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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records

Synthesis of adriamycin-coupled polyglutaraldehyde microspheres and evaluation of their cytostatic activity

Adriamycin was coupled to polyglutaraldehyde microspheres having an average diameter of 4500 A. The coupled microspheres remained stable during incubation with cells. Full cytostatic activity was observed when the coupled adriamycin was tested with murine or human leukemia and murine sarcoma cell lines. A 10-fold increase in sensitivity was obtained with drug-resistant human leukemia cell lines. Repeated use of the coupled microspheres in the cytostatic assays did not decrease their activity, indicating that these complexes can be recycled. The results suggest that coupled adriamycin sufficiently perturbs the plasma membrane to lead to cytostatic activity. It is proposed that this mode of drug delivery provides multiple and repetitious sites for drug-cell interactions. In addition, the drug-polymer complexes may overcome those forms of resistance that are the result of decreased drug binding at the cell surface.

Tokes, Z. A.

Gas absorption cell photometer for rocket observations of local interstellar helium

A photometer sensitive in the 584-A line of He I, incorporating a helium-gas absorption cell, has been developed. The helium is confined at a pressure of 0.2 torr between thin-metal-foil broad-band ultraviolet filters. The cell contains sufficient helium to absorb 584-A radiation scattered from atmospheric helium. The ratio of fluxes seen with the cell full and empty provides a valuable datum for fitting models of the local interstellar medium, which is independent of solar 584-A flux, interstellar helium density, and photometer sensitivity.-

Freeman, J.

Observations of interstellar helium with a gas absorption cell - Limits on the bulk velocity of the interstellar medium

Results are reported for observations of solar 584-A flux resonantly scattered by the 1s(2)-1s2p transition of neutral interstellar helium. A photometer equipped with a helium gas-absorption cell and flown aboard a sounding rocket to a peak altitude of 185 km was employed to observe the sky in Perseus. The data reduction procedure is described, including subtraction of the terrestrial atmospheric background, calculation of the solar flux, and reduction of the number density of scatters to a function of phase-space parameters of the local interstellar medium. The ratio of 584-A fluxes observed with the gas cell full and empty is computed and compared with numerical models of the interstellar-helium flow through the solar system. The results show that the bulk speed of the distant interstellar medium with respect to the sun is unlikely to be less than 10 to 15 km/s, at the 2-sigma level. Since this value is inconsistent with results obtained from Lyman-alpha observations, it is suggested that either the total ionization rate for helium is variable or present models of the behavior of the local interstellar medium need further refinement.

Freeman, J.

Extreme ultraviolet photometer for observations of helium in interplanetary space

A four-channel photometer sensitive to two solar EUV lines which are resonantly scattered by helium gas was developed for flight on the Apollo-Soyuz Test Project. Two channels observed the 58.4-nm line of He I and used helium gas resonant absorption cells to determine the intensities of the center and wings of that line. The other two channels observed the 30.4-nm line of He II. The instrument surveyed much of the celestial sphere during a series of slow rolling maneuvers by the Apollo spacecraft. The experiment operated properly, and usable data were obtained. Study of the distributions of flux seen, and of the ratio 58.4-nm fluxes seen with gas cells full and empty, will refine current understanding of several poorly known properties of the local interstellar medium. Study of the 30.4-nm flux distribution will refine present knowledge of the structure of the earth's plasmasphere.

Bowyer, S.

Development of advanced fuel cell system, phase 2

A multiple task research and development program was performed to improve the weight, life, and performance characteristics of hydrogen-oxygen alkaline fuel cells for advanced power systems. Development and characterization of a very stable gold alloy catalyst was continued from Phase I of the program. A polymer material for fabrication of cell structural components was identified and its long term compatibility with the fuel cell environment was demonstrated in cell tests. Full scale partial cell stacks, with advanced design closed cycle evaporative coolers, were tested. The characteristics demonstrated in these tests verified the feasibility of developing the engineering model system concept into an advanced lightweight long life powerplant.

Handley, L. M.

