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At least 19 records

Neutral cometary atmospheres. III - Acceleration of cometary CN by solar radiation pressure

The acceleration of cometary CN radicals due to solar radiation pressure has been determined by fitting Monte Carlo models to nine observed sunward-tailward pairs of brightness profiles of the (0-0) band of CN at 3883 A. The profiles were determined from spectrograms of comets Bennett 1970 II and West 1976 VI. The values of the observed acceleration agree with those computed from resonance fluorescence calculations to within the expected uncertainties. This provides an independent confirmation of the identification of the observed scale lengths with the photochemical lifetimes and velocities associated with the production of observed cometary CN by the photodissociation of HCN. The ratio of the intensity of the (0-1) band of CN at 4216 A to the (0-0) band at 3883 A has been determined from spectrograms of comet West, and is compared with theoretical values.

Combi, M. R.

Numerical simulation of cometary nuclei. III - Internal temperatures of cometary nuclei

The thermal diffusion equation for the internal temperature of cometary nuclei is exactly solved by means of a one-dimensional numerical model in order to shed light on the complex behavior of these temperatures with varying orbital and thermal parameters and in order to consider possible cometary nucleus thermal evolution targets for comet rendezvous and/or sample-return missions. The concept of 'new' and 'old' comets, classified in terms of how many passages around the sun have been made, may take on new meaning in view of the present demonstration that differences in eccentricity between two comets having the same period and number of apparitions may yield significantly different internal temperature profiles.

Herman, Gary

End products of cometary evolution - Cometary origin of earth-crossing bodies of asteroidal appearance

The present state of the understanding of the dynamic mechanisms under which the orbits of some comets evolve into those observed for Apollo-Amor objects is reviewed. Observed Jupiter-family objects of asteroidal appearance, e.g., 1983SA, are much more likely to be of cometary rather than asteroidal origin. 'Decoupling' is facilitated by several mechanisms: perturbations by terrestrial planets, perturbations by Jupiter and the other giant planets, and nongravitational orbital changes caused by the loss of gas and dust from the comet. The dynamical time scale for decoupling is argued to be 100,000-1,000,000 yr, and almost all decoupled comets are likely to be of asteroidal appearance. Estimates can be made of the number of cometary Apollo-Amor 'asteroids', the observed number of earth-crossing active and inactive short-period comets, and the production rate of short-period comets. These estimates are compatible with other theoretical and observational inferences that suggest the presence of a significant population of Apollo objects that formerly were active comets.

Wetherill, G. W.

Cometary dust: A thermal criterion to identify cometary samples among the collected interplanetary dust

The relative proportions of the cometary and the asteroidal contributions to the interplanetary dust have not yet been definitively established. These proportions may vary with time as a result of major catastrophic disruptions in the main belt or the appearance of fresh, active comets. Dermott et al. and Reach suggest the debris from catastrophic collisions in the main belt can account for most of the zodiacal cloud particles. Earth collection of these asteroidal particles is strongly favored by near-Earth gravitational enhancement. However, comets are observed to produce interplanetary dust particles (IDP's), and the identification of cometary IDP's would allow inferences of the compositions, mineralogies, and physical properties of the comets. The peak temperatures reached by IDP's on atmospheric entry indicate the distribution of IDP velocities. Each IDP contains many internal thermometers: minerals that transform above certain temperatures, volatile elements that are lost sequentially with increasing temperatures, solar flare tracks that anneal at different temperatures in different minerals, and solar-implanted noble gases that outgas progressively with temperature. Thus, limits on the peak temperature reached by each IDP on Earth atmospheric entry can be set. Other aspects of this investigation are covered.

Flynn, George J.

Lower hybrid turbulence at cometary bow wave and acceleration of cometary protons

The wave measurements at the spacecraft encounters with Comet Halley have shown intense wave activity at the lower hybrid frequency. The excitation of the lower hybrid instability by the pickup cometary ions (protons and water group) in the bow wave region and the quasi-linear diffusion of the ions in these fluctuations are discussed. The quasi-linear diffusion of the pickup protons takes place over a scale length shorter than that of the heavier water group ions. This enhances damping of the waves by protons, and when the pickup proton density is large enough, it can result in the saturation of the instability as this damping balances the heavy ion driven growth. The observed electric field amplitude and the scale length of proton relaxation are in agreement with the theory. For small pickup proton density the instability can saturate due to the wave energy cascade arising from the modulation instability of the large-amplitude lower hybrid waves. This saturation mechanism leads to electron acceleration and suprathermal tail formation.

