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At least 19 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS1982

Forces acting on free carriers in semiconductors of inhomogeneous composition I, II

An investigation shows that the extended Wannier-Slater theorem with its position-dependent effective mass m cannot be considered a viable description of a semiconductor with compositional changes. The correct description of the behavior of the electron or hole flow in semiconductors in which the chemical composition changes gradually from position to position is more difficult. It is necessary to find a model Hamiltonian. This model Hamiltonian is to some extent arbitry, but it must be representative of a homogeneous sample. The difference between the true and the model Hamiltonian should be small in the sense that this difference may be considered a perturbation. However, a Hamiltonian with the required specifications can always be found provided that the compositional inhomogeneities do not change drastically over the distances of interest.

Von Roos, O.↗
NASA NTRS1990

The effects of compositional inhomogeneities and fractal dimension on the optical properties of astrophysical dust

Mathis and Whiffen (1989) have recently suggested that interstellar dust particles are fluffy aggregates of submicron-size particles composed of various astronomical minerals. These dust particles should exhibit optical properties that are quite different from standard dust, characterized by spherical particles of various homogeneous mineral composition. In this paper, the discrete dipole approximation (DDA) method is used to examine the effects of chemical inhomogeneities and spatial structure on the optical properties of interstellar Mathis-Whiffen-type dust particles. The spatial structure of the dust is represented by its fractal dimension, and the chemical inhomogeneities are simulated by randomly assigning the composition of the occupied sites in the structure to be either carbon or silicate. It is found that compositional inhomogeneities are the dominant parameter affecting the shape of the 9.7 and 18 micron silicate bands. Some bands-shape variations can be attributed to the fractal dimension of the dust. The results derived here can be used to explain or constrain variations in these parameters among various astronomical objects.

Bazell, David↗
NASA NTRS1981

Compositional inhomogeneities in a single Icelandic tholeiite flow

New trace element analyses of 25 basalt samples from a vertical traverse in an 11 m thick flow of Icelandic tholeiite show compositional differences which exceed analytical uncertainties and are random with respect to height. These variations suggest a short-range segregation model in which the amounts of phenocrysts, groundmass materials, and residual liquid vary randomly in different samples of the flow; a least-squares method is applied to determine if these variations reflect different proportions of crystallizing phases and residual liquid. Monte Carlo computations indicate that short-range segregation results in inhomogeneity of a magnitude of interflow compositional differences; this causes incoherence in elements with different geochemical behaviors while preserving coherence in elements of similar behavior.

Lindstrom, M. M.↗
NASA NTRS1994

The possibility of forming an inhomogeneous Sun and the solar neutrino effect

Recent observations confirm that the flux of neutrinos from the interior of the Sun is significantly less than what is expected on the basis of solar models. It has long been known that a low neutrino flux could result from a temperature in the Sun's core lower than the approximately 1.5 x 10(exp 7) K central temperature given by standard solar models. A low central temperature could occur if the solar interior were depleted in the so-called metals -- atomic species heavier than helium -- resulting in lower internal opacity. In this case, chemical abundances measured in the solar convection zone would be unrepresentative of the deep-interior abundances. The possibility of a compositionally inhomogeneous Sun has usually been discarded on the basis of cosmogonical arguments against the formation of such nonhomogeneity. This paper suggests that compositional nonhomogeneity could have arisen through unremarkable physical processes during the formation of the Sun, and that a compositionally inhomogeneous Sun remains a viable possibility for investigation of the solar neutrino problem.

Levy, E. H.↗
NASA NTRS1984

Experimental and Theoretical Studies of Moisture and Temperature Effects on the Mechanical Properties of Graphite/Epoxy Laminates and Neat Resins

The properties of high performnce composites which are strongly dependent on the physical properties of the matrix resin were studied. Moisture adversely affect the properties of both neat epoxy resin and epoxy matrix composites. Inhomogeneous swelling as to the moisture degradation of mechanical properties, both in the neat resin and the composite. It is postulated that the postcuring process can change structure/moisture interactions and partially alleviate its adverse effects. The study is directed toward are understanding of the physical/mechanical/thermodynamic aspects of this problem.

