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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records

Electrostatic Levitation for Studies of Additive Manufacturing Materials for Extreme Environments

The electrostatic levitation (ESL) laboratory at NASA's Marshall Space Flight Center (MSFC) is a national resource for researchers developing advanced materials for new technologies. Researchers have used MSFC's ESL Laboratory to develop advanced high-temperature materials for aerospace applications, coatings and structural materials for rocket nozzles, improved medical and industrial optics, metallic glasses, ablatives for reentry vehicles, and materials with memory. Modeling of additive manufacturing materials for extreme environments is necessary for the control of their resulting materials properties. Unfortunately, there is very little materials properties data for many additive manufacturing materials, especially of the materials in the liquid state. The MSFC ESL lab is ideal for the study of additive manufacturing materials to be used in extreme environments. The lab can provide density, surface tension, and viscosity of molten materials, emissivity measurements, and even creep strength measurements.

SanSoucie, Michael↗

Materials for Extreme Environments: Paving the Way for Lunar Exploration

As humanity expands its ventures into lunar and planetary exploration, the demand intensifies for resilient materials capable of enduring extreme environmental and service conditions. The Moon’s surface presents numerous challenges, including ultra-high vacuum exposure, temperature extremes and intense radiation. Additionally, lunar regolith poses a significant threat to component durability and reusability due to its abrasive nature. Lunar dust particles scoring, adhering, or embedding into surfaces and within device-confined geometries, such as bearings, drive mechanisms and connectors, can cause premature component wear or failure. Furthermore, the interaction between the rocket plume and the surface during vehicle landings and ascents creates severe erosive conditions near critical vehicle components and adjacent infrastructure. A key barrier hindering materials discovery for lunar dust tolerant applications is a lack of standard laboratory methods to evaluate material properties and performance under representative operating conditions. A case will be presented for research activities supporting identification, processing and characterization of candidate materials in conjunction with innovations in standardized testing and qualification. Results will highlight current and emerging test methods for simulating lunar dust exposure and component degradation, paving the way for a new generation of robust materials and coatings for space exploration.

Lunar dust↗

High Temperature Vaporization into Different Environments

Materials in extreme environments are often negatively affected by the process of vaporization. The maximum vaporization rate is determined by calculating a flux from the equilibrium vapor pressure(s) of each component. However, this maximum vaporization flux is decreased by the vaporization coefficient and the atmosphere above the material. This paper discusses each of these factors for common oxides, using SiO2 as an example. Vaporization into a vacuum is an ideal starting point, as the basic mechanisms for vaporization have been derived from these studies. Imposing an over-pressure of a static gas changes the vaporization rates from both a thermodynamic and kinetic aspect. Finally, a flowing gas is the most common situation encountered in many extreme environments. Laminar and turbulent flow effects are be treated with both analytical transport expressions and computational fluid dynamics (CFD). The example of a vaporizing SiO2 coupon in a laboratory furnace is examined with both the analytical expressions and with CFD.

Jacobson, Nathan↗

Low-temperature radiation-resistant material for ball-bearing retainers

Radiation resistant material, made of polyimide polymers and S-glass cloth, is used in ball bearing retainers for extreme environments. Material displays satisfactory wear resistance, lubricity, and stability. Results of comparative tests with fluorocarbon materials are given.

Desau, P. O.↗

Structures and Materials Technologies for Extreme Environments Applied to Reusable Launch Vehicles

This paper provides an overview of the evolution of structures and materials technology approaches to survive the challenging extreme environments encountered by earth-to-orbit space transportation systems, with emphasis on more recent developments in the USA. The evolution of technology requirements and experience in the various approaches to meeting these requirements has significantly influenced the technology approaches. While previous goals were primarily performance driven, more recently dramatic improvements in costs/operations and in safety have been paramount goals. Technologies that focus on the cost/operations and safety goals in the area of hot structures and thermal protection systems for reusable launch vehicles are presented. Assessments of the potential ability of the various technologies to satisfy the technology requirements, and their current technology readiness status are also presented.

Scotti, Stephen J.↗

Characterizing the Chemical Stability of High Temperature Materials for Application in Extreme Environments