Shapiro, V. D.

Ion bombardment experiments suggesting an origin for organic particles in pre-cometary and cometary ices

During the Giotto and Vega encounters with Comet Halley both organic particles called CHON and energetic ions were detected. The acceleration of ions to hundreds of keV in the vicinity of the bow shock and near the nucleus may be a demonstration of a situation occurring in the early solar system (perhaps during the T Tauri stage) that led to the formation of organic particles only now released. Utilizing a Van de Graaff accelerator and a target chamber having cryogenic and mass spectrometer capabilities, frozen gases were bombarded at 10 K with 175 keV protons with the result that fluffy solid material remains after sublimation of the ice. Initial experiments were carried out with a gas mixture in parts of 170 carbon monoxide, 170 argon, 25 water, 20 nitrogen, and 15 methane formulated to reflect an interstellar composition in experiments involving the freezing out of the products of a plasma. The plasma experiments resulted in a varnish-like film residue that exhibited luminescence when excited with ultraviolet radiation, while the ion bombardment created particulate material that was not luminescent.

Wdowiak, Thomas J.

Laboratory simulation of the photoprocessing and warm-up of cometary and pre-cometary ices: Production of complex organic molecules

The recent missions to Comet Halley detected large quantities of organic material on grains as well as organic molecules in the gas phase. A possible origin of these materials is the energetic processing of ice mantles on the grains prior to comet formation, either in the pre-solar nebula or the interstellar medium. This process was simulated in the laboratory by depositing interstellar ice analogs (H2O/CH3OH/CO/NH3) on a cold (10 K) substrate with simultaneous UV irradiation. The material evaporating during warm-up of the photolyzed ice as well as the residue remaining at room temperature was analyzed by a number of techniques. It was found that a large number of organic molecules of various complexity are synthesized during the simulation process, stressing the possible significance of UV photolysis for producing the organic Comet material.

Schutte, W. A.

Laboratory simulation of the photoprocessing and warm-up of cometary and pre-cometary ices - Production and analysis of complex organic molecules

The recent missions to Comet Halley detected large quantities of organic material on grains as well as organic molecules in the gas phase. A possible origin of these materials is the energetic processing of ice mantles on the grains prior to comet formation, either in the pre-solar nebula or the interstellar medium. This process was simulated in the laboratory by depositing interstellar ice analogs (H2O/CH3OH/CO/NH3) on a cold (10 K) substrate with simultaneous UV irradiation. The material evaporating during warm-up of the photolyzed ice as well as the residue remaining at room temperature was analyzed by a number of techniques. It was found that a large number of organic molecules of various complexity are synthesized during the simulation process, stressing the possible significance of UV photolysis for producing the organic Comet material.

Schutte, W. A.

Ion Bombardment Experiments Suggesting an Origin for Organic Particles in Pre-Cometary and Cometary Ices

Simple molecules frozen as mantles of interstellar and circumstellar grains and incorporated into comets are subjected to ion bombardment in the form of cosmic rays, stellar flares, stellar winds, and ions accelerated in stellar wind shocks. The total expected dosage for the variety of situations range from 10 eV/molecule for interplanetary dust subjected to solar flares to 10(exp 6) eV/molecule for material in the T Tauri environment. Utilizing a Van de Graaff accelerator and a target chamber having cryogenic and mass spectrometer capabilities, we have bombarded frozen gases in the temperature range of 10 K to 30 K with 175 keV protons. After irradiation, removal of the ice by sublimation at an elevated temperature in vacuum reveals a fluffy residue. These experiments suggest that processes resulting in the formation of organic particles found in the coma of Comet Halley, "CHON", may have included ion bombardment. Also, the moderate energy (100 keV to 500 keV) shock accelerated ion environment of bipolar outflow of stars in the planetary nebula stage such as the Red Rectangle, could produce complex molecular species which emit the observed unidentified infrared bands at 3.3 micro-m, 6.2 micro-m, 7.7 micro-m, 8.6 micro-m, and 11.3 micro-m.

Wdowiak, Thomas J.