Sternstein, S. S.↗
NASA NTRS1986

Pre-perihelion observations of Comet Halley at 2-13 microns

Between Nov. 8, 1985 and Jan. 13, 1986 comet Halley brightness was obtained as a function of time at 2.3, 3.6, 4.6, and 10.3 microns. Brightness outbursts were noted, an especially significant one beginning Jan. 10, 1986 and persisting for several days during which the IR brightness more than doubled. The heliocentric brightness indices for 2.3, 3.6, 4.6, and 10.3 microns are -5.7, -7.1, -8.5, and -6.2, respectively. Comet Halley's absolute magnitudes at these wavelengths are 7.3, 4.4, 2.8, and -1.8. The 4.6 to 10.3 micron color temperature dependence on heliocentric distance (R) is slightly less steep than the Rsup -1/2 expected theoretically. The albedo of the comet is 8% to 9%. Based on spectral differences between outbursts on Nov. 8, 1985 and Jan. 10 to 13, 1986, it is concluded that the comet displays composition inhomogeneities.

Lynch, David K.↗
NASA NTRS1986

Thin-film temperature sensors for gas turbine engines Problems and prospects

The erosion and corrosion of thermocouples used to measure the temperature in turbine engines are studied. Structural and metallurgical interactions and instabilities at thermocouple interfaces are analyzed. Consideration is given to the adhesion, dielectric quality, surface topography, and hardness of the thermal oxides; it is observed that the structural and thermoelectric stability of thin-film thermocouple elements depends on adhesion, surface topography, and dielectric strength. The electrical conductivity and impurity content of the oxide scale are evaluated. Methods for improving the adhesion of thermocouples on the alumina surfaces are described. Compositional inhomogeneities in the sensors and contamination of the thermocouple elements are examined. The fabrication of the thermocouples is discussed. It is noted that Al2O3 and Si3N4 are useful for developing stable thermocouple elements on the surface of the blades and vanes.

Budhani, R. C.↗
NASA NTRS1983

Influence of convection on the growth of crystals from solution

This is a review of the influence of convection on the growth of crystals from solution. The growth rate is increased by convection up to the point where interface kinetics becomes rate controlling. Compositional inhomogeneity and morphological instability (inclusion formation) are probably worse for gentle convection than for either no convection or for vigorous stirring. Stirring, particularly of crystal suspensions, can cause an orders of magnitude increase in the rate of formation of new crystals. This is called 'secondary nucleation'.

Wilcox, William R.↗
NASA NTRS1993

Characterization of convection related defects in II-VI compound semiconductors

The research carried out under NAG8-913, 'Characterization of Convection Related Defects in II-VI Compound Semiconductors', was aimed at exploration of the potential of axial magnetic fields for melt stabilization when applied in Bridgman geometry to the growth of HgMnTe. The thrust of the work was directed at the experimental establishment of the limits of magnetic melt stabilization during crystal growth and at the analytical verification of the effects of stabilization on critical materials properties. The data obtained indicate noticeable stabilization effects, particularly as far as the formation of microscopic compositional inhomogeneities is concerned. The effects of magnetic fields on precipitate formation are found to be minor. Magnetic field effects were investigated for both 'Bridgman' and 'travelling heater' geometries. The research was conducted during the period from May 22 to September 30, 1992.

Witt, August F.↗
NASA NTRS1994

Interactions between solidification and compositional convection in mushy layers

Mushy layers are ubiquitous during the solidification of alloys. They are regions of mixed phase wherein solid crystals are bathed in the melt from which they grew. The matrix of crystals forms a porous medium through which the melt can flow, driven either by external forces or by its own buoyancy in a gravitational field. Buoyancy-driven convection of the melt depends both on temperature gradients, which are necessary for solidification, and on compositional gradients, which are generated as certain components of the alloy are preferentially incorporated in the solid phase and the remaining components are expelled into the melt. In fully liquid regions, the combined action of temperature and concentration on the density of the liquid can cause various forms of double-diffusive convection. However, in the interior of mushy regions the temperature and concentration are thermodynamically coupled so only single-diffusive convection can occur. Typically, the effect of composition on the buoyancy of the melt is much greater than the effect of temperature, and thus convection in mushy layers in driven primarily by the computational gradients within them. The rising interstitial liquid is relatively dilute, having come from colder regions of the mushy layer, where the liquidus concentration is lower, and can dissolve the crystal matrix through which it flows. This is the fundamental process by which chimneys are formed. It is a nonlinear process that requires the convective velocities to be sufficiently large, so fully fledged chimneys (narrow channels) might be avoided by means that weaken the flow. Better still would be to prevent convection altogether, since even weak convection will cause lateral, compositional inhomogeneities in castings. This report outlines three studies that examine the onset of convection within mushy layers.

