Unveiling the dimensionality effect of conductive fillers in thick battery electrodes for high-energy storage systems
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99 GENERAL AND MISCELLANEOUS↗
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Results for “energy/power systems”
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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A Stochastic Multi-Criteria Decision-Making Algorithm for Dynamic Load Prioritization in Grid-Interactive Efficient Buildings
Increasing deployment of advanced sensing, controls, and communication infrastructure enables buildings to provide services to the power grid, leading to the concept of grid-interactive efficient buildings. Since occupant activities and preferences primarily drive the availability and operational flexibility of building devices, there is a critical need to develop occupant-centric approaches that prioritize devices for providing grid services, while maintaining the desired end-use quality of service. In this paper, we present a decision-making framework that facilitates a building owner/operator to effectively prioritize loads for curtailment service under uncertainties, while minimizing any adverse impact on the occupants. The proposed framework uses a stochastic (Markov) model to represent the probabilistic behavior of device usage from power consumption data, and a load prioritization algorithm that dynamically ranks building loads using a stochastic multi-criteria decision-making algorithm. The proposed load prioritization framework is illustrated via numerical simulations in a residential building use-case, including plug-loads, air-conditioners, and plug-in electric vehicle chargers, in the context of load curtailment as a grid service. Suitable metrics are proposed to evaluate the closed-loop performance of the proposed prioritization algorithm under various scenarios and design choices. Scalability of the proposed algorithm is established via computational analysis, while time-series plots are used for intuitive explanation of the ranking choices.
24 POWER TRANSMISSION AND DISTRIBUTION↗
Optical damage considerations in the design of the matter in extreme condition upgrade (MEC-U) laser systems
The Matter in Extreme Conditions Upgrade (MEC-U) project is a major upgrade to the MEC instrument of the LINAC Coherent Light Source (LCLS) X-ray free electron laser (XFEL) user facility at SLAC National Accelerator Laboratory. Here, the envisioned MEC upgrade will significantly enhance the capabilities of the pump laser sources in current MEC experimental station, boosting the energy of the nanosecond shock driver from 100 J to the kJ level, and increasing the power and repetition rate of the short pulse laser from 25 TW at 5 Hz to 1 PW at 10 Hz rate. Building such high energy/power pump laser systems presents challenges to minimize and mitigate against laser-induced optical damage. Here, as part of the system design, we have identified the optics at high-risk to damage and we have designed the laser systems to mitigate against these damage risks to ensure sustained facility operation.
Coating↗
Li Anode Technology for Improved Performance
A novel, low-cost approach to stabilization of Li metal anodes for high-performance rechargeable batteries was developed. Electrolyte additives are selected and used in Li cell electrolyte systems, promoting formation of a protective coating on Li metal anodes for improved cycle and safety performance. Li batteries developed from the new system will show significantly improved battery performance characteristics, including energy/power density, cycle/ calendar life, cost, and safety.
Chen, Tuqiang↗
Solid-State, Single-Ion Conducting, Polymer Blend Electrolytes with Enhanced Li + Conduction, Electrochemical Stability, and Limiting Current Density
The development of solid-state polymer electrolytes with high lithium conductivity is crucial to improve lithium-ion battery performance and ameliorate the safety challenges associated with current solvent-based electrolytes. Unfortunately, sluggish polymer segmental dynamics are known to constrain conductivity enhancements in solid-state polymer electrolyte systems, limiting overall performance. In this work, a glassy single-ion-conducting polymer, poly[lithium sulfonyl(trifluoromethane sulfonyl)imide methacrylate] (PLiMTFSI), was blended with a flexible polymer, poly(oligo-oxyethylene methyl ether methacrylate) (POEM), and the impact of PLiMTFSI molecular weight and ion concentration on the thermal and ion-conducting behavior of blend electrolytes was investigated. High ionic conductivities approaching 1 × 10 -2 S/cm at 150 °C were realized in this polymer blend electrolyte system as a result of decoupling Li + transport from polymer segmental dynamics. The decoupled ion transport was attributed to the packing frustration of the glassy PLiMTFSI – sufficient percolating free volume was generated to produce effective ion diffusion pathways. This decoupling was tunable as the ion transport could be altered from being closely coupled to the polymer segmental dynamics (Vogel–Tammann–Fulcher-like) to hopping (Arrhenius-like) by increasing the PLiMTFSI molecular weight and ion concentration. Moreover, the immobilized TFSI anion resulted in high Li + selectivity (Li + transference number = 0.9), high electrochemical stability (up to 4.7 V against Li + / Li), and limiting current density of 1.8 mA/cm 2 (electrolyte thickness = 0.05 cm). These features suggest that this single-ion-conducting, polymer blend electrolyte might be a promising alternative to a benchmark system – salt-doped polyethylene oxide. Moreover, the above characteristics can support the battery operation at higher voltages using energy-dense Li metal anodes, with faster charging rates and enhanced energy/power densities. Altogether, the results suggest that polymer chain packing frustration can be exploited to overcome the constraints of slow polymer segmental relaxations to achieve rapid and highly selective ion transport and enhanced performance in solid-state polymer electrolytes.