Ryugu-Like Phyllosilicate Clast from A Giant Cluster IDP of Probable Cometary Origin: Evidence for Material Exchange Between Asteroidal and Cometary Regions

The presence of hydrous minerals in comets is currently an open question. They were commonly produced inside primitive meteorite parent bodies but apparently not inside the active comets that never contained liquid water. Despite examination of hundreds of particles returned from the Jupiter Family comet Wild 2 by the Stardust(SD) spacecraft, no phyllosilicates have yet been found. Near IR spectra obtained by the Rosetta spacecraft of short-period comet 67P Churyumov-Gerasimenko (67P CG) similarly did not reveal the presence of phyllosilicate minerals. IR spectral features in ejecta from comet Temple 1were interpreted as hydrated minerals but this match is controversial. Studies of a giant cluster interplanetary dust particle (IDP) have demonstrated that the IDP has a large number of chemical and physical properties consistent with its derivation from a comet including 1) its porous aggregate morphology similar to fragile aggregate particles imaged from comet 67P CG, 2) an unequilibrated mineral assemblage, 3) mineral isotopic compositions similar to like minerals in comet Wild 2, 4) uncorrelated Fe-Mn ratios of olivines that mimic those from Wild 2, 5) high presolar silicate abundance [8] and 6) Kool grains which are observed in comet Wild 2 but not in chondrites. Our examination of 70+>5 μm fragments from the IDP have shown that it is overwhelmingly composed of anhydrous silicates. We have observed, however, a 5 x 15 μm porous aggregate fragment (LT10), which contains a rare phyllosilicate clast encased in anhydrous mineral and rock fragments. We conducted detailed TEM and O isotopic analyses of this particle to constrain its origin.

D J Joswiak

Chemical and Physical Properties of Cometary Dust

Cometary dust particles are best preserved remnants of the matter present at the onset of the formation of the Solar System. In Space missions, telescopic observations and laboratory analyses advanced the knowledge on the properties of cometary dust. the only samples certified with a cometary origin were returned by the Stardust space mission from comet 81P/Wild2. The “chondritic porous” (here called “chondritic anhydrous”) interplanetary dust particles (CA-IDPs) and micrometeorites (CP-MMs), and the ultracarbonaceous Antarctic MMs (UCAMMs) also show strong evidence for a cometary origin. The elemental composition of cometary dust is generally consistent with the chondritic (CI) composition, with the notable exception of elevated contents in carbon and nitrogen compared with CI. The organic matter of cometary dust is mixed with minor amounts of crystalline (at least 25% of the minerals) and amorphous mineral phases. The most abundant crystalline minerals are ferromagnesian silicates (olivine and low-Ca pyroxenes), but High-Ca pyroxenes, refractory minerals and Low Ni Fe sulfides are also present. The crystalline olivine and low-Ca pyroxene compositions can vary from their Mg-rich end-member (forsterite and enstatite) to relatively Fe-rich compositions. Refractory minerals as well as secondary minerals likeLIME (low-iron, Mn-enriched) olivines, unusual Fe sulfides or mineral aggregates of specific compositions like Kosmochloric high-Ca pyroxene and FeO-rich olivine - KOOL grains) are also found. The presence of carbonates in cometary dust is still debated, but a phyllosilicate-like phase was observed in a UCAMM. The abundance of pyroxene to olivine (in numbers) is larger than in primitive meteorites (e.g. the Px/Ol ratio is usually larger than 1). GEMS phases (glass with embedded metals and sulfides) are abundant in cometary dust, although not systematically found. Some of the organic matter present in cometary dust particle resembles the insoluble organic matter (IOM) present in primitive meteorites, but amorphous carbon and exotic (e.g. N-rich) organic phases are also present. The hydrogen isotopic composition of cometary dust particles (in the organic matter) is usually rich in deuterium, tracing a formation at very low temperatures, either in the protosolar cloud or in the outer regions of the protoplanetary disk. The presolar dust concentration in cometary dust can reach about 1%, which is the most elevated value observed in extraterrestrial samples. The size distribution of cometary dust in comet trails is well represented by a power-law distribution (differential size distribution) with a mean power index N typically ranging from -3 to -4. Polarimetric and light scattering studies of cometary dust suggest mixtures of porous agglomerates of sub-micrometer minerals with organic matter, which is compatible with the in situ analyses of 67P/Churyumov-Gerasimenko by MIDAS (Rosetta) and with the studies of it Stardust samples, CA-IDPs, CP-MMs and UCAMMs. Cometary dust particles have low tensile strength, and low density.

