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NASA NTRS2010

Chemical sensors using coated or doped carbon nanotube networks

Methods for using modified single wall carbon nanotubes ("SWCNTs") to detect presence and/or concentration of a gas component, such as a halogen (e.g., Cl.sub.2), hydrogen halides (e.g., HCl), a hydrocarbon (e.g., C.sub.nH.sub.2n+2), an alcohol, an aldehyde or a ketone, to which an unmodified SWCNT is substantially non-reactive. In a first embodiment, a connected network of SWCNTs is coated with a selected polymer, such as chlorosulfonated polyethylene, hydroxypropyl cellulose, polystyrene and/or polyvinylalcohol, and change in an electrical parameter or response value (e.g., conductance, current, voltage difference or resistance) of the coated versus uncoated SWCNT networks is analyzed. In a second embodiment, the network is doped with a transition element, such as Pd, Pt, Rh, Ir, Ru, Os and/or Au, and change in an electrical parameter value is again analyzed. The parameter change value depends monotonically, not necessarily linearly, upon concentration of the gas component. Two general algorithms are presented for estimating concentration value(s), or upper or lower concentration bounds on such values, from measured differences of response values.

Li, Jing↗

NASA NTRS2011

Coated or doped carbon nanotube network sensors as affected by environmental parameters

Li, Jing↗

NASA NTRS1977

Upper bound on the equilibrium concentration of atomic H in solid H2

A phenomenological rate process theory has been developed for the production, storage and recombination of atomic H free radicals in a tritium-impregnated solid H2 at temperatures in the range of about 0.1 to 4 K. In this paper it is shown that the theory requires a stringent upper bound on the equilibrium concentration of trapped atomic H, namely that it cannot exceed about 0.125%, even if the temperature is reduced to an arbitrary low value and a very strong magnetic field is applied to the tritium-impregnated H2 solid.

Rosen, G.↗

NASA NTRS2019

The Effect of Redox Conditions on Seismic Waves in Iron-Bearing Olivine: Implications for Understanding Planetary Interiros Through Seismilogy

Seismic data, inclusive of velocities and attenuation, can be utilized to elucidate the physical state of planetary interiors]. However, numerous micromechanical factors have been either experimentally demonstrated, or theoretically considered, to affect the propagation and dissipation of seismic energy within crystalline solids - including, but not limited to, changes in grain size, temperature, melt fraction, pressure and dislocation density. Thus, observed variations in seismic wave speeds and attenuation may be used to ultimately ‘map’ variations in physical properties, such as those listed above, within planetary bodies. But, in order to complete a successful inversion of seismic data into representations of physical properties, a first requirement is to obtain a fundamental laboratory based understanding of how each of these possible factors individually influences seismic waves. Here we conduct an experimental study with the initial objective to further understand one of the most commonly invoked, yet least studied, mechanisms that could alter intrinsic seismic wave attenuation: water content (occurring as chemically-bound hydroxyl). The historical basis for determining the effect of water on seismic properties was established predominantly through analogy with large-strain creep experiments conducted on olivine under water-saturated conditions. While these deformation experiments routinely demonstrate a weakening of olivine in the presence of water, they represent a fundamentally different deformation regime in comparison to the microstrains experienced due to a passing seismic wave. Thus, in order to directly assess the effects of water on seismic properties, small-strain experiments are required. Substantially modified seismic properties in the presence of water have been observed previously at low strains and low frequencies, but only in a single exploratory study conducted under water-saturated conditions. Thus, to properly test the theoretical predictions we conducted a systematic study of the seismic properties of olivine using low-frequency torsional oscillation on aggregates containing varying concentrations of bound hydroxyl, for the first time at under saturated conditions.

Cline, C. J., II↗

NASA NTRS1970

Study of permeability characteristics of membranes Quarterly report

Diffusive and electrical transport of KOH and dissolved ZnO through membrane bounded by concentrated KOH solution

Kwak, J. C. T.↗

NASA NTRS1988

Trapping Ne, Ar, Kr, and Xe in Si2O3 smokes

Simple Si2O3 smokes have been condensed at both low (less than 750 K) and high (greater than 1000 K) temperature at 35 torr H2 pressure in the presence of 0, 10, 100, and 1000 microns of a noble gas mixture containing Ne, Ar, Kr, and Xe. In general, both Ne and Ar are quite loosely bound in the smokes (6.0 x 10 to the -8th and 2.6 x 10 to the -4th ccSTP/g, respectively), and are degassed at temperatures below 1200 K. Both Kr and Xe are somewhat more strongly bound at concentrations of 1.0 x 10 to the -7th and 8.2 x 10 to the -8th ccSTP/g, respectively, and in addition show a double release with a second component at a temperature of about 1875 K. With the exception that Si2O3 smokes appear to show a particular affinity for argon, possibly due to an anomalous absorption of atmospheric argon, none of the other noble gases are found in sufficient concentration to explain the gases observed in meteorites as primary circumstellar condensates. However, this data in conjunction with observations of Honda et al. (1979) do seem to show a degree of dependence between noble gas retention and chemical composition.

