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Utah FORGE: Geochemical Data for Cold Groundwaters and Produced Geothermal Fluids

Geochemical data for cold groundwaters and produced geothermal fluids around the Utah FORGE site. The data is compiled into four tables in the attached Excel File. Table 1 is a compilation of compositions (anions, cations, weak acids, oxygen, hydrogen, and carbon isotopes) for cold groundwaters and produced geothermal waters in the Milford valley, Utah. Table 2 is a compilation of noble gas (He, Ne, Ar) and He and Ne isotopic compositions for cold groundwaters and produced geothermal waters in the Milford valley, Utah. Table 3 provides values for calculated advective and diffusive fluxes of helium. Table 4 provides values of calculated subsurface stored heat between the Opal Mound fault and the Utah FORGE site, which are related to volumes of recently solidified magmatic heat sources.

15 GEOTHERMAL ENERGY↗

Helium diffusion in the sun

We calculate improved standard solar models using the new Livermore (OPAL) opacity tables, an accurate (exportable) nuclear energy generation routine which takes account of recent measurements and analyses, and the recent Anders-Grevesse determination of heavy element abundances. We also evaluate directly the effect of the diffusion of helium with respect to hydrogen on the calculated neutrino fluxes, on the primordial solar helium abundance, and on the depth of the convective zone. Helium diffusion increases the predicted event rates by about 0.8 SNU, or 11 percent of the total rate, in the chlorine solar neutrino experiment, by about 3.5 SNU, or 3 percent, in the gallium solar neutrino experiments, and by about 12 percent in the Kamiokande and SNO solar neutrino experiments. The best standard solar model including helium diffusion and the most accurate nuclear parameters, element abundances, and radiative opacity predicts a value of 8.0 SNU +/- 3.0 SNU for the C1-37 experiment and 132 +21/-17 SNU for the Ga - 71 experiment, where the uncertainties include 3 sigma errors for all measured input parameters.

Bahcall, J. N.↗

On the origin of the MeV energy nucleon flux associated with CIRs

Measurements of recurrent enhancements of interplanetary nucleon flux in the MeV energy range are presented and interpreted. The features recur at the solar rotation period in association with stream-stream plasma interaction regions corotating with the sun. At distances from the sun less than 1 AU, the maximum intensities of the hydrogen and helium components increase with increasing distance between 300%/AU and 600%/AU. A model is proposed which predicts the acceleration of nuclei from keV plasma energies to MeV energies by means of transit time damping of magnetosonic waves as solar wind plasma flows from the sun. Numerical solutions of the transport equation are derived to demonstrate that the model does not reproduce radial variations of hydrogen and helium fluxes, and estimates are made of the radial diffusive mean free path. Finally, the observations are found to be consistent with nucleon acceleration at the CIR shocks beyond 1 AU with subsequent diffusion toward the sun.

Christon, S. P.↗

Effect of Helium Flux on Near-surface Helium Accumulation in Plasma-Exposed Tungsten

We report results of object kinetic Monte Carlo (OKMC) simulations aimed at understanding the effect of helium flux on the near-surface helium accumulation in plasma-facing tungsten, which is initially defect-free and has a W(100) surface orientation. These OKMC simulations are performed at 933 K for fluxes ranging from 10 22 to 4 × 10 25 He/m 2 s, with 100 eV helium atoms impinging on a W(100) surface up to a maximum fluence of 4×10 19 He/m 2 . In the near-surface region, helium clusters interact elastically with the free surface. The interaction is attractive and results in the drift of mobile helium clusters towards the surface as well as increased trap mutation rates. The associated kinetics and energetics of the above-mentioned processes obtained from molecular dynamics simulations are also considered. The OKMC simulations indicate that as the flux decreases, the retention of implanted helium decreases, and its depth distribution shifts to deeper below the surface in initially pristine tungsten. Furthermore, the fraction of retained helium diffusing into the bulk increases as well, so much so that for 10 22 He/m 2 s, almost all of the retained helium diffused into the bulk with minimal/negligible near-surface helium accumulation. At a given flux, with increasing fluence, the fraction of retained helium initially decreases and then starts to increase after reaching a minimum. The occurrence of the retention minimum shifts to higher fluences as the flux decreases. Although the near-surface helium accumulation spreads deeper into the material with decreasing flux and increasing fluence, the spread appears to saturate at depths between 80 and 100 nm. Finally, we present a detailed analysis of the influence of helium flux on the size and depth distribution of total helium and helium bubbles.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Radiation considerations for interplanetary missions