Worster, M. Grae↗
NASA NTRS1996

Turbulent flame propagation in partially premixed flames

Turbulent premixed flame propagation is essential in many practical devices. In the past, fundamental and modeling studies of propagating flames have generally focused on turbulent flame propagation in mixtures of homogeneous composition, i.e. a mixture where the fuel-oxidizer mass ratio, or equivalence ratio, is uniform. This situation corresponds to the ideal case of perfect premixing between fuel and oxidizer. In practical situations, however, deviations from this ideal case occur frequently. In stratified reciprocating engines, fuel injection and large-scale flow motions are fine-tuned to create a mean gradient of equivalence ratio in the combustion chamber which provides additional control on combustion performance. In aircraft engines, combustion occurs with fuel and secondary air injected at various locations resulting in a nonuniform equivalence ratio. In both examples, mean values of the equivalence ratio can exhibit strong spatial and temporal variations. These variations in mixture composition are particularly significant in engines that use direct fuel injection into the combustion chamber. In this case, the liquid fuel does not always completely vaporize and mix before combustion occurs, resulting in persistent rich and lean pockets into which the turbulent flame propagates. From a practical point of view, there are several basic and important issues regarding partially premixed combustion that need to be resolved. Two such issues are how reactant composition inhomogeneities affect the laminar and turbulent flame speeds, and how the burnt gas temperature varies as a function of these inhomogeneities. Knowledge of the flame speed is critical in optimizing combustion performance, and the minimization of pollutant emissions relies heavily on the temperature in the burnt gases. Another application of partially premixed combustion is found in the field of active control of turbulent combustion. One possible technique of active control consists of pulsating the fuel flow rate and thereby modulating the equivalence ratio (Bloxsidge et al. 1987). Models of partially premixed combustion would be extremely useful in addressing all these questions related to practical systems. Unfortunately, the lack of a fundamental understanding regarding partially premixed combustion has resulted in an absence of models which accurately capture the complex nature of these flames. Previous work on partially premixed combustion has focused primarily on laminar triple flames. Triple flames correspond to an extreme case where fuel and oxidizer are initially totally separated (Veynante et al. 1994 and Ruetsch et al. 1995). These flames have a nontrivial propagation speed and are believed to be a key element in the stabilization process of jet diffusion flames. Different theories have also been proposed in the literature to describe a turbulent flame propagating in a mixture with variable equivalence ratio (Muller et al. 1994), but few validations are available. The objective of the present study is to provide basic information on the effects of partial premixing in turbulent combustion. In the following, we use direct numerical simulations to study laminar and turbulent flame propagation with variable equivalence ratio.

Poinsot, T.↗
NASA NTRS1998

Hot Corrosion of Single-Crystal NiAl-X Alloys

Several single-crystal NiAl-X alloys (X=Hf, Ti, Cr, Ga) underwent hot corrosion testing in a Mach 0.3 burner rig at 900 deg. C for 300 1-hr cycles. The surface morphology after testing consisted of either mounds or an inward, uniform-type of attack which preserved surface features. It was observed that the surface morphology was affected by the surface preparation treatments. Microstructurally, the hot corrosion attack initiated as pits but evolved to a rampant attack consisting of the rapid inward growth of Al2O3. Electropolishing and chemical milling produced many pits and grooves on the surface. However, the presence of pits and grooves did not appear to strongly influence the hot corrosion response. Attack on many samples was strongly localized which was attributed to compositional inhomogeneity within the samples. It was found that increasing the Ti content from 1% to 5 % degraded the hot corrosion response of these alloys. In contrast, the addition of 1-2% Cr reduced the susceptibility of these alloys to hot corrosion attack and negated the deleterious effect of the 4-5% Ti addition.

Nesbitt, James A.↗
NASA NTRS1996

Nonlinear Response of Layer Growth Dynamics in the Mixed Kinetics-Bulk-Transport Regime

