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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

pi-Extended Porphyrins: The Impact of Aromatic Heterocycles on the Properties of the Largely pi-Extended Structures (Final Report_UNT_SC0016766)

Largely π-extended carbon-rich materials represent fascinating yet challenging frontiers in chemistry and materials science as it offers numerous opportunities in molecular electronics. pi-Extended porphyrins possess unique set of electronic and photophysical properties and are very attractive for a wide range of applications. However, the synthesis and functionalization of pi-extended porphyrins had been very challenging. To explore and expand this intriguing research field, it is essential to develop synthetic tools to make them accessible. Funded by the Department of Energy Basic Energy Science, my laboratory addressed these synthetic challenges by developing concise and versatile methods for pi-extended porphyrins. Significant progress has been made in multiple directions, including fusing Polycyclic Aromatic Hydrocarbons (PAH), aromatic heterocycles, antiaromatic component, and cross-conjugated component to porphyrins as well as push-pull porphyrins. The availability of these methods has made it possible to rationally design and synthesize functionalized pi-extended porphyrins. Unprecedented electronic and photophysical properties have been discovered for these pi-extended porphyrins.

36 MATERIALS SCIENCE↗
DOE OSTI2026

The ever-evolving active site: transformation of single atoms to extended structures during the Rh-catalyzed reverse water–gas shift reaction

At low temperatures (< 400°C), single atoms of Rh supported on rutile TiO 2 (rTiO 2 ) are responsible for the formation of CO during the reverse water gas shift (RWGS), while methane production is associated with the Rh-TiO 2 interface due to the correlation between methane formation rates and the volume-averaged Rh nanoparticle diameter. As the temperature is increased to >540°C, there is a notable increase in CO selectivity and methane production rates tend towards zero. The time to reach zero depends on the temperature but independent of the initial Rh structure (single atoms and/or nanoparticles), which is controlled by the catalyst preparation method (wetness impregnation versus colloidal nanoparticles). At 600°C and > 4 h time on stream, the catalytic behaviour becomes completely agnostic to the initial Rh structure as well as weight loading, and the catalysts are highly selective for the reverse water gas-shift reaction. Post-reaction HR-TEM image analysis confirms Rh nanoparticles crystallize/order during the reaction; at 400°C, most of the Rh particles are disordered, while at 600°C, they are more ordered (i.e., development of defined faceting). Infrared spectroscopy of CO adsorption on Rh nanoparticles confirms the appearance of defined facets after annealing in nitrogen at high temperatures. Annealing the Rh/rTiO 2 catalysts prior to the RWGS reaction demonstrates the structural transformation of Rh depends only on time and temperature and not on reactant or product fugacity. Sites responsible for stabilizing Rh single atoms are no longer competent at higher temperatures, enabling their integration into existent nanoparticles. As the reaction temperature is increased to temperatures >540°C, the dominant active site for CO production evolves from single atoms to extended Rh structures.

36 MATERIALS SCIENCE↗
NASA NTRS1966

An extendible structure for solar electric power in space

The needs of certain space experiments have required the development of a mechanism capable of extending solar array panels from a spacecraft in orbit, and of positioning the panels so they function effectively as solar collectors. Rather stringent design requirements were imposed by the power and configuration requirements of the spacecraft itself. Further, since high reliability was essential, a simple mechanism was called for. The resulting design can be described as four "jack-in-the-box" modules, each containing a simple slider-crank device which extends and positions a solar panel in a single, continuous cycle. The modules have been fabricated and qualification tested and will be flight-tested in the near future.

EXPANDABLE STRUCTURE↗
NASA NTRS2006

Measuring Extended Structure in Stars Using the Keck Interferometer Nuller

The Keck Interferometer Nuller is designed to detect faint off-axis mid-infrared light a few tens to a few hundreds of milliarcseconds from a bright central star. The starlight is suppressed by destructive combination along the long (85 m) baseline, which produces a fringe spacing of 25 mas at a wavelength of 10 m, with the central null crossing the position of the star. The strong, variable mid-infrared background is subtracted using interferometric phase chopping along the short (5 m) baseline. This paper presents an overview of the observing and data reduction strategies used to produce a calibrated measurement of the off-axis light. During the observations, the instrument cycles rapidly through several calibration and measurement steps, in order to monitor and stabilize the phases of the fringes produced by the various baselines, and to derive the fringe intensity at the constructive peak and destructive null along the long baseline. The data analysis involves removing biases and coherently demodulating the short-baseline fringe with the long-baseline fringe tuned to alternate between constructive and destructive phases, combining the results of many measurements to improve the sensitivity, and estimating the part of the null leakage signal which is associated with the finite angular size of the central star. Comparison of the results of null measurements on science target and calibrator stars permits the instrumental leakage - the "system null leakage" - to be removed and the off-axis light to be measured.