Galactic cosmic radiation (GCR) poses a serious radiation hazard for long-duration missions. In designing a lunar habitat or Mars transfer vehicle, the worst-case radiation exposure determines shielding thickness and, hence, the weight of spacecraft. Using the spherically symmetric diffusion theory of the solar modulation of GCR, it was possible to use data on the differential energy spectra of hydrogen, helium, oxygen, and iron from 1954 to 1989 to show that the flux at 1 A.U. is determined by the diffusion parameter, K, which is a function of the time in the solar cycle. This analysis also showed that the solar minimum of 1976 to 1977 was the deepest minimum in the last 37 years. Using this theory, we have obtained the GCR spectra for all the nuclei and calculated the depth-dose as a function of aluminum shield thickness. Using the ICRP-26 definition of the quality factor, it is shown that the shielding required to stay below the LEO recommended annual limit of 50 cSv is 17.5 (+8, -3), g/sq cm of aluminum; if the limit is raised to 60 cSv, the required shielding is 9 (5, -1.5) g/sq cm. We also discuss the issues and shielding needs for protection against solar particle events.

Badwar, Gautam D.↗

Helioseismic Constraints on New Solar Models from the MoSEC Code

Evolutionary solar models are computed using a new stellar evolution code, MOSEC (Modular Stellar Evolution Code). This code has been designed with carefully controlled truncation errors in order to achieve a precision which reflects the increasingly accurate determination of solar interior structure by helioseismology. A series of models is constructed to investigate the effects of the choice of equation of state (OPAL or MHD-E, the latter being a version of the MHD equation of state recalculated by the author), the inclusion of helium and heavy-element settling and diffusion, and the inclusion of a simple model of mixing associated with the solar tachocline. The neutrino flux predictions are discussed, while the sound speed of the computed models is compared to that of the sun via the latest inversion of SOI-NMI p-mode frequency data. The comparison between models calculated with the OPAL and MHD-E equations of state is particularly interesting because the MHD-E equation of state includes relativistic effects for the electrons, whereas neither MHD nor OPAL do. This has a significant effect on the sound speed of the computed model, worsening the agreement with the solar sound speed. Using the OPAL equation of state and including the settling and diffusion of helium and heavy elements produces agreement in sound speed with the helioseismic results to within about +.-0.2%; the inclusion of mixing slightly improves the agreement.

Elliott, J. R.↗

Energization and transport of ions of ionospheric origin in the terrestrial magnetosphere

The work of this grant has been predominantly focused on ion outflows from two data sets: Prognoz 7 and Dynamics Explorer. The Prognoz analysis studied ion densities, temperatures, and flow velocities in the magnetotail. The work performed under this contract consisted of developing a program to load the raw data, computing the background subtraction of a strong sun pulse, and using the net count to calculate the low order moments of the distribution function. The study confirms the results of ISEE with regard to the supply of plasma from the cusp as a major source of plasmasheet plasma and goes beyond this to discuss the use of ion velocities as a way to examine the motions of the magnetotail. The abstract of the work to be reported is included as an appendix. The work on the DE/Retarding Ion Mass Spectrometer is separated into two categories: (1) classification of low-energy ion flows from high-latitudes, and (2) studies of the polar wind. Major publications resulting from this work are also included as an appendix to this report. The polar wind is in a category by itself as a result of the thermal escape of hydrogen and helium because of ambipolar diffusion through the heavier, oxygen-dominated topside ionosphere. The analysis of the polar wind reports the flux variability as a function of season, magnetic activity, etc. Much effort has been expended under this grant to complete a follow on study of the thermal structure of the polar wind. Extensive display tools and analysis software have been developed and used in an attempt to carry out this thermal analysis. The present work uses a constrained fit scheme that combines the ion densities and flow velocities derived from Chandler et al. and a spacecraft potential derived from an empirical relation to the total ion density to determine the remaining fit parameter, the ion temperature, via a least squares fit to the RIMS data.

