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Viscoelastic properties of entangled polymers - Ternary blends of monodisperse homopolymers

In a previous publication from this laboratory, the Rouse-Bueche-Zimm molecular theory of viscoelasticity has been extended by using a transient network model to apply to binary blends of monodisperse polymers with chain entanglements. The dynamics of the entanglements were modeled both by the enhanced frictional coefficients and by the additional elastic couplings. It was recognized that entanglements not only may form between chains of the same lengths (intracomponent entanglements) but also between those of different lengths (intercomponent entanglements). At a given intercomponent entanglement, the longer chain was assumed to have the frictional coefficient of the shorter chain. Similarly, for blends consisting of several monodisperse components with different molecular weights, such modifications are also required to predict their linear viscoelastic behavior. The frequency of these interactions is assumed to be proportional to the weight ratio of the respective component chains in the blend. Equations of motion are formulated for each component and solved numerically for the relaxation time spectra. Linear viscoelastic properties such as the dynamic mechanical moduli, stress relaxation moduli, and zero-shear viscosity can then be computed for these systems by linear summation of those of the components.

Soong, D.

Rotational fluid coupling eliminates hose entanglements

Rotational fluid coupling mechanism circulates a temperature controlled fluid between a stationary heat exchanger and a coolant plate on a rotating platform. The mechanism consists of two concentric cylinders containing one or more flexible tubes which are controlled and positioned in such a way that it eliminates tubing entanglement.

Aubol, P. B.

A molecular theory of elastomer deformation and rupture.

The mechanical properties of elastomers, including rupture and its time dependence, can be semiquantitatively predicted from nine molecular parameters which are characteristic for a given species, from the initial molecular weight of a sample before cross-linking and from the effective chain concentration (which must still be determined for each vulcanizate). Only two empirical quantities are involved - the Plazek retardation function for entanglement slippage and a related constant which serves to locate this function on the time scale. The theory leads to a new method of estimating fatigue lifetimes from short-time data.

Landel, R. F.

Low-cost calibration of acoustic locators

Method uses modified commerically-available piezoelectric-torch lighter. Handheld lighter has controlled spark gap that can be easily adjusted to produce repeatable short-duration high-amplitude voltage spikes. Pulser and lighter are coupled via short axial cable, eliminating long cable run variations in cable attenuation, and problem with cable entangling with anything in its path.

Berry, R. F.

DUMAND Summer Workshop, University of California, La Jolla, Calif., July 24-September 2, 1978, Proceedings. Volume 3 - Oceanographic and ocean engineering studies

The DUMAND (Deep Underwater Muon and Neutrino Detector) array, a hexagon 800 m on a side, 673 m high, and consisting of 22,698 sensor modules, is designed to detect neutrinos in the TeV range, hadronic cascades, muons and Cerenkov radiation. Its engineering, signal processing, and logistic aspects are considered, as are its optical detection (photomultiplier tubes) system and electronics. Geological and bottom current surveys were made at two proposed sites for the array (the Maui and Keahole Point basins of Hawaii), and a study of the steady-state response of a sensor string to current drag forces is reported. Biological interference with the DUMAND array, including mechanical entanglement by large animals, bioluminescence, and especially biofouling are considered, as well as the deployment, implantment and maintenance of the array.

Wilkins, G.

Viscoelastic Properties of Polymer Blends

Viscosity, shear modulus and other viscoelastic properties of multicomponent polymer blends are predicted from behavior of individual components, using a mathematical model. Model is extension of two-component-blend model based on Rouse-Bueche-Zimm theory of polymer viscoelasticity. Extension assumes that probabilities of forming various possible intracomponent and intercomponent entanglements among polymer molecules are proportional to relative abundances of components.

Hong, S. D.

Tool Blunts Cotter Pin Legs for Safety

Jaws on new insertion tool contain upset point and anvil. Point forces cotter-pin legs into loop as it engages anvil. Cotter pin before insertion consists of loop and straight shaft composed of two legs welded together as tips. After insertion, welded legs have been shaped into loop. Tool used to prevent bent loose ends of cotter pins from scratching workers' fingers or cutting and entangling wires.