C. Engrand

Modelling, simulation and sounding of cometary nuclei; Proceedings of the International Workshop, Cagliari, Italy, May 28-30, 1991

The present workshop on the modeling, simulation, and sounding of cometary nuclei discusses the Rosetta comet-nucleus sample return mission, the importance of comet models in the design of the Rosetta mission, the challenge of sample acquisition in a cometary environment, and a simulation of Rosetta on-comet operations. Attention is given to HST observations of the inner coma of Comet Levy 1990c, cometary coma particulate modeling for the Rosetta mission aphelion rendezvous, recent gas flux modeling and applications of cometary nuclei, and the 3D time-dependent modeling of comet nucleus surface layers. Topics addressed include models of cometary nuclei and future space mission, the composition of cometary materials, experiments with cometary analogs at the DLR, and crust formation in cometary analogs. Also considered are gaseous products from VUV photolysis of cometary solids, cosmic ray modification of organic cometary matter as simulated by cyclotron irradiation, and KOSI comet simulation experiments.

Source record

Cometary Evolution: Clues on Physical Properties from Chondritic Interplanetary Dust Particles

The degree of diversity or similarity detected in comets depends primarily on the lifetimes of the individual cometary nuclei at the time of analysis. It is inherent in our understanding of cometary orbital dynamics and the seminal model of comet origins by Oort that cometary evolution is the natural order of events in our Solar System. Thus, predictions of cometary behaviour in terms of bulk physical, mineralogical or chemical parameters should contain an appreciation of temporal variation(s). Previously, Rietmeijer and Mackinnon developed mineralogical bases for the chemical evolution of cometary nuclei primarily with regard to the predominantly silicate fraction of comet nuclei. We suggested that alteration of solids in cometary nuclei should be expected and that indications of likely reactants and products can be derived from judicious comparison with terrestrial diagenetic environments which include hydrocryogenic and low-temperature aqueous alterations. In a further development of this concept, Rietmeijer provides indirect evidence for the formation of sulfides and oxides in comet nuclei. Furthermore, Rietmeijer noted that timescales for hydrocryogenic and low-temperature reactions involving liquid water are probably adequate for relatively mature comets, e.g. P/comet Halley. In this paper, we will address the evolution of comet nuclei physical parameters such as solid particle grain size, porosity and density. In natural environments, chemical evolution (e.g. mineral reactions) is often accompanied by changes in physical properties. These concurrent changes are well-documented in the terrestrial geological literature, especially in studies of sediment diagenesis and we suggest that similar basic principles apply within the upper few meters of active comet nuclei. The database for prediction of comet nuclei physical parameters is, in principle, the same as used for the proposition of chemical evolution. We use detailed mineralogical studies of chondritic interplanetary dust particles (IDPS) as a guide to the likely constitution of mature comets traversing the inner Solar System. While there is, as yet, no direct proof that a specific sub-group or type of chondritic IDP is derived from a specific comet, it is clear that these particles are extraterrestrial in origin and that a certain portion of the interplanetary flux received by the Earth is cometary in origin. Two chondritic porous (CP) MPs, sample numbers W7010A2 and W7029Cl, from the Johnson Space Center Cosmic Dust Collection have been selected for this study of putative cometary physical parameters. This particular type of particle is considered a likely candidate for a cometary origin on the basis of mineralogy, bulk composition and morphology. While many IDPs have been subjected to intensive study over the past decade, we can develop a physical parameter model on only these two CP IDPs because few others have been studied in sufficient detail.

Rietmeijer, Frans J. M.

Cometary Evolution: Clues on Physical Properties from Chondritic Interplanetary Dust Particles