Waite, J. Hunter JR.↗

OH density, flux and loss probability measurements in a room temperature atmospheric pressure surface discharge by microscopic laser induced fluorescence

Many applications involving atmospheric pressure plasma-substrate interactions are enabled by the large fluxes of short-lived reactive species such as OH radicals to the substrate, nonetheless, the accurate measurement of radical densities and fluxes at substrates at atmospheric pressure has received little attention to date, particularly for surface ionization waves. We report the measurement of the OH density distribution in a surface discharge on a fused silica (quartz) substrate generated by an impinging atmospheric pressure plasma jet in dry and humid helium. The OH density is measured by microscopic laser induced fluorescence with a spatial resolution of 10 µm in the direction perpendicular to the quartz substrate. The measured OH diffusive flux varied for the investigated experimental conditions by almost three orders of magnitude and had a maximum value of 1.7 × 10 15 cm -2 s -1 . The corresponding surface loss probability of OH on the quartz surface was determined to be ~0.01. The high spatial resolution was required to accurately resolve the near surface gradient of OH radicals.

plasma-surface interactions↗

The submillimeter spectrum of the cosmic background radiation

The diffuse brightness of the sky has been measured in six submillimeter passbands, using a rocket-borne, liquid helium-cooled, absolute radiometer. The flux measured at 1160 microns is in good agreement with the average of longer wavelength measurements of the temperature of the cosmic background radiation. The fluxes measured at 709 microns and 481 microns show a rapid decrease toward shorter wavelength, but correspond to significantly higher temperatures. No local source of this excess flux has been identified. The spectrum of the excess significantly constrains cosmological models. Data at 262, 137, and 102 microns are consistent with emission from interstellar dust.

Matsumoto, T.↗

Improved solar models constructed with a formulation of convection for stellar structure and evolution calculations without the mixing-length theory approximations

We have updated a previous attempt to incorporate within a solar model a treatment of convection based upon numerical simulations of convection rather than mixing-length theory (MLT). We have modified our formulation of convection for a better treatment of the kinetic energy flux. Our solar model has been updated to include a complete range of OPAL opacities, the Debye-Hueckel correction to the equation of state, helium diffusion due to gravitational settling, and atmospheres by Kurucz. We construct a series of models using both MLT and our revised formulation of convection and the compared results to measurements of the solar radius, the solar luminosity, and the depth of the solar convection zone as inferred from helioseismology. We find X(solar) = 0.702 +/- 0.005, Y(solar) = 0.278 +/- 0.005, and Z(solar) = 0.0193 +/- 0.0005.

Lydon, Thomas J.↗

Impact of Soret effect on hydrogen and helium retention in PFC tungsten under ELM-like conditions

Abstract In our previous work, we have demonstrated using nonequilibrium molecular-dynamics simulations that the fluxes of helium and self-interstitial atoms in the presence of a thermal gradient in tungsten are directed opposite to the heat flux, indicating that species transport is governed by a Soret effect, namely, thermal-gradient-driven diffusion, characterized by a negative heat of transport that drives species transport uphill, i.e. from the cooler to the hot regions of the tungsten sample. In this work, the findings of our thermal and species transport analysis have been implemented in our cluster-dynamics code, Xolotl, which has been used to compute temperature and species profiles over spatiotemporal scales representative of plasma-facing component (PFC) tungsten under typical reactor operating conditions, including extreme heat loads at the plasma-facing surface characteristic of plasma instabilities that induce edge localized modes (ELMs). We demonstrate that the steady-state species profiles, when properly accounting for the Soret effect, vary significantly from those where temperature-gradient-driven transport is not accounted for and discuss the implications of such a Soret effect on the response to plasma exposure of plasma-facing tungsten. Although our cluster-dynamics simulations do not yet include self-clustering of helium or hydrogen blister formation, our simulation results show that the Soret effect substantially reduces helium and hydrogenic species retention inside PFC tungsten.