Development of advanced fuel cell system, phase 3

A multiple task research and development program was performed to improve the weight, life, and performance characteristics of hydrogen-oxygen alkaline fuel cells for advanced power systems. Gradual wetting of the anode structure and subsequent long-term performance loss was determined to be caused by deposition of a silicon-containing material on the anode. This deposit was attributed to degradation of the asbestos matrix, and attention was therefore placed on development of a substitute matrix of potassium titanate. An 80 percent gold 20 percent platinum catalyst cathode was developed which has the same performance and stability as the standard 90 percent gold - 10 percent platinum cathode but at half the loading. A hybrid polysulfone/epoxy-glass fiber frame was developed which combines the resistance to the cell environment of pure polysulfone with the fabricating ease of epoxy-glass fiber laminate. These cell components were evaluated in various configurations of full-size cells. The ways in which the baseline engineering model system would be modified to accommodate the requirements of the space tug application are identified.

Handley, L. M.

A simple model for compressor stall cell propagation

A simple model for full-span stall cells in axial compressors has been formulated. The sudden changes in velocity across blade rows as the blade passages enter and leave the stall are shown to have important dynamical consequences for the stall flow field. The one empirical constant needed in the analysis is determined using the data of Day (1976, 1978). From this, reasonable predictions of stall cell speed and trends in speed have been obtained for a number of different compressors. From the satisfactory comparison between predicted and measured stall cell speeds, it is tentatively concluded that the model contains the essentials of a correct description of the controlling mechanism of full-span rotating stall.

Cumpsty, N. A.

CO2 laser annealing of 50-microns-thick silicon solar cells

A test program is conducted to determine thin solar cell annealing effects using a laser energy source. A CO2 continuous-wave laser was used in annealing experiments on 50 micrometers-thick silicon solar cells after proton irradiation. Test cells were irradiated to a fluence of 1.0 x 10 to the 12th power protons/sq cm with 1.9 MeV protons. After irradiation, those cells receiving full proton dosage were degraded by an average of 30% in output power. In annealing tests laser beam exposure times on the solar cell varied from 2 seconds to 16 seconds reaching cell temperatures of from 400 C to 500 C. Under those conditions annealing test results showed recovery in cell output power of from 33% to 90%.

Walker, F. E.

Development and test fuel cell powered on-site integrated total energy systems. Phase 3: Full-scale power plant development

The on-site system application analysis is summarized. Preparations were completed for the first test of a full-sized single cell. Emphasis of the methanol fuel processor development program shifted toward the use of commercial shell-and-tube heat exchangers. An improved method for predicting the carbon-monoxide tolerance of anode catalysts is described. Other stack support areas reported include improved ABA bipolar plate bonding technology, improved electrical measurement techniques for specification-testing of stack components, and anodic corrosion behavior of carbon materials.

Kaufman, A.

Development of Advanced Fuel Cell System (Phase 4)

A multiple-task research and development program was performed to improve the weight, life, and performance characteristics of hydrogen-oxygen alkaline fuel cells for advanced power systems. During Phase 4, the lowest stabilized degradation rate observed in all the testing completed during four phases of the program, 1 microvolt/hour, was demonstrated. This test continues after 5,000 hours of operation. The cell incorporates a PPf anode, a 90Au/10Pt cathode, a hybrid frame, and a Fybex matrix. These elements were developed under this program to extend cell life. The result demonstrated that the 80Au/20Pt cathode is as stable as a 90Au/10Pt cathode of twice the precious metal loading, was confirmed in full-scale cells. A hybrid frame two-cell plaque with dedicated flow fields and manifolds for all fluids was demonstrated to prevent the cell-to cell electrolyte transfer that limited the endurance of multicell plaques. At the conclusion of Phase 4, more than 90,900 hours of testing had been completed and twelve different cell designs had been evaluated. A technology base has been established which is ready for evaluation at the powerplant level.

Meyer, A. P.

Flight qualification test results for violet cells

The violet solar cell has been submitted to a flight qualification program. The tasks included in this program were: to define the violet cell's electrical output from -100 C to +100 C; to determine the violet cell's degradation under 2 MeV, 1 MeV and .3 MeV proton irradiation, under a high humidity environment and under ultraviolet light; to thermal cycle two similar modules of violet cells; to flight qualify a full size violet cell panel for the IMP-J flight; and to obtain a primary balloon-flown standard of the violet cell type. The results of these tests demonstrate that the violet cell is fully qualified for space flight use with no further development work. The tests show that the violet cell offers a power increase of at least twenty-one per cent over presently available commercial cells.