nulling interferometry↗
NASA NTRS1994

New very large array maps of highly core-dominated BL Lacs: Testing unified schemes

We present high dyanamic range (greater than 10 000:1) Very Large Array (VLA) maps of four highly c ore-dominated BL Lacertae Objects (PKS 0735+178, OJ 287, 1219+285, and PKS 1413+135), all of which had been reported previously as being unresolved at dynamic ranges approximately 1000-3000:1. Three of the four possess low surface brightness kpc-scale structure, with extended power levels and morphologies reasonable for FR 1 radio galaxies. One, however (PKS 1413+135), possesses no extended structure at dynamic range 9600:1. Only one of the sources exhibits aligned Very Large Array (VLA) and VLBI structures, suggesting bends on approximately 100-1000 pc size scales for the other two. As these four have extremely high core-to-extended flux ratios (f approximately 30-5000), they provide an extreme test of unified schemes. By deriving minimum constraints for the beaming angles and Lorentz factors which are required to produce the degrees of core dominance seen, we find that the three extended radio sources are consistent with being beamed FR 1 radio galaxies. PKS 1413+135 remains an anomalous BL Lac Object for several reasons.

Perlman, Eric S.↗
NASA NTRS1989

Radio emission and the hot interstellar medium of early-type galaxies

The results of an analysis of a sample of 84 elliptical and S0 galaxies, observed in X-rays with the Einstein Observatory and in radio continuum at 5 GHz, are reported. Radio flux densities result in some of the lowest radio powers yet reported for early-type galaxies. Radio structures extending beyond the optical radius are found only in galaxies with 5 GHz radio power greater than about 10 exp 29.5 ergs/s/Hz. Radio and X-ray luminosities are correlated, although with large intrinsic scatter, suggesting that more than one mechanism may be involved. A correlation between core radio power and the X-ray-to-optical ratio suggests a connection between the hot ISM and nuclear radio sources and points to accreting cooling flows as the fuel for the radio sources. For the same radio core power, extended radio lobes tend to be associated with galaxies with relatively smaller X-ray-to-optical ratios, pointing to the importance of the hot ISM in disrupting the radio jets and confining extended radio structures.

Fabbiano, G.↗
NASA NTRS1995

An extended structure-function model and its application to the analysis of solar wind intermittency

An extended structure-function model is developed by including the new effect in the p-model of Meneveau and Sreenivasan (1987a), i.e., that the averaged energy cascade rate changes with scale, a situation which has been found to prevail in non-fully-developed turbulence in the inner solar wind. This model is useful for the small-scale fluctuations in the inner heliosphere, where the turbulence is not fully developed and cannot be explained quantitatively by any of the previous intermittency turbulence models. With two model parameters, the intrinsic index of the energy spectrum, alpha and the fragmentation fraction p, the model can fit, for the first time, all the observed scaling exponents of the structure functions, which are calculated for time lags ranging from 81 seconds to 0.7 hours from the Helios solar wind data. From the cases we studied we can establish for p neither a clear radial evolution trend, nor a solar-wind-speed, or stream-structure dependence, or a systematic anisotropy for both the flow velocity and magnetic field component fluctuations. Generally, p has values between 0. 7 and 0.8. However, in some cases in low-speed wind p has somewhat higher values for the magnetic components, especially for the radial component. In high-speed wind, the inferred intrinsic spectral indices (alpha) of the velocity and magnetic field components are about equal, while the experimental spectral indices derived from the observed power spectra differ. The magnetic index is somewhat larger than the index of the velocity spectrum. For magnetic fluctuations in both high- and low-speed winds, the intrinsic exponent alpha has values which are near 1.5, while the observed spectral exponent has much higher values.