Stein, J. A.

Tangleproof Rotary Electrical Coupling

New rotary coupling connects large number of electrical cables to turntable without stressing cables or tangling them. Device accommodates 246 cables containing total of 758 conductors and allows turntable to rotate through arc of 320 degrees. At extremes of rotation, cables are loose enough that they are not pulled taut and overstressed. At halfway point, cables are not so loose that they become entangled.

Keller, F.

Materials investigation of STS-3 parachute failure

Main parachute, No. 2 of SRB A-12 on STS-3, sustained damage during deployment or initial inflation that resulted in its collapse and failure to sustain load. During an investigation of the materials from this parachute, optical and scanning electron microscope analyses were conducted. This examination identified stains and abrasions on vent lines that appear to have been a result of friction contact with its flotation bag lanyard. Mechanical testing of the vent band indicated a reduction in strength of 37 percent obviously due to structural overload, heat, and ocean water exposure. It is concluded from this and other available data that entanglement of parachutes No. 1 and No. 2 during deployment caused adequate structural damage to main parachute No. 2 to render it unable to carry load.

Nichols, R. L.

NMR (Nuclear Magnetic Resonance) and macromolecular migration in a melt or in concentrated solutions

The purpose of this paper is to analyze the migration process of long polymer molecules in a melt or in concentrated solutions as it may be observed from the dynamics of the transverse magnetization of nuclear spins linked to these chains. The low frequency viscoelastic relaxation of polymer systems is known to be mainly controlled by the mechanism of dissociation of topological constraints excited on chains and which are called entanglements. This mechanism exhibits a strong dependence upon the chain molecular weight. These topological constraints also govern the diffusion process of polymer chains. So, the accurate description of the diffusion motion of a chain may be a convenient way to characterize disentanglement processes necessarily involved in any model proposed to explain viscoelastic effects.

Addad, J. P. C.

Revisiting the Soyuz-1 Parachute Failure in the Context of Safety in the Modern Era

The Soyuz‑1 accident remains one of the most consequential parachute related failures in human spaceflight history and provides enduring lessons for modern Entry, Descent, and Landing (EDL) system design. Occurring during the height of the Cold War and the Space Race, the mission unfolded under extraordinary political and schedule pressure as the Soviet Union sought to maintain its early leadership in space achievements following the death of chief designer Sergei Korolev. Despite unresolved propulsion, electrical, and parachute system deficiencies, Soyuz‑1 proceeded to launch and immediately encountered critical inflight anomalies, including a failed solar panel deployment, attitude control issues, and communication dropouts. Upon reentry, a malfunction in the parachute system, driven by a primary main canopy that failed to deploy, and subsequent entanglement of the reserve main canopy with the primary drogue parachute, resulted in insufficient deceleration and the fatal crash of cosmonaut Vladimir Komarov. Subsequent investigations revealed deep rooted cultural and organizational issues within the Soviet space program, including inadequate testing, suppression of dissent, undocumented last minute design changes, and the absence of integrated parachute system verification. More than 200 design flaws were identified after the accident, and firsthand accounts, including those from Yuri Gagarin, highlighted widespread concern prior to launch. Over time, the Soviet program implemented substantial reforms: systematic design corrections, rigorous process documentation, and an extensive series of drop tests that ultimately transformed the Soyuz system into one of the world’s most reliable human-rated return vehicles. This paper examines the technical architecture of the Soyuz‑1 parachute system, reconstructs the likely deployment sequence and failure mechanism, and analyzes the cultural contributors that shaped the accident. The study draws parallels to modern spacecraft parachute development, emphasizing the critical importance of integrated system testing, transparent engineering culture, and continuous hardware surveillance. These lessons remain directly relevant to today’s NASA and Commercial Crew Programs (CCP), where the Government continues to refine its understanding of aggregate risk and strengthen overall astronaut safety in the face of increasingly complex parachute systems.

Aaron L Morris