36 MATERIALS SCIENCE↗

Wind enhanced planetary escape: Collisional modifications

The problem of thermal escape is considered in which both the effects of thermospheric winds at the exobase and collisions below the exobase are included in a Monte Carlo calculation. The collisions are included by means of a collisional relaxation layer of a background gas which models the transition region between the exosphere and the thermosphere. The wind effects are considered in the limiting cases of vertical and horizontal flows. Two species are considered: terrestrial hydrogen and terrestrial helium. In the cases of terrestrial hydrogen the escape fluxes were found to be strongly filtered or throttled by collisions at high exospheric temperatures. The model is applied to molecular hydrogen diffusing through a methane relaxation layer under conditions possible on Titan. The results are similar to the case of terrestrial hydrogen with wind enhanced escape being strongly suppressed by collisions. It is concluded that wind enhanced escape is not an important process on Titan.

Curtis, S. A.↗

Response of 11 B enriched ZrB 2 ultra-high temperature ceramic to neutron irradiation at elevated temperatures

ZrB 2 , an ultra-high temperature ceramic (UHTC) is being considered for use in fusion reactor first-wall structures, yet its response to irradiation remains poorly understood. This study employed scanning/transmission electron microscopy (S/TEM), synchrotron X-ray diffraction (XRD), finite element calculations, and thermal property measurements to thoroughly investigate the neutron-irradiation effects on 11 B-enriched ZrB 2 . Neutron irradiations were conducted at 220 °C and 620 °C, with a neutron fluence of 2.2 × 10 25 neutron/m 2 (energy > 0.1 MeV), resulting in 3.9 dpa and 4200 appm He. The study revealed the unusual prevalence of prism loops and a > c anisotropic lattice swelling, likely linked to the low c/a ratio of ZrB 2 , leading to grain boundary microcracking. Reducing the grain sizes was effective in reducing intergranular cracking and macroscopic swelling. The observation of cavities in ZrB 2 irradiated at 620 °C, as opposed to 220 °C, prompts questions about the temperature at which vacancies in ZrB 2 become mobile, and the role of neutron absorption by 10 B in elevating irradiation temperatures. Isotopic enrichment in 11 B proves to be a viable strategy for mitigating helium production in transition-metal diborides, which is a critical consideration for nuclear applications. Irradiation-induced defects reduce the thermal diffusivity and conductivity of ZrB 2 by a factor of 4–9, which has important implications for its role as a plasma-facing material in fusion reactors that drive high heat fluxes through first-wall materials. Here, this comprehensive study lays the foundation for understanding ZrB 2 behavior under neutron irradiation and highlights important phenomena to consider for various material applications.

36 MATERIALS SCIENCE↗

Non-thermal hydrogen in the Venus exosphere - The ionospheric source and the hydrogen budget

A nonthermal, or 'hot', Venus corona of H atoms has been observed by Mariners 5 and 10 and Venera 9. Of the sources investigated, reaction of H2 with ionospheric O(+) is still the strongest. It can explain the smaller densities but falls somewhat short of the largest (from Mariner 5). The subsequent recombination of OH(+), supplemented by solar-wind processes, may give an escape flux of 10 million atoms per sq cm/s. The low density of thermal H atoms on the day side has previously been attributed to either a large eddy diffusion coefficient or an escape flux tenfold greater than this. An alternative mechanism, suggested by Hartle and Mayr (1977) is supported: the hydrogen is swept to the night side by strong thermospheric winds. This process is analogous to the 'Johnson pump' for the terrestrial winter helium bulge. Large nightside bulges of H and H2 are predicted; the night/day density ratio is estimated to be as large as 100 for each.

Kumar, S.↗

Understanding the effect of minor alloying elements on helium bubble formation in ferritic-martensitic steels