Nuth, Joseph A., III↗

NASA NTRS1999

Oxidation of the skeletal muscle Ca2+ release channel alters calmodulin binding

This study presents evidence for a close relationship between the oxidation state of the skeletal muscle Ca2+ release channel (RyR1) and its ability to bind calmodulin (CaM). CaM enhances the activity of RyR1 in low Ca2+ and inhibits its activity in high Ca2+. Oxidation, which activates the channel, blocks the binding of 125I-labeled CaM at both micromolar and nanomolar Ca2+ concentrations. Conversely, bound CaM slows oxidation-induced cross-linking between subunits of the RyR1 tetramer. Alkylation of hyperreactive sulfhydryls (<3% of the total sulfhydryls) on RyR1 with N-ethylmaleimide completely blocks oxidant-induced intersubunit cross-linking and inhibits Ca2+-free 125I-CaM but not Ca2+/125I-CaM binding. These studies suggest that 1) the sites on RyR1 for binding apocalmodulin have features distinct from those of the Ca2+/CaM site, 2) oxidation may alter the activity of RyR1 in part by altering its interaction with CaM, and 3) CaM may protect RyR1 from oxidative modifications during periods of oxidative stress.

NASA Discipline Musculoskeletal↗

NASA NTRS1995

Quantitative remote sensing of ammonium minerals, Cedar Mountains, Esmeralda County, Nevada

Mineral-bound ammonium (NH4+) was discovered by the U.S. Geological Survey in the southern Cedar Mountains of Esmeralda County, Nevada in 1989. At 10 km in length, this site is 100 times larger than any previously known occurrence in volcanic rocks. The ammonium occurs in two hydrothermally altered, crystal-rich rhyolitic tuff units of Oligocene age, and is both structurally and stratigraphically controlled. This research uses Advanced Visible/Infrared Imaging Spectrometer (AVIRIS) data to quantitatively map the mineral-bound ammonium (buddingtonite) concentration in the altered volcanic rocks. Naturally occurring mineral-bound ammonium is fairly rare; however, it has been found to occur in gold-bearing hydrothermal deposits. Because of this association, it is thought that ammonium may be a useful too in exploration for gold and other metal deposits. Mineral-bound ammonium is produced when an ammonium ion (NH4+) replaces the alkali cation site (usually K+) in the crystal structure of silicate minerals such as feldspars, micas and clays. Buddingtonite is an ammonium feldspar. The ammonium originates in buried organic plant matter and is transported to the host rock by hydrothermal fluids. Ammonium alteration does not produce visible changes in the rock, and it is barely detectable with standard x-ray diffraction methods. It is clearly identified, however, by absorption features in short wave-infrared (SWIR) wavelengths (2.0 - 2.5 micrometers). The ammonium absorption features are believed to be caused by N-H vibrational modes and are analogous to hydroxyl (O-H) vibrational modes, only shifted slightly in wavelength. Buddingtonite absorption features in the near- and SWIR lie at 1.56, 2.02 and 2.12 micrometers. The feature at 2.12 micrometer is the strongest of the three and is the only one used in this study. The southern Cedar Mountains are sparsely vegetated and are an ideal site for a remote sensing study.

Baugh, William M.↗

NASA NTRS2019

Quantifying the Influence of Redox Conditions on the Seismic Properties of Olivine