The chemical stability of high temperature materials must be known for use in the extreme environments of combustion applications. The characterization techniques available at NASA Glenn Research Center vary from fundamental thermodynamic property determination to material durability testing in actual engine environments. In this paper some of the unique techniques and facilities available at NASA Glenn will be reviewed. Multiple cell Knudsen effusion mass spectrometry is used to determine thermodynamic data by sampling gas species formed by reaction or equilibration in a Knudsen cell held in a vacuum. The transpiration technique can also be used to determine thermodynamic data of volatile species but at atmospheric pressures. Thermodynamic data in the Si-O-H(g) system were determined with this technique. Free Jet Sampling Mass Spectrometry can be used to study gas-solid interactions at a pressure of one atmosphere. Volatile Si(OH)4(g) was identified by this mass spectrometry technique. A High Pressure Burner Rig is used to expose high temperature materials in hydrocarbon-fueled combustion environments. Silicon carbide (SiC) volatility rates were measured in the burner rig as a function of total pressure, gas velocity and temperature. Finally, the Research Combustion Lab Rocket Test Cell is used to expose high temperature materials in hydrogen/oxygen rocket engine environments to assess material durability. SiC recession due to rocket engine exposures was measured as a function of oxidant/fuel ratio, temperature, and total pressure. The emphasis of the discussion for all techniques will be placed on experimental factors that must be controlled for accurate acquisition of results and reliable prediction of high temperature material chemical stability.

Opila, Elizabeth↗

An Overview of SBIR Phase 2 Materials Structures for Extreme Environments

Technological innovation is the overall focus of NASA's Small Business Innovation Research (SBIR) program. The program invests in the development of innovative concepts and technologies to help NASA's mission directorates address critical research and development needs for agency projects. This report highlights innovative SBIR Phase II projects from 2007-2012 specifically addressing Areas in Materials and Structures for Extreme Environments which is one of six core competencies at NASA Glenn Research Center. There are twenty three technologies featured with emphasis on a wide spectrum of applications such as fine-filament superconductor wire, composite oxide cathode materials, nano-composites, high radiation solar cell, wrapped multilayer insulation, thin aerogel, and much more. Each article in this booklet describes an innovation, technical objective, and highlights NASA commercial and industrial applications. This report serves as an opportunity for NASA personnel including engineers, researchers, and program managers to learn of NASA SBIR's capabilities that might be crosscutting into this technology area. As the result, it would cause collaborations and partnerships between the small companies and NASA Programs and Projects resulting in benefit to both SBIR companies and NASA.

nano composites↗

An Overview of Materials Structures for Extreme Environments Efforts for 2015 SBIR Phases I and II

Technological innovation is the overall focus of NASA's Small Business Innovation Research (SBIR) program. The program invests in the development of innovative concepts and technologies to help NASA's mission directorates address critical research and development needs for Agency projects. This report highlights innovative SBIR 2015 Phase I and II projects that specifically address areas in Materials and Structures for Extreme Environments, one of six core competencies at NASA Glenn Research Center. Each article describes an innovation, defines its technical objective, and highlights NASA applications as well as commercial and industrial applications. Ten technologies are featured: metamaterials-inspired aerospace structures, metallic joining to advanced ceramic composites, multifunctional polyolefin matrix composite structures, integrated reacting fluid dynamics and predictive materials degradation models for propulsion system conditions, lightweight inflatable structural airlock (LISA), copolymer materials for fused deposition modeling 3-D printing of nonstandard plastics, Type II strained layer superlattice materials development for space-based focal plane array applications, hydrogenous polymer-regolith composites for radiation-shielding materials, a ceramic matrix composite environmental barrier coating durability model, and advanced composite truss printing for large solar array structures. This report serves as an opportunity for NASA engineers, researchers, program managers, and other personnel to learn about innovations in this technology area as well as possibilities for collaboration with innovative small businesses that could benefit NASA programs and projects.

integrated reacting fluid dynamics and predictive ↗

An Overview of 2014 SBIR Phase I and Phase II Materials Structures for Extreme Environments

NASA's Small Business Innovation Research (SBIR) program focuses on technological innovation by investing in development of innovative concepts and technologies to help NASA mission directorates address critical research needs for Agency programs. This report highlights nine of the innovative SBIR 2014 Phase I and Phase II projects that emphasize one of NASA Glenn Research Center's six core competencies-Materials and Structures for Extreme Environments. The technologies cover a wide spectrum of applications such as high temperature environmental barrier coating systems, deployable space structures, solid oxide fuel cells, and self-lubricating hard coatings for extreme temperatures. Each featured technology describes an innovation, technical objective, and highlights NASA commercial and industrial applications. This report provides an opportunity for NASA engineers, researchers, and program managers to learn how NASA SBIR technologies could help their programs and projects, and lead to collaborations and partnerships between the small SBIR companies and NASA that would benefit both.