36 MATERIALS SCIENCE↗
An unwanted guest in the electrochemical oxidation of high-voltage Li-ion battery electrolytes: the life of highly reactive protons
Lithium-ion batteries (LIBs) are central to the urgent societal need to decarbonize both transportation and energy storage on the grid. Unfortunately, despite their attractive energy/power density, as well as high coulombic and energy efficiencies, further improvement of this technology – especially their durability – is desperately needed. To support these efforts, our study focuses on fundamental understanding of the decomposition pathways for LIB electrolytes at the cathode–electrolyte interface (CEI), as the nature of these reactions directly controls the extent to which cell capacity and voltage decays in these systems. In this study, we employ electrochemical methods, coupled with product analysis using NMR spectroscopy and mass spectrometry, to determine the decomposition mechanisms in both model and technologically relevant electrolytes. Remarkably, we discovered the electrochemical formation of protons with high chemical activity, comparable to known superacids, at potentials relevant to practical Li-ion batteries. Their reactivity toward every individual component of the CEI provides a unified thermochemical origin for a myriad of side reactions that are commonly associated with the electrochemical reaction. In particular, electrochemically generated protons react with intact EC molecules to form CO 2 and other short and long chain ethers. They also undergo an acid–base reaction with LiPF 6 , to form the weaker acid HF, and with the cathode active material, leaching transition metals into the electrolyte. Collectively, the results of this study all point to the urgent need to either mitigate this proton formation or introduce benign harvesting additives via new electrolyte design strategies.
Ilic, Stefan [Argonne National Laboratory (ANL), A↗
Tortuosity Engineering for Improved Charge Storage Kinetics in High-Areal-Capacity Battery Electrodes
The increasing demands of electronic devices and electric transportation necessitate lithium-ion batteries with simultaneous high energy and power capabilities. However, rate capabilities are often limited in high-loading electrodes due to the lengthy and tortuous ion transport paths with their electrochemical behaviors governed by complicated electrode architectures still elusive. Here, we report the electrode-level tortuosity engineering design enabling improved charge storage kinetics in high-energy electrodes. Both high areal capacity and high-rate capability can be achieved beyond the practical level of mass loadings in electrodes with vertically oriented architectures. The electrochemical properties in electrodes with various architectures were quantitatively investigated through correlating the characteristic time with tortuosity. The lithium-ion transport kinetics regulated by electrode architectures was further studied via combining the three-dimensional electrode architecture visualization and simulation. Finally, the tortuosity-controlled charge storage kinetics revealed in this study can be extended to general electrode systems and provide useful design consideration for next-generation high-energy/power batteries.
25 ENERGY STORAGE↗
ISRU Technology Development for Extraction of Water from the Mars Surface
Goals: Develop technologies to extract water from planetary regolith considering production rate vs: energy/power consumption (efficiency, yield, heat recuperation options); Mass and sizing: modularity, batch sizes, soil feed options, etc.; Ruggedness in terms of soil, environmental, and operational parameters; seals and component wear, etc.; Removal of product and disposal of spent material. Summary: Technology development is underway for several ISRU water extraction hardware concepts for Mars application - Hydrated minerals (Auger dryer, Microwave, Open Air), Subsurface Ice (Rodwell); Models are developed with experimental and breadboard efforts for use in larger ISRU system models; Each effort consists of a 3 year development plan, with the goal of integrating into a larger subsystem test in 2020 - Concurrent technology advance allows for flexibility in system design; depending on architecture decisions and progress of associated subsystems.
In-Situ Resource Utilization↗
Operations Concept for Responding to Urgent Requests for NASA-ISRO Synthetic Aperture Radar (NISAR)
The NASA-ISRO Synthetic Aperture Radar, or NISAR, mission is an Earth-mapping radar observatory to be launched from Sriharikota (India) in 2022. This mission is a collaboration between the National Aeronautics and Space Administration (NASA) and the Indian Space Research Organization (ISRO). This spacecraft will carry two instruments that will operate at radar wavelengths (L and Sband) and will provide data for understanding changes in the Earth’s land surface. The scientific data from this mission will revolutionize our understanding of the causes and consequences of land surface changes on Earth, ranging from Solid Earth Deformation in the form of natural hazards like earthquakes, volcanic eruptions and landslides, to ecosystem disturbances, to changes in the cryosphere (measurements of polar ice caps, ice sheets and sea ice). A nominal Reference Observation Plan, that repeats roughly every 12-24 days, developed prior to launch by the NISAR Mission Planning team, in consultation with the Science Team, will form the basis of science data collection by the payload instruments onboard the NISAR observatory after launch. Scheduling of science observations for the mission requires accounting for limited spacecraft resources like onboard data storage, downlink capacity, energy/power, thermal limits and instrument duty cycles. In addition to nominal science data collection, the project has a Level 1 requirement to respond to requests for urgent data acquisition over disaster sites (natural or anthropogenic) by scheduling new acquisitions within 24 hrs of notification and delivering science data within 5 hours of data acquisition. This capability is to be exercised on a ‘best-efforts basis’. While the definition of what constitutes an ‘urgent request’, and how such requests would be submitted to the project, is within the domain of the Science Team, the Mission System team is responsible for developing the baseline operations concept and implementation approach for responding to such requests. Given the ‘best-efforts’ nature of this requirement, a few highlevel guidelines have been developed to help guide the formulation of the operations concept, and are presented in this paper. Requests for urgent response data will be accommodated following the guiding principle of minimal to no impact on nominal science and planned engineering activities. No change in satellite orbit or attitude will be made for urgent response. Restricting response approaches to only changing the downlink and/or ground processing priority for existing observations, and adding new observations only in areas where NISAR will not be nominally imaging, allows for minimal impact on the Reference science Observation Plan. No instrument mode changes will be allowed for urgent response (except for high-priority requests), and no new observations that impact either planned science or engineering activities will be scheduled. Additionally, data requests must fit within the available project resource margins (both spacecraft and ground resources are to be evaluated). Both JPL and ISRO will be involved at various steps of the implementation, irrespective of whether the urgent request is for L-SAR (NASA instrument) or S-SAR (ISRO instrument) or a joint dataset.
Sharma, Priyanka↗