Tu, C.-Y.↗
NASA NTRS2006

Enhanced Surface Spray Cooling with Embedded and Compound Extended Surface Structures

Experiments were conducted to study the effects of enhanced surface structures on heat flux using spray cooling. The surface enhancements consisted of embedded structures (dimples, pores, and tunnels) and compound extended surface enhancements (straight fins, cubic pin fins and dimples) machined on and within the top surface of copper heater blocks. Each copper block had a projected cross-sectional area of 2.0 sq cm. Measurements were also obtained on a heater block with a flat surface for baseline comparison purposes. A 2x2 nozzle array was used with PF-5060 as the working fluid. Thermal performance data was obtained under nominally degassed (chamber pressure of 41.4 kPa) and gassy conditions (chamber with N2 gas at 101 kPa) with a bulk fluid temperature of 20.5 C. Results for both the nominally degassed and gassy cases show that the highest critical heat flux (CHF) was attained using straight fins and porous tunnels. For the nominally degassed case, both had a CHF of approx.: 142 W/sq cm while for the gassy case their CHF values increased to 175 W/sq cm. This gave an enhancement relative to the nominally degassed flat surface case of approx. 77% and 119% respectively.

Silk, Erie A.↗
NASA NTRS1995

An extended structure-based model based on a stochastic eddy-axis evolution equation

We have proposed and implemented an extension of the structure-based model for weak deformations. It was shown that the extended model will correctly reduce to the form of standard k-e models for the case of equilibrium under weak mean strain. The realizability of the extended model is guaranteed by the method of its construction. The predictions of the proposed model were very good for rotating homogeneous shear flows and for irrotational axisymmetric contraction, but were seriously deficient in the case of plane strain and axisymmetric expansion. We have concluded that the problem behind these difficulties lies in the algebraic constitutive equation relating the Reynolds stresses to the structure parameters rather than in the slow model developed here. In its present form, this equation assumes that under irrotational strain the principal axes of the Reynolds stresses remain locked onto those of the eddy-axis tensor. This is correct in the RDT limit, but inappropriate under weaker mean strains, when the non-linear eddy-eddy interactions tend to misalign the two sets of principal axes and create some non-zero theta and gamma.

Kassinos, S. C.↗
DOE OSTI2024

Friends or Foes: Fundamental Principles of Th-Organic Scaffold Chemistry Using Zr-Analogs as a Guide

The fundamental interest in actinide chemistry, particularly for the development of thorium-based materials, is experiencing a renaissance owing to the recent and rapidly growing attention to fuel cycle reactors, radiological daughters for nuclear medicine, and efficient nuclear stockpile development. Herein, we uncover fundamental principles of thorium chemistry on the example of Th-based extended structures such as metal–organic frameworks in comparison with the discrete systems and zirconium extended analogs, demonstrating remarkable over two-and-half-year chemical stability of Th-based frameworks as a function of metal node connectivity, amount of defects, and conformational linker rigidity through comprehensive spectroscopic and crystallographic analysis as well as theoretical modeling. Despite exceptional chemical stability, we report the first example of studies focusing on the reactivity of the most chemically stable Th-based frameworks in comparison with the discrete Th-based systems such as metal–organic complexes and a cage, contrasting multicycle recyclability and selectivity (>97%) of the extended structures in comparison with the molecular compounds. Altogether, the presented work not only establishes the conceptual foundation for evaluating the capabilities of Th-based materials but also represents a milestone for their multifaceted future and foreshadows their potential to shape the next era of actinide chemistry.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1987

Building validation tools for knowledge-based systems

The Expert Systems Validation Associate (EVA), a validation system under development at the Lockheed Artificial Intelligence Center for more than a year, provides a wide range of validation tools to check the correctness, consistency and completeness of a knowledge-based system. A declarative meta-language (higher-order language), is used to create a generic version of EVA to validate applications written in arbitrary expert system shells. The architecture and functionality of EVA are presented. The functionality includes Structure Check, Logic Check, Extended Structure Check (using semantic information), Extended Logic Check, Semantic Check, Omission Check, Rule Refinement, Control Check, Test Case Generation, Error Localization, and Behavior Verification.

