

An investigation was conducted to evaluate the stability of a specific low expansion glass-ceramic material relative to its use as a large, lightweight mirror substrate for diffraction-limited spaceborne optical applications. These evaluations were made on a segment (0.44 meter diameter by 0.31 meter thick) of a 2 to 3 meter diameter mirror blank. The dimensional stability of this mirror was measured interferometrically before and after lightweighting, as a function of rough machining, etching, thermal environment, and support configuration. A special computer analysis program was used to plot the coefficients corresponding to aberrations with sixfold symmetry (caused by the mirror's self-weight deflection on a three point support). The objective was to enhance the test sensitivity. Results indicate that any such effects due to self-weight deflection are of the order of 0.015 lambda rms. The rms and peak-to-peak figure changes associated with each processing operation are summarized.

Slomba, A. F.↗
NASA NTRS1973

Exploratory development of a glass ceramic automobile thermal reactor

This report summarizes the design, fabrication and test results obtained for glass-ceramic (CER-VIT) automotive thermal reactors. Several reactor designs were evaluated using both engine-dynamometer and vehicle road tests. A maximum reactor life of about 330 hours was achieved in engine-dynamometer tests with peak gas temperatures of about 1065 C (1950 F). Reactor failures were mechanically induced. No evidence of chemical degradation was observed. It was concluded that to be useful for longer times, the CER-VIT parts would require a mounting system that was an improvement over those tested in this program. A reactor employing such a system was designed and fabricated.

Gould, R. E.↗
NASA NTRS1974

The 1974 NASA-ASEE summer faculty fellowship aeronautics and space research program

Research activities by participants in the fellowship program are documented, and include such topics as: (1) multispectral imagery for detecting southern pine beetle infestations; (2) trajectory optimization techniques for low thrust vehicles; (3) concentration characteristics of a fresnel solar strip reflection concentrator; (4) calaboration and reduction of video camera data; (5) fracture mechanics of Cer-Vit glass-ceramic; (6) space shuttle external propellant tank prelaunch heat transfer; (7) holographic interferometric fringes; and (8) atmospheric wind and stress profiles in a two-dimensional internal boundary layer.

Obrien, J. F., Jr.↗
NASA NTRS1975

Fabrication and evaluation of an OSO-1 type baseplate

An OSO-1 type baseplate of a low thermal-expansion glass-ceramic material was evaluated for its dimensional stability after exposure to thermal cycling and mechanical vibration. The results indicate that baseplates of relatively simple design can be successfully cast and machined, although the demonstration article produced deviated somewhat from design specifications. It is likely that baseplates of more sophisticated designs and improved structural efficiency also can be prepared from low thermal expansion material.

Marschall, C. W.↗
NASA NTRS1976

Dimensional stability

The temporal stability of glass and glass-ceramic materials is important to the success of a large diffraction-limited telescope. The results are presented of an experimental study of the dimensional stability of glasses and glass ceramics being considered for substrates of massive diffraction-limited mirrors designed for several years of service in earth orbit. The purpose of the study was to measure the relative change in length of the candidate substrate materials, to the order of 5 parts in 10 to the 8th power, as a function of several years time. The development of monolithic test etalons, the development and improvement of two types of ultra-high precision interferometers, and certain aspects of tests data presently achieved are discussed.

Hocken, R.↗
NASA NTRS1976

Chemical vapor deposition growth

A chemical vapor deposition (CVD) reactor system with a vertical deposition chamber was used for the growth of Si films on glass, glass-ceramic, and polycrystalline ceramic substrates. Silicon vapor was produced by pyrolysis of SiH4 in a H2 or He carrier gas. Preliminary deposition experiments with two of the available glasses were not encouraging. Moderately encouraging results, however, were obtained with fired polycrystalline alumina substrates, which were used for Si deposition at temperatures above 1,000 C. The surfaces of both the substrates and the films were characterized by X-ray diffraction, reflection electron diffraction, scanning electron microscopy optical microscopy, and surface profilometric techniques. Several experiments were conducted to establish baseline performance data for the reactor system, including temperature distributions on the sample pedestal, effects of carrier gas flow rate on temperature and film thickness, and Si film growth rate as a function of temperature.

Ruth, R. P.↗
NASA NTRS1977

Potentially improved glasses from space environment

The benefits of processing glasses in a low-gravity space environment are examined. Containerless processing, the absence of gravity driven convection, and lack of sedimentation are seen as potential advantages. Potential applications include the formation of glass-ceramics with a high content of active elements for ferromagnetic devices, the production of ultrapure chalcogenide glasses for laser windows and IR fiber optics, and improved glass products for use in optical systems and laser fusion targets.

Nichols, R.↗
NASA NTRS1979

Alternate methods of applying diffusants to silicon solar cells

Low-melting phosphate and borate glasses were screen printed on silicon wafers and heated to form n and p junctions. Data on surface appearance, sheet resistance and junction depth are presented. Similar data are reported for vapor phase transport from sintered aluminum metaphosphate and boron-containing glass-ceramic solid sources. Simultaneous diffusion of an N(+) layer with screen-printed glass and a p(+) layer with screen-printed Al alloy paste was attempted. No p(+) back surface field formation was achieved. Some good cells were produced but the heating in an endless-belt furnace caused a large scatter in sheet resistance and junction depth for three separate lots of wafers.

Brock, T. W.↗
NASA NTRS1980

The mechanisms of the SAMS experiment flown on Nimbus 7 with particular reference to the 2 axis scanning mirror

The stratospheric and mesospheric sounder (SAMS) experiment on Nimbus 7 includes a 2 axis scanning mirror and 7 pressure modulator cells. The SAMS experiment is a limb sounding instrument to measure the temperature profile and minor constituents of the atmosphere. The limb scan requires small mirror steps over a 3 deg range, while the scan in azimuth is in larger steps over a 15 deg range. The mirror is plane, 20 cm in diameter, and of zero expansion glass-ceramic. It is supported on two tilt tables, fitted one on the other, with the axes at right angles. The angle of tilt is adjusted by means of recirculating ball screws which are ion plated with lead for lubrication and driven by stepper motors. The seven gas filled cells are each pressure modulated by a 3 cm diameter, 0.3 cm stroke piston which is supported by diaphragm springs and driven electromagnetically at the system's mechanical resonant frequency. The mean pressure of the filling gas, which is the atmospheric constituent being measured, is changed by varying the temperature of a suitable molecular sieve.

Hadley, H.↗