Ferritic-martensitic steels are promising structural materials for advanced nuclear reactors. To minimize long-term radioactivity, reduced-activation ferritic-martensitic steels have been developed by substituting high-activation elements like Ni and Mo with low-activation elements such as W. However, the impact of these alloying modifications on helium bubble formation, which plays a key role in material swelling, remains unclear. Here, in this study, we compared helium bubble formation in ferritic-martensitic steel T91 and reduced-activation ferritic-martensitic steel F82H. Both materials were irradiated with sequential 100 keV, 150 keV, and 200 keV helium ions to a dose of 0.5 dpa and a helium concentration of 9,000 appm at 500°C. The helium bubbles in F82H exhibited a larger average size and a lower density than those in T91, suggesting differences in minor alloying elements may influence the bubble growth. Here, to investigate the effects of these alloying elements, we characterized radiation-induced segregation near bubbles and grain boundaries. Prominent Ni-Mn-Si enriched clusters were found near bubbles in T91, while only Mn-Si enriched clusters were found near bubbles in F82H. In addition, the obvious Cr enrichment near grain boundaries was absent around bubbles in both steels. The different segregation trends among elements revealed the variations in element diffusion mechanisms and the different sink biases between bubbles and grain boundaries. Cr enrichment near grain boundaries is mostly driven by interstitial-mediated diffusion. However, since bubble growth relies on net vacancy flux, vacancy-mediated diffusion plays a dominant role in controlling element segregation near bubbles. Therefore, Cr enrichment was not found near bubbles. Because of preferential vacancy-drag diffusion for Ni, Si and Mn, these elements were enriched near bubbles. Due to the strong binding energies of vacancies with these solute atoms, the vacancy diffusivity can be reduced near these solutes. Therefore, the more prominent Ni-Si-Mn clustered near helium bubbles in T91 lead to stronger suppression of helium bubble growth compared to F82H.

36 MATERIALS SCIENCE↗

Effect of Hydrogen and Helium on Irradiation Damage Accumulation in Nickel

We report our results on the study of the effects of hydrogen and helium on irradiation damage accumulation in nickel, aiming to understand the TEM observations made by Edwards et al. regarding the Ni-coatings protecting the getter tube in a TPBAR. We hypothesized that differences in the fluxes of 3 H and/or He between the coatings might explain these microstructural variations. However, our simulation results show that during the initial stages of irradiation, the presence of H or He enhances void nucleation by stabilizing small vacancy clusters against thermal dissociation and does not enhance void growth. Nevertheless, we think that helium’s higher diffusivity, stronger binding with vacancy clusters, and ability to displace a nearby lattice atom—either to create a new vacancy or to enlarge an existing vacancy cluster—could result in a larger average vacancy cluster size. Therefore, it is likely that void growth will occur post-nucleation phase as more He accumulates at higher doses than those simulated in this study.

36 MATERIALS SCIENCE↗

A Computational Fluid Dynamic and Heat Transfer Model for Gaseous Core and Gas Cooled Space Power and Propulsion Reactors

A computational model based on the axisymmetric, thin-layer Navier-Stokes equations is developed to predict the convective, radiation and conductive heat transfer in high temperature space nuclear reactors. An implicit-explicit, finite volume, MacCormack method in conjunction with the Gauss-Seidel line iteration procedure is utilized to solve the thermal and fluid governing equations. Simulation of coolant and propellant flows in these reactors involves the subsonic and supersonic flows of hydrogen, helium and uranium tetrafluoride under variable boundary conditions. An enthalpy-rebalancing scheme is developed and implemented to enhance and accelerate the rate of convergence when a wall heat flux boundary condition is used. The model also incorporated the Baldwin and Lomax two-layer algebraic turbulence scheme for the calculation of the turbulent kinetic energy and eddy diffusivity of energy. The Rosseland diffusion approximation is used to simulate the radiative energy transfer in the optically thick environment of gas core reactors. The computational model is benchmarked with experimental data on flow separation angle and drag force acting on a suspended sphere in a cylindrical tube. The heat transfer is validated by comparing the computed results with the standard heat transfer correlations predictions. The model is used to simulate flow and heat transfer under a variety of design conditions. The effect of internal heat generation on the heat transfer in the gas core reactors is examined for a variety of power densities, 100 W/cc, 500 W/cc and 1000 W/cc. The maximum temperature, corresponding with the heat generation rates, are 2150 K, 2750 K and 3550 K, respectively. This analysis shows that the maximum temperature is strongly dependent on the value of heat generation rate. It also indicates that a heat generation rate higher than 1000 W/cc is necessary to maintain the gas temperature at about 3500 K, which is typical design temperature required to achieve high efficiency in the gas core reactors. The model is also used to predict the convective and radiation heat fluxes for the gas core reactors. The maximum value of heat flux occurs at the exit of the reactor core. Radiation heat flux increases with higher wall temperature. This behavior is due to the fact that the radiative heat flux is strongly dependent on wall temperature. This study also found that at temperature close to 3500 K the radiative heat flux is comparable with the convective heat flux in a uranium fluoride failed gas core reactor.

Anghaie, S.↗