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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS1965

Studies in Perturbation Theory. XI. Lower Bounds to Energy Eigenvalues, Ground State, and Excited States

The bracketing theorem in the partitioning technique for solving the Schrödinger equation may be used in principle to determine upper and lower bounds to energy eigenvalues. Practical lower bounds of any accuracy desired may be evaluated by utilizing the properties of ``inner projections'' on finite manifolds in the Hilbert space. The method is here applied to the ground state and excited states of a Hamiltonian H=H(sub 0)+V having a positive definite perturbation V. Even if inspiration is derived from the method of intermediate Hamiltonians, the final results are of bracketing type and independent of this approach. The method is numerically illustrated in some accompanying papers.

Loewdin, Per-Olov↗
NASA NTRS1974

Reactions of ions in excited electronic states - Excited N2/+/ ion reacting with N2 to yield N3/+/ and N

Study of the mechanism of formation of the N3(+) ion from the bimolecular reaction of excited N2(+) ions in gaseous N2. Using ion cyclotron resonance spectroscopy, an attempt is made to inquire more deeply than hitherto into the origin of the N3(+) ions and to determine the rate constant for their formation and the limits on the lifetime of the reactant excited N2(+) ions.

Bowers, M. T.↗
NASA NTRS1979

The dispersed fluorescence spectrum of NaAr - Ground and excited state potential curves

Potential curves for the ground state and the first excited state of NaAr were determined. The van der Waals molecule NaAr was prepared by supersonic free jet expansion of a mixture of sodium, argon, and helium. The electronic transition from the ground state to the first excited state A2pi was excited by a tunable dye laser and the resulting fluorescence was studied. The dispersed fluorescence spectra show discrete and diffuse features, corresponding to transitions from excited vibrational levels of the A state to bound and unbound levels of the x state. The characteristic reflection structure in the bound-free spectra permits an unambiguous assignment of the vibrational numbering in the A state, and this assignment together with previously measured spectroscopic constants are used to calculate the potential curve of the A state. The discrete structure in the fluorescence spectra is used to determine the potential curve of the x state in the well region, and the repulsive part of the X curve is then deduced through trial-and-error simulation of the bound-free spectra.

Tellinghuisen, J.↗
NASA NTRS1971

Excited states of Ce-138

Ce 138 excited states identification in beta decay spectra of Pr 138m and Pr 138 sources, using proton target bombardment

Fessler, T. E.↗