The degree of diversity or similarity detected in comets depends primarily on the lifetimes of the individual cometary nuclei at the time of analysis. It is inherent in our understanding of cometary orbital dynamics and the seminal model of comet origins that cometary evolution is the natural order of events in our Solar System. Thus, predictions of cometary behaviour in terms of bulk physical, mineralogical or chemical parameters should contain an appreciation of temporal variation(s). Previously, Rietmeijer and Mackinnon [1987] developed mineralogical bases for the chemical evolution of cometary nuclei primarily with regard to the predominantly silicate fraction of comet nuclei. We suggested that alteration of solids in cometary nuclei should be expected and that indications of likely reactants and products can be derived from judicious comparison with terrestrial diagenetic environments which include hydrocryogenic and low-temperature aqueous alterations. In a further development of this concept, Rietmeijer [1988] provides indirect evidence for the formation of sulfides and oxides in comet nuclei. Furthermore, Rietmeijer [1988] noted that timescales for hydrocryogenic and low-temperature reactions involving liquid water are probably adequate for relatively mature comets, e.g. P/comet Halley. In this paper, we will address the evolution of comet nuclei physical parameters such as solid particle grain size, porosity and density. In natural environments, chemical evolution (e.g. mineral reactions) is often accompanied by changes in physical properties. These concurrent changes are well-documented in the terrestrial geological literature, especially in studies of sediment diagenesis and we suggest that similar basic principles apply within the upper few meters of active comet nuclei. The database for prediction of comet nuclei physical parameters is, in principle, the same as used for the proposition of chemical evolution. We use detailed mineralogical studies of chondritic interplanetary dust particles (IDPS) as a guide to the likely constitution of mature comets traversing the inner Solar System. While there is, as yet, no direct proof that a specific sub-group or type of chondritic IDP is derived from a specific comet, it is clear that these particles are extraterrestrial in origin and that a certain portion of the interplanetary flux received by the Earth is cometary in origin. Two chondritic porous (CP) IDPS, sample numbers W701OA2 and W7029CI, from the Johnson Space Center Cosmic Dust Collection have been selected for this study of putative cometary physical parameters. This particular type of particle is considered a likely candidate for a cometary origin on the basis of mineralogy, bulk composition and morphology. While many IDPs have been subjected to intensive study over the past decade, we can develop a physical parameter model on only these two CP IDPs because few others have been studied in sufficient detail.

Reitmeijer, Frans J. M.

Electromagnetic instabilities in solar wind interaction with dusty cometary plasmas

Dusty plasmas contain charged dust grains which are much more massive than protons, carry high negative charges due to preferential capture of electrons, and do not have a fixed charge. Fluctuations in the grain charges due to liberation or capture of additional electrons and protons translate as mass and momentum losses or gains for these species, which can render linear modes unstable. On the other hand, many authors have addressed the pickup of ions of cometary origin by the solar wind, which for the parallel part is due to relative streaming between cometary and solar wind ions which excites low-frequency electromagnetic turbulence. In the present work we look again at those instabilities by including effects due to the presence of charged dust in the cometary environments. We have investigated several frequency regimes: nonresonant below the cometary watergroup gyrofrequency, nonresonant below the cometary charged dust gyrofrequency (new and interesting but highly unlikely!) and resonant with the cometary watergroup ions. For most parameter ranges either the existing instabilities are enhanced, showing that the presence of charged dust facilitates the cometary ion pickup by the solar wind, or new instabilities have been shown to exist. Similar conclusions might be relevant for other kinds of astrophysical and heliospheric plasmas containing charged dust, as in planetary rings.

Verheest, Frank

Cometary Coma Chemical Composition (C4) Mission

Cometary exploration remains of great importance to virtually all of space science. Because comets are presumed to be remnants of the early solar nebula, they are expected to provide fundamental knowledge as to the origin and development of the solar system as well as to be key to understanding of the source of volatiles and even life itself in the inner solar system. Clearly the time for a detailed study of the composition of these apparent messages from the past has come. A comet rendezvous mission, the Cometary Coma Chemical Composition (C4) Mission, is now being studied as a candidate for the new Discovery program. This mission is a highly-focussed and usefully-limited subset of the Cometary Rendezvous Asteroid Flyby (CRAF) Mission. The C4 mission will concentrate on measurements that will produce an understanding of the composition and physical makeup of a cometary nucleus. The core science goals of the C4 mission are 1) to determine the chemical, elemental, and isotopic composition of a cometary nucleus and 2) to characterize the chemical and isotopic nature of its atmosphere. A related goal is to obtain temporal information about the development of the cometary coma as a function of time and orbital position. The four short-period comets -- Tempel 1, Tempel 2, Churyumov-Gerasimenko, and Wirtanen -which all appear to have acceptable dust production rates, were identified as candidate targets. Mission opportunities have been identified beginning as early as 1998. Tempel I with a launch in 1999, however, remains the baseline comet for studies of and planning the C4 mission. The C4 mission incorporates two science instruments and two engineering instruments in the payload to obtain the desired measurements. The science instruments include an advanced version of the Cometary Ice and Dust Experiment (CIDEX), a mini-CIDEX with a sample collection system, an X-ray Fluorescence Spectrometer and a Pyrolysis-Gas Chromatograph, and a simplified version of the Neutral Gas and Ion Mass Spectrometer (NIGMS). Both of these instruments have substantial heritage as they are based on those developed for the CRAF Mission. The engineering instruments include a simplified Comet Dust Environmental Monitor (SCODEM) and a navigational Camera, NAVCAM. While neither of the instruments will be permitted to establish science requirements, it is anticipated that significant science return will be accomplished Radio science will also be included.