barrier coating system; deployable space structure↗

High Temperature Polyimide Materials in Extreme Temperature Environments

At the end of the NASA High Speed Research (HSR) Program, NASA Langley Research Center (LaRC) began a program to screen the high-temperature Polymeric Composite Materials (PMCs) characterized by the HSR Durability Program for possible use in Reusable Launch Vehicles (RLVs) operating under extreme temperature conditions. The HSR Program focused on developing material-related technologies to enable a High Speed Civil Transport (HSCT) capable of operating temperatures ranging from 54 C (-65 F) to 177 C (350 F). A high-temperature polymeric resin, PETI-5 was used in the HSR Program to satisfy the requirements for performance and durability for a PMC. For RLVs, it was anticipated that this high temperature material would contribute to reducing the overall weight of a vehicle by eliminating or reducing the thermal protection required to protect the internal structural elements of the vehicle and increasing the structural strain limits. The tests were performed to determine temperature-dependent mechanical and physical proper-ties of IM7/PETI-5 composite over a temperature range from cryogenic temperature -253 C (-423F) to the material's maximum use temperature of 230 C (450 F). This paper presents results from the test program for the temperature-dependent mechanical and physical properties of IM7/PETI-5 composite in the temperature range from -253 C (-423 F) to 27 C (80 F).

Johnson, Theodore F.↗

Electrospun Silica Nanofibers as Passive Thermal Control Materials for the Extreme Environment of Low Earth Orbit

Effective thermal management is crucial for maintaining spacecraft and onboard systems at optimal temperatures, ensuring their longevity in space missions. Passive thermal management is particularly promising due to its lower power consumption compared to active systems. This study focuses on developing materials with low solar absorptance and large thermal emittance to facilitate self-cooling under the harsh thermal conditions of space. We employ electrospinning, a nano/micro-manufacturing technique, to create a lightweight, fibrous thermal control material from silica (SiO 2 ). Using scanning electron microscopy (SEM), we examine the nanoporous structure of the electrospun material. Its optical properties, including reflectance, transmittance, and absorptance across ultraviolet, visible, and infrared wavelengths, are assessed using spectrometers interfaced with integrating spheres. To test durability in space, we conduct high temperature endurance and ultraviolet resistance tests to observe changes in optical properties of the materials and evaluate their performance in low Earth orbit (LEO). We also compare the material's solar reflectance and thermal emittance to existing spacecraft materials. The findings suggest that electrospun silica nanofibers presents a new paradigm for passive thermal control in space applications.

thermal emittance↗

Thermal Testing of Woven TPS Materials in Extreme Entry Environments

NASAs future robotic missions to Venus and outer planets, namely, Saturn, Uranus, Neptune, result in extremely high entry conditions that exceed the capabilities of current mid density ablators (PICA or Avcoat). Therefore mission planners assume the use of a fully dense carbon phenolic heatshield similar to what was flown on Pioneer Venus and Galileo. Carbon phenolic (CP) is a robust TPS however its high density and thermal conductivity constrain mission planners to steep entries, high heat fluxes, high pressures and short entry durations, in order for CP to be feasible from a mass perspective. In 2012 the Game Changing Development Program in NASAs Space Technology Mission Directorate funded NASA ARC to investigate the feasibility of a Woven Thermal Protection System to meet the needs of NASAs most challenging entry missions. The high entry conditions pose certification challenges in existing ground based test facilities. Recent updates to NASAs IHF and AEDCs H3 high temperature arcjet test facilities enable higher heatflux (2000 Wcm2) and high pressure (5 atm) testing of TPS. Some recent thermal tests of woven TPS will be discussed in this paper. These upgrades have provided a way to test higher entry conditions of potential outer planet and Venus missions and provided a baseline against carbon phenolic material. The results of these tests have given preliminary insight to sample configuration and physical recession profile characteristics.

TPS↗

Materials for Power Transmission in Extreme Environments

NASA’s goal for a sustained human presence on the Moon and a future Lunar economy requires the development of novel power transmission materials for extreme environments. As an increasing number of public and private entities set their sights towards a future on the Moon, the demand for surface power will dramatically increase – potentially up to megawatt levels. A Lunar economy is envisioned to include a human habitat, manned and unmanned science exploration assets, excavation rovers and systems, and large-scale infrastructure construction such as solar arrays and power grids. A NASA trade study estimated that 1 to 3 km of power transmission lines (1 to 3 KV ac and dc) will be needed over time. Current high power and voltage SOA cables/wire can easily exceed 1 kg/m where mass is not as critical. Connectors, deployment spools and robots further increase the subsystem mass significantly increasing costs. On the other hand, advances in aeronautics provides path towards space missions. The operating environment on the Moon presents substantial risk to safe and reliable power transmission due to space weathering and degradation. These challenges include cosmic and UV radiation, extreme temperatures swings, the electrostatic Lunar exosphere, and the electrostatic and abrasive lunar regolith. The critical need for lightweight, safe and reliable power cables/wires materials is evident. In this presentation, the extreme high altitude and lunar environments and recent materials development from NASA Glenn Research Center’s High Voltage Materials team towards meeting NASA’s objectives and goals for aeronautics and space missions.

Cu/CNT conductors↗