Gaddy, E. M.

Development of a high efficiency thin silicon solar cell

Preparation for full scale operation of the pilot line included reduction of the back metallization coverage to reduce the differential thermal expansion of very thin cells, mapping excess injection current at low dark forward voltage, determining the radius of curvature for fracture as a function of silicon thickness, and determining absorptance/emittance ratios for thin silicon solar cells.

Lindmayer, J.

Experimental techniques for evaluating steady-state jet engine performance in an altitude facility

Jet engine calibration tests were conducted in an altitude facility using a contoured bellmouth inlet duct, four fixed-area water-cooled exhaust nozzles, and an accurately calibrated thrust measuring system. Accurate determination of the airflow measuring station flow coefficient, the flow and thrust coefficients of the exhaust nozzles, and the experimental and theoretical terms in the nozzle gross thrust equation were some of the objectives of the tests. A primary objective was to develop a technique to determine gross thrust for the turbojet engine used in this test that could also be used for future engine and nozzle evaluation tests. The probable error in airflow measurement was found to be approximately 0.6 percent at the bellmouth throat design Mach number of 0.6. The probable error in nozzle gross thrust measurement was approximated 0.6 percent at the load cell full-scale reading.

Smith, J. M.

Solid Polymer Electrolyte (SPE) fuel cell technology program

The overall objectives of the Phase IV Solid Polymer Electrolyte Fuel Cell Technology Program were to: (1) establish fuel cell life and performance at temperatures, pressures and current densities significantly higher than those previously demonstrated; (2) provide the ground work for a space energy storage system based on the solid polymer electrolyte technology (i.e., regenerative H2/O2 fuel cell); (3) design, fabricate and test evaluate a full-scale single cell unit. During this phase, significant progress was made toward the accomplishment of these objectives.

Source record

Reconditioning experience at Marshall Space Flight Center

Problems encountered on Skylab prompted the development of a reconditioning circuit which involves a DC to DC converter, a circuit sensing device, and the capability of switching several size reconditioners onto a circuit. Across each cell there is a full bridge rectifier. During battery discharge, if there is low cell voltage, the reconditioning systems holds that voltage up and permits discharge to continue on the system. When the cell is good, the voltage is up about one volt, the diodes are back, or reversed biased, and the current drawn out of the system is very low. The system has a standby power thrown at about one volt. As the voltage drops on a cell, the circuit strts picking up the load and helps hold the overall battery voltage up.

Paschal, L. E.

Solid Polymer Electrolyte Fuel Cell Technology Program

Work is reported on phase 5 of the Solid Polymer Electrolyte (SPE) Fuel Cell Technology Development program. The SPE fuel cell life and performance was established at temperatures, pressures, and current densities significantly higher than those previously demonstrated in sub-scale hardware. Operation of single-cell Buildup No. 1 to establish life capabilities of the full-scale hardware was continued. A multi-cell full-scale unit (Buildup No. 2) was designed, fabricated, and test evaluated laying the groundwork for the construction of a reactor stack. A reactor stack was then designed, fabricated, and successfully test-evaluated to demonstrate the readiness of SPE fuel cell technology for future space applications.

Source record

Develop and test fuel cell powered on-site integrated total energy system

Satisfactory performance is reported for the first 12-cell sub-stack of the 5 kW rebuild using improved ABA reactant distribution plates. Construction and test results are described for the first full-sized single-cell test (0.33 m x 0.56 m). Test duration was 450 hours. Plans are outlined for construction and testing of two methanol reformer units based on commercially-available shell-and-tube heat exchangers. A 5 kW-equivalent precursor and a 50 kW-equivalent prototype will be built. Supporting design and single-tube experimental data are presented. Stack support efforts are summarized on corrosion currents of graphite materials and acid-management of single-cell test facilities. Comparative properties are summarized for the two methanol/steam reforming catalysts evauated under Task V (now completed); T2107RS and C70-2RS.

Kaufman, A.