Carle, Glenn C.

Analyses of Cometary Silicate Crystals: DDA Spectral Modeling of Forsterite

Comets are the Solar System's deep freezers of gases, ices, and particulates that were present in the outer protoplanetary disk. Where comet nuclei accreted was so cold that CO ice (approximately 50K) and other supervolatile ices like ethane (C2H2) were preserved. However, comets also accreted high temperature minerals: silicate crystals that either condensed (greater than or equal to 1400 K) or that were annealed from amorphous (glassy) silicates (greater than 850-1000 K). By their rarity in the interstellar medium, cometary crystalline silicates are thought to be grains that formed in the inner disk and were then radially transported out to the cold and ice-rich regimes near Neptune. The questions that comets can potentially address are: How fast, how far, and over what duration were crystals that formed in the inner disk transported out to the comet-forming region(s)? In comets, the mass fractions of silicates that are crystalline, f_cryst, translate to benchmarks for protoplanetary disk radial transport models. The infamous comet Hale-Bopp has crystalline fractions of over 55%. The values for cometary crystalline mass fractions, however, are derived assuming that the mineralogy assessed for the submicron to micron-sized portion of the size distribution represents the compositional makeup of all larger grains in the coma. Models for fitting cometary SEDs make this assumption because models can only fit the observed features with submicron to micron-sized discrete crystals. On the other hand, larger (0.1-100 micrometer radii) porous grains composed of amorphous silicates and amorphous carbon can be easily computed with mixed medium theory wherein vacuum mixed into a spherical particle mimics a porous aggregate. If crystalline silicates are mixed in, the models completely fail to match the observations. Moreover, models for a size distribution of discrete crystalline forsterite grains commonly employs the CDE computational method for ellipsoidal platelets (c:a:b=8.14x8.14xl in shape with geometrical factors of x:y:z=1:1:10, Fabian et al. 2001; Harker et al. 2007). Alternatively, models for forsterite employ statistical methods like the Distribution of Hollow Spheres (Min et al. 2008; Oliveira et al. 2011) or Gaussian Random Spheres (GRS) or RGF (Gielen et al. 200S). Pancakes, hollow spheres, or GRS shapes similar to wheat sheaf crystal habit (e.g., Volten et al. 2001; Veihelmann et al. 2006), however, do not have the sharp edges, flat faces, and vertices seen in images of cometary crystals in interplanetary dust particles (IDPs) or in Stardust samples. Cometary forsterite crystals often have equant or tabular crystal habit (J. Bradley). To simulate cometary crystals, we have computed absorption efficiencies of forsterite using the Discrete Dipole Approximation (DDA) DDSCAT code on NAS supercomputers. We compute thermal models that employ a size distribution of discrete irregularly shaped forsterite crystals (nonspherical shapes with faces and vertices) to explore how crystal shape affects the shape and wavelength positions of the forsterite spectral features and to explore whether cometary crystal shapes support either condensation or annealing scenarios (Lindsay et al. 2012a, b). We find forsterite crystal shapes that best-fit comet Hale-Bopp are tetrahedron, bricks or brick platelets, essentially equant or tabular (Lindsay et al. 2012a,b), commensurate with high temperature condensation experiments (Kobatake et al. 2008). We also have computed porous aggregates with crystal monomers and find that the crystal resonances are amplified. i.e., the crystalline fraction is lower in the aggregate than is derived by fitting a linear mix of spectral features from discrete subcomponents, and the crystal resonances 'appear' to be from larger crystals (Wooden et al. 2012). These results may indicate that the crystalline mass fraction in comets with comae dominated by aggregates may be lower than deduced by popular methods that only emoy ensembles of discrete crystals.

Wooden, Diane