A series of eight olivine specimens were fabricated by hot-pressing at 1200 degrees Celsius and 300 megapascals (MPa). Each hot-pressed specimen was then wrapped in Pt, Ni or NiFe foil to vary oxygen fugacity (fO2), and interrogated via forced torsional oscillation. Mechanical testing was conducted at 10 oscillation periods between 1 and 1000 seconds, at a confining pressure of 200 MPa, during a slow staged-cooling from a maximum temperature of 1200 degrees Celsius to room temperature. After mechanical testing, each specimen was axially sectioned and EBSD (Electron BackScatter Diffraction) was used for the determination of the representative grain size, and grain size distribution of each sample. In addition, each longitudinal section was mapped via FTIR (Fourier Transform InfraRed spectroscopy) to determine the spatial distribution and concentrations of chemically bound and molecular water. Amongst these specimens, chemically bound ‘water’ contents were observed to vary between 0 and 1150 atom ppm (parts per million) H/Si, and molecular water concentrations varied between 0 and 245 atom ppm H/Si. Our forced-oscillation results demonstrate that the measured magnitude of anelastic relaxation within the experimental ‘window’ of oscillation periods is unrelated to the water content. Rather, a relationship was observed between the magnitude of anelastic relaxation and the prevailing redox conditions, which is influenced by the choice of metal sleeving used during the mechanical test. Further, regardless of water content or metal sleeving, each specimen exhibits coupled variations in shear modulus and dissipation within the observational window, indicative of ‘high-temperature background’ behavior, that can be described by a Burgers-type model. During initial fitting of the Burgers models, the unrelaxed shear modulus at a reference temperature of 900 degrees Celsius (G (sub UR)) and the temperature derivative of the unrelaxed shear modulus (dG (sub U)/dT), were treated as adjustable parameters. For all Fe-bearing olivine samples (but not a hydrous and oxidized Fe-free sample) we observe deficits of G (sub UR), and increased values of dG (sub U)/dT, relative to the expected elastic (anharmonic) behavior of Fo90 olivine. This behavior is indicative of anelastic relaxation occurring at shorter periods than observable within the ‘window’ of oscillation periods used in the mechanical test. Moving towards a comprehensive seismologically applicable Burgers model, which includes this newly observed effect of redox conditions on anelastic relaxation, we will present our progress in reconciling truly anharmonic and elastic behavior of Fo (sub 90) olivine with our observed forced-oscillation data.

Cline, Christopher, II↗

NASA NTRS2019

The Influence of Redox Conditions on the Seismic Properties of Polycrystalline Olivine

Eight olivine specimens were fabricated by use of a solgel method and hot-pressing at 1200 degrees Centigrade and 300 megapascals (MPa) inside of welded Pt capsules. Each hot-pressed specimen was then recovered, precision ground, and wrapped in Pt, Ni or NiFe foil to vary oxygen fugacity (fO2) during the subsequent forced torsional oscillation measurements. Mechanical testing was conducted at 10 oscillation periods between 1 and 1000 seconds, at a confining pressure of 200 MPa, during a slow staged-cooling from a maximum temperature of 1200 degrees Centigrade down to room temperature. After mechanical testing, each specimen was axially sectioned and EBSD (Electron BackScatter Diffraction) was used for the determination of the representative grain size, and grain size distribution of each sample. In addition, each longitudinal section was mapped via FTIR (Fourier Transform Infrared Spectroscopy) to determine the spatial distribution and concentrations of chemically bound and molecular water. Amongst these eight specimens, chemically bound ‘water’ contents were observed to vary between 0 and 1150 atom parts per million (ppm) H/Si, and molecular water concentrations varied between 0 and 245 atom ppm H/Si. Our forced-oscillation results demonstrate that the measured magnitude of anelastic relaxation within the experimental ‘window’ of oscillation periods is unrelated to the water content. Rather, a relationship was observed between the magnitude of anelastic relaxation and the prevailing redox conditions, which is influenced by the choice of metal sleeving used during the mechanical test. Further, regardless of water content or metal sleeving, each specimen exhibits coupled variations in shear modulus and dissipation within the observational window, indicative of ‘high-temperature background’ behavior, that can be described by a Burgers-type model. During initial fitting of the Burgers models, the unrelaxed shear modulus at a reference temperature of 900°C (elastic unloading/reloading shear modulus G (sub UR)) and the temperature derivative of the unrelaxed shear modulus (dGU/dT), were treated as adjustable parameters. For all Fe-bearing olivine samples we observe deficits of G (sub UR) and increased values of dGU/dT, relative to the expected elastic (anharmonic) behavior for Fo (Forsterite content percentage) (sub 90) olivine. This behavior is indicative of anelastic relaxation occurring at shorter periods than observable within the ‘window’ of oscillation periods used in the mechanical test. Moving towards a comprehensive and seismologically applicable Burgers model, which includes this newly observed effect of redox conditions on anelastic relaxation, we will present our progress on reconciling truly anharmonic and elastic behavior of Fo (sub 90) olivine with our observed forced-oscillation data.