In situ high-resolution interferometry on horizontal facets of the protein lysozyme reveal that the local growth rate R, vicinal slope p, and tangential (step) velocity v fluctuate by up to 80% of their average values. The time scale of these fluctuations, which occur under steady bulk transport conditions through the formation and decay of step bunches (macrosteps), is of the order of 10 min. The fluctuation amplitude of R increases with growth rate (supersaturation) and crystal size, while the amplitude of the v and p fluctuations changes relatively little. Based on a stability analysis for equidistant step trains in the mixed transport-interface-kinetics regime, we argue that the fluctuations originate from the coupling of bulk transport with nonlinear interface kinetics. Furthermore, step bunches moving across the interface in the direction of or opposite to the buoyancy-driven convective flow increase or decrease in height, respectively. This is in agreement with analytical treatments of the interaction of moving steps with solution flow. Major excursions in growth rate are associated with the formation of lattice defects (striations). We show that, in general, the system-dependent kinetic Peclet number, Pe(sub k) , i.e., the relative weight of bulk transport and interface kinetics in the control of the growth process, governs the step bunching dynamics. Since Pe(sub k) can be modified by either forced solution flow or suppression of buoyancy-driven convection under reduced gravity, this model provides a rationale for the choice of specific transport conditions to minimize the formation of compositional inhomogeneities under steady bulk nutrient crystallization conditions.

Vekilov, Peter G.↗
NASA NTRS2000

Crystal Growth of ZnSe and Related Ternary Compound Semiconductors by Vapor Transport

Interest in optical devices which can operate in the visible spectrum has motivated research interest in the II-VI wide band gap semiconductor materials. The recent challenge for semiconductor opto-electronics is the development of a laser which can operate at short visible wavelengths. In the past several years, major advances in thin film technology such as molecular beam epitaxy and metal organic chemical vapor deposition have demonstrated the applicability of II-VI materials to important devices such as light-emitting diodes, lasers, and ultraviolet detectors. With an energy gap of 2.7 eV at room temperature, and an efficient band- to-band transition, ZnSe has been studied extensively as the primary candidate for a blue light emitting diode for optical displays, high density recording, and military communications. By employing a ternary or quaternary system, the energy band gap of II-VI materials can be tuned to a specific range. While issues related to the compositional inhomogeneity and defect incorporation are still to be fully resolved, ZnSe bulk crystals and ZnSe-based heterostructures such as ZnSe/ZnSeS, ZnSe/ZnCdSe and ZnCdSe/ZnSeS have showed photopumped lasing capability in the blue-green region at a low threshold power and high temperatures. The demonstration of its optical bistable properties in bulk and thin film forms also make ZnSe a possible candidate material for the building blocks of a digital optical computer. Despite this, developments in the crystal growth of bulk H-VI semiconductor materials has not advanced far enough to provide the low price, high quality substrates needed for the thin film growth technology.

Su, Ching-Hua↗
NASA NTRS2004

Ar-39 - Ar-40 Dating of Unusual Eucrite NWA-011: Is it from Vesta?

Basaltic meteorite NWA-011 is similar to eucrites in many aspects, but its oxygen isotopic composition lies far off the oxygen fractionation line defined by eucrites. It was suggested that NWA011 may have derived from a different parent body from that of eucrites, which are thought to derive from the asteroid Vesta. Some other eucrites also show small anomalous oxygen compositions. This suggests that for all eucrites to derive from Vesta, it must be compositionally inhomogeneous. Some workers have speculated whether early, large impactors on Vesta might have contributed the anomalous oxygen.

Bogard, D. D.↗
NASA NTRS2007

Flash Diffusivity Technique Applied to Individual Fibers

A variant of the flash diffusivity technique has been devised for determining the thermal diffusivities, and thus the thermal conductivities, of individual aligned fibers. The technique is intended especially for application to nanocomposite fibers, made from narrower fibers of polyphenylene benzobisthiazole (PBZT) and carbon nanotubes. These highly aligned nanocomposite fibers could exploit the high thermal conductivities of carbon nanotubes for thermal-management applications. In the flash diffusivity technique as practiced heretofore, one or more heat pulse(s) is (are) applied to the front face of a plate or disk material specimen and the resulting time-varying temperature on the rear face is measured. Usually, the heat pulse is generated by use of a xenon flash lamp, and the variation of temperature on the rear face is measured by use of an infrared detector. The flash energy is made large enough to produce a usefully high temperature rise on the rear face, but not so large as to significantly alter the specimen material. Once the measurement has been completed, the thermal diffusivity of the specimen is computed from the thickness of the specimen and the time dependence of the temperature variation on the rear face. Heretofore, the infrared detector used in the flash diffusivity technique has been a single-point detector, which responds to a spatial average of the thermal radiation from the rear specimen surface. Such a detector cannot distinguish among regions of differing diffusivity within the specimen. Moreover, two basic assumptions of the thermaldiffusivity technique as practiced heretofore are that the specimen is homogeneous and that heat flows one-dimensionally from the front to the rear face. These assumptions are not valid for an inhomogeneous (composite) material.

Mayeaux, Brian↗