Stachowitz, R. A.↗
NASA NTRS1992

Linear stability analysis of spherical accretion flows onto compact objects

The steady state structure and linear stability of spherical accretion flows onto compact objects are investigated over a wide range of accretion rates (ARs) for a variety of cooling functions as a function of the ratio of specific heats (gamma). Both radial and nonradial shock perturbations are considered. The flows become more extended as AR decreases. The cooling function has a significant effect on the extended structure of settling solutions with gamma = 5/3. In contrast, the extended structure of settling solutions with gamma = 4/3 is nearly independent of the form of the cooling function. For both gamma = 4.3 and gamma = 5.3, radial shock oscillation in the fundamental and first overtone modes are destabilized in spherically extended accretion envelopes. The application of these results to postsupernova neutron star accretion flows and to luminosity oscillations in AM Her objects are discussed.

Houck, John C.↗
DOE OSTI2025

Algorithms and file structures to extend and enhance liquid chromatography and ion mobility mass spectrometry workflows (CRADA Final Report)

The purpose of this project was to continue supporting customizations of algorithms and raw data file structures to enhance software workflows for liquid chromatography (LC), mass spectrometry (MS) and ion mobility mass spectrometry (IM-MS)-based protein and metabolite characterization. PNNL worked with Agilent to design, implement, evaluate, and demonstrate new algorithms and integrated them as functionalities into the PNNL-PreProcessor software. The project augmented PNNL’s capabilities to analyze complex proteomics and metabolomics samples. These capabilities are directly beneficial to DOE and PNNL efforts to characterize and analyze these compounds in microbial and plant communities. The project assisted Agilent in further developing improved instrument-software solutions combining liquid chromatography and ion mobility with mass spectrometry for widespread applications in life sciences and other fields.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Possible jet reorientation in low-frequency radio structures of blazars

ABSTRACT Blazars are active galactic nuclei (AGNs) observed at small viewing angles to the observer’s line of sight; hence most of them are compact sources in the radio regime. At low radio frequencies, we may observe additional extended structures, considered to be lobes propagating directly towards Earth. However, there are rare cases of blazars whose morphologies are interpreted in the framework of an episodic jet activity with a reorientation of the jet axis. In this paper, we aim to find other candidates for sources of this kind and present Low Frequency Array (LOFAR) observations of seven blazars with rare morphologies composed of kiloparsec-scale jets and elongated multihundred kiloparsec-scale features. Based on their radio images and physical parameters, we propose that jets could change the direction of propagation out of the sky plane during the lifetime of at least some of these sources and with such we may observe morphologically different AGN types simultaneously, similar to the previously discovered blazar SBS B1646+499. Several plausible origin scenarios are presented, including fast realignment and precession. We also derive the 144 MHz fluxes of the compact and extended structures, the total radio luminosities, the spectral indices for the diffuse haloes, and the core-dominance parameters. We also discuss the possibility that these objects are actually giant blazars with rare Fanaroff–Riley I (FR I) morphology. The previously discovered blazar SBS B1646+499 should be classified as a giant independently of its inclination with regard to the observer.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1992

Infrared morphology of mass outflow from GL 2591

Results are presented of a spectrophotometric study of a young stellar object, GL 2591, at wavelengths covering 2.10 to 2.27 microns, employing the KPNO long-slit cryogenic spectrometer. H2 emission was discovered in this source. A map of the v = 1-0 S(1) emission line shows a bipolar structure extending over 0.9 d (d/2 kpc) pc in an east-west direction roughly centered around GL 2591 IRS, with four bright knotty peaks. Br-gamma emission was detected in this source. A map of the Br-gamma emission line delineates a monopolar jetlike structure emanating over 0.2 d (d/2 kpc)pc from NIRS 1 to the southwest. The map of 2-micron continuum emission shows a multilooplike structure extending predominantly to the west. The dust distribution derived from this continuum map reveals a monopolar shell structure composed of several clumps. The spatial distribution of the H2, Br-gamma and 2-micron continuum emission is consistently explained by an outflow and dust disk model around GL 2591, if this emission is interpreted as shocked gas, ionized, gas, and swept-up dust, respectively, associated with the outflow from GL 2591.

Tamura, Motohide↗