Cline, C. J., II↗

NASA NTRS1984

On archaebacterial ATPase from Halobacterium saccharovorum

The energy transducing ATPase from Halobacterium saccharovorum was studied in order to define the origin of energy transducing systems. The ATPase required high salt concentration (4M NaCl) for activity; activity was rapidly lost when NaCl was below 1 Molar. At low salt concentration, the membrane bound ATPase activity could be stabilized in presence of spermine. However, following solubilization spermine was ineffective. Furthermore, F1 ATPase activity was stabilized by ammonium sulfate even when the NaCl concentration was less than 1 Molar. These studies suggest that stabilization by hydrophobic interactions preceded ionic ones in the evolution of the energy transducing ATPases.

Kristjansson, H.↗

NASA NTRS1995

Molecular indicators for palaeoenvironmental change in a Messinian evaporitic sequence (Vena del Gesso, Italy). II: High-resolution variations in abundances and 13C contents of free and sulphur-bound carbon skeletons in a single marl bed

The extractable organic matter of 10 immature samples from a marl bed of one evaporitic cycle of the Vena del Gesso sediments (Gessoso-solfifera Fm., Messinian, Italy) was analyzed quantitatively for free hydrocarbons and organic sulphur compounds. Nickel boride was used as a desulphurizing agent to recover sulphur-bound lipids from the polar and asphaltene fractions. Carbon isotopic compositions (delta vs PDB) of free hydrocarbons and of S-bound hydrocarbons were also measured. Relationships between these carbon skeletons, precursor biolipids, and the organisms producing them could then be examined. Concentrations of S-bound lipids and free hydrocarbons and their delta values were plotted vs depth in the marl bed and the profiles were interpreted in terms of variations in source organisms, 13 C contents of the carbon source, and environmentally induced changes in isotopic fractionation. The overall range of delta values measured was 24.7%, from -11.6% for a component derived from green sulphur bacteria (Chlorobiaceae) to -36.3% for a lipid derived from purple sulphur bacteria (Chromatiaceae). Deconvolution of mixtures of components deriving from multiple sources (green and purple sulphur bacteria, coccolithophorids, microalgae and higher plants) was sometimes possible because both quantitative and isotopic data were available and because either the free or S-bound pool sometimes appeared to contain material from a single source. Several free n-alkanes and S-bound lipids appeared to be specific products of upper-water-column primary producers (i.e. algae and cyanobacteria). Others derived from anaerobic photoautotrophs and from heterotrophic protozoa (ciliates), which apparently fed partly on Chlorobiaceae. Four groups of n-alkanes produced by algae or cyanobacteria were also recognized based on systematic variations of abundance and isotopic composition with depth. For hydrocarbons probably derived from microalgae, isotopic variations are well correlated with those of total organic carbon. A resistant aliphatic biomacromolecule produced by microalgae is, therefore, probably an important component of the kerogen. These variations reflect changes in the depositional environment and early diagenetic transformations. Changes in the concentrations of S-bound lipids induced by variations in conditions favourable for sulphurization were discriminated from those related to variations in primary producer assemblages. The water column of the lagoonal basin was stratified and photic zone anoxia occurred during the early and middle stages of marl deposition. During the last stage of the marl deposition the stratification collapsed due to a significant shallowing of the water column. Contributions from anaerobic photoautotrophs were apparently associated with variations in depth of the chemocline.

Non-NASA Center↗

NASA NTRS2003

Quantitating Iron in Serum Ferritin by Use of ICP-MS

A laboratory method has been devised to enable measurement of the concentration of iron bound in ferritin from small samples of blood (serum). Derived partly from a prior method that depends on large samples of blood, this method involves the use of an inductively-coupled-plasma mass spectrometer (ICP-MS). Ferritin is a complex of iron with the protein apoferritin. Heretofore, measurements of the concentration of serum ferritin (as distinguished from direct measurements of the concentration of iron in serum ferritin) have been used to assess iron stores in humans. Low levels of serum ferritin could indicate the first stage of iron depletion. High levels of serum ferritin could indicate high levels of iron (for example, in connection with hereditary hemochromatosis an iron-overload illness that is characterized by progressive organ damage and can be fatal). However, the picture is complicated: A high level of serum ferritin could also indicate stress and/or inflammation instead of (or in addition to) iron overload, and low serum iron concentration could indicate inflammation rather than iron deficiency. Only when concentrations of both serum iron and serum ferritin increase and decrease together can the patient s iron status be assessed accurately. Hence, in enabling accurate measurement of the iron content of serum ferritin, the present method can improve the diagnosis of the patient s iron status. The prior method of measuring the concentration of iron involves the use of an atomic-absorption spectrophotometer with a graphite furnace. The present method incorporates a modified version of the sample- preparation process of the prior method. First, ferritin is isolated; more specifically, it is immobilized by immunoprecipitation with rabbit antihuman polyclonal antibody bound to agarose beads. The ferritin is then separated from other iron-containing proteins and free iron by a series of centrifugation and wash steps. Next, the ferritin is digested with nitric acid to extract its iron content. Finally, a micronebulizer is used to inject the sample of the product of the digestion into the ICPMS for analysis of its iron content. The sensitivity of the ICP-MS is high enough to enable it to characterize samples smaller than those required in the prior method (samples can be 0.15 to 0.60 mL).

Smith, Scott M.↗

NASA NTRS2003

Numerical Simulations of Silverpit Crater Collapse

The Silverpit crater is a recently discovered, 60-65 Myr old complex crater, which lies buried beneath the North Sea, about 150 km east of Britain. High-resolution images of Silverpit's subsurface structure, provided by three-dimensional seismic reflection data, reveal an inner-crater morphology similar to that expected for a 5-8 km diameter terrestrial crater. The crater walls show evidence of terracestyle slumping and there is a distinct central uplift, which may have produced a central peak in the pristine crater morphology. However, Silverpit is not a typical 5-km diameter terrestrial crater, because it exhibits multiple, concentric rings outside the main cavity. External concentric rings are normally associated with much larger impact structures, for example Chicxulub on Earth, or Orientale on the Moon. Furthermore, external rings associated with large impacts on the terrestrial planets and moons are widely-spaced, predominantly inwardly-facing, asymmetric scarps. However, the seismic data show that the external rings at Silverpit represent closely-spaced, concentric fault-bound graben, with both inwardly and outwardly facing faults-carps. This type of multi-ring structure is directly analogous to the Valhalla-type multi-ring basins found on the icy satellites. Thus, the presence and style of the multiple rings at Silverpit is surprising given both the size of the crater and its planetary setting.

Collins, G. S.↗

NASA NTRS1976

The direct measurement of nitric oxide concentration in the upper atmosphere by a rocket-borne chemiluminescent detector

The paper describes a rocket-borne chemiluminescent NO detector and gives some NO mixing ratios in the altitude range from 42 to 60 km calculated on the basis of data obtained from this instrument. The mixing ratios were calculated from the observed counting rates on the assumption of a standard atmospheric pressure profile and the known vehicle velocity profile. The NO mixing ratio decreased from 4.2 billionths at 42 km to 2.2 billionths at 50 km, and then increased to 5.2 billionths at 60 km. The results are deemed accurate to within 20% and may be viewed as upper bounds on nitric oxide concentration in the absence of any NO loss processes.

Mason, C. J.↗

NASA NTRS1975

Effect of fuel properties on performance of a single aircraft turbojet combustor

The performance of a single-can JT8D combustor was investigated with a number of fuels exhibiting wide variations in chemical composition and volatility. Performance parameters investigated were combustion efficiency, emissions of CO, unburned hydrocarbons and NOx, as well as liner temperatures and smoke. At the simulated idle condition no significant differences in performance were observed. At cruise, liner temperatures and smoke increased sharply with decreasing hydrogen content of the fuel. No significant differences were observed in the performance of an oil-shale derived JP-5 and a petroleum-based Jet A fuel except for emissions of NOx which were higher with the oil-shale JP-5. The difference is attributed to the higher concentration of fuel-bound nitrogen in the oil-shale JP-5.

Butze, H. F.↗

NASA NTRS1975

Effect of fuel properties on performance of a single aircraft turbojet combustor

Butze, H. F.↗

NASA NTRS1973

Condensation in CO2 free jet expansions. I - Dimer formation.

A theoretical and experimental investigation of the kinetics of CO2 dimer formation in the adiabatically expanding core of a free jet expansion has been carried out. The theoretical analysis is based on dimer formation by an efficient termolecular process and dimer destruction by bimolecular collisions. Account is taken of the expected variation of the specific heat ratio during the expansion and of the effective increase in the termolecular collision rate at low temperatures due to the presence of loosely bound orbiting pairs. Experimental dimer concentrations were measured mass spectrometrically by forming a molecular beam from the expanded gas mixture after the onset of molecular flow. Observed dimer concentrations, for a range of pre-expansion conditions of 400 to 900 torr pressure and room temperature, are in good agreement with the theoretical analysis, provided that account is taken of the effect of loosely bound orbiting pairs at low temperatures.

Dorfeld, W. G.↗