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At least 19 records

Simultaneous observation of rotational coherent Stokes Raman scattering and coherent anti-Stokes Raman scattering in air and nitrogen

Rotational coherent Stokes Raman scattering (CSRS) and coherent anti-Stokes Raman scattering (CARS) in air and in nitrogen were observed simultaneously by using broadband generation and detection. In the broadband technique used, the entire CARS and CSRS spectrum was generated in a single laser pulse; the CSRS and CARS signals were dispersed by a spectrograph and detected simultaneously by an optical multichannel analyzer. A three-dimensional phase-matching geometry was used to achieve spatial resolution of the CSRS and CARS beams from the input beams. Under resonant conditions, similar experiments may provide a means of investigating the possible interaction between the CSRS and CARS processes in driving the rotational levels.

Snow, J. B.↗

The effects of focusing on the efficiency of coherent anti-Stokes Raman scattering

The efficiency of coherent anti-Stokes Raman scattering (CARS) is calculated as a function of the input beam sizes of the Stokes and pump laser beams. A Green's function formalism is used to show that maximum efficiency occurs when the confocal parameters of the two input beams are unequal and when the phase mismatch between the anti-Stokes field and the nonlinear polarization is nonzero.

Guha, S.↗

Molecular-Based Optical Measurement Techniques for Transition and Turbulence in High-Speed Flow

High-speed laminar-to-turbulent transition and turbulence affect the control of flight vehicles, the heat transfer rate to a flight vehicle's surface, the material selected to protect such vehicles from high heating loads, the ultimate weight of a flight vehicle due to the presence of thermal protection systems, the efficiency of fuel-air mixing processes in high-speed combustion applications, etc. Gaining a fundamental understanding of the physical mechanisms involved in the transition process will lead to the development of predictive capabilities that can identify transition location and its impact on parameters like surface heating. Currently, there is no general theory that can completely describe the transition-to-turbulence process. However, transition research has led to the identification of the predominant pathways by which this process occurs. For a truly physics-based model of transition to be developed, the individual stages in the paths leading to the onset of fully turbulent flow must be well understood. This requires that each pathway be computationally modeled and experimentally characterized and validated. This may also lead to the discovery of new physical pathways. This document is intended to describe molecular based measurement techniques that have been developed, addressing the needs of the high-speed transition-to-turbulence and high-speed turbulence research fields. In particular, we focus on techniques that have either been used to study high speed transition and turbulence or techniques that show promise for studying these flows. This review is not exhaustive. In addition to the probe-based techniques described in the previous paragraph, several other classes of measurement techniques that are, or could be, used to study high speed transition and turbulence are excluded from this manuscript. For example, surface measurement techniques such as pressure and temperature paint, phosphor thermography, skin friction measurements and photogrammetry (for model attitude and deformation measurement) are excluded to limit the scope of this report. Other physical probes such as heat flux gauges, total temperature probes are also excluded. We further exclude measurement techniques that require particle seeding though particle based methods may still be useful in many high speed flow applications. This manuscript details some of the more widely used molecular-based measurement techniques for studying transition and turbulence: laser-induced fluorescence (LIF), Rayleigh and Raman Scattering and coherent anti-Stokes Raman scattering (CARS). These techniques are emphasized, in part, because of the prior experience of the authors. Additional molecular based techniques are described, albeit in less detail. Where possible, an effort is made to compare the relative advantages and disadvantages of the various measurement techniques, although these comparisons can be subjective views of the authors. Finally, the manuscript concludes by evaluating the different measurement techniques in view of the precision requirements described in this chapter. Additional requirements and considerations are discussed to assist with choosing an optical measurement technique for a given application.

Bathel, Brett F.↗

Evaluation of turbulence induced noise in coherent anti-Stokes Raman scattering

The effect of turbulence in a transonic wind tunnel on coherent anti-Stokes Raman scattering is considered. The driving pump and Stokes waves are taken to be coaxially propagating Gaussian beam waves which are focused on the Raman active medium through the turbulent boundary layer of the flow tube. The random index of refraction variations in the layer are modeled as phase perturbations of the driving waves which cause a reduction of the mean on-axis field and an increase in the mean diameter of the beams. Effective Gaussian beam parameters are developed and the radiated anti-Stokes power calculated as a function of the phase screen parameters. A significant reduction in signal strength occurs for realistic estimates of the phase screen parameter appropriate to a confined transonic flow. A method for estimating the signal degradation which could be applied to other experimental situations is presented.

Elliott, R. A.↗

Spatially and spectrally resolved multipoint coherent anti-Stokes Raman scattering from N2 and O2 flows

Single-shot spectrally resolved broadband rotational coherent anti-Stokes Raman scattering (CARS) from multiple points along a line intersecting a flow has been observed for N2 and O2. A large-angle phase-matching configuration was used to achieve spatial resolution of 0.1 mm x 0.1 mm x 0.1 mm for each of 20 points in the interaction volume. Single-shot multipoint CARS of N2 at different temperatures and of several species in a coflowing jet was observed.

Snow, J. B.↗

Dual-Pump Coherent Anti-Stokes Raman Scattering Temperature and CO2 Concentration Measurements

Measurements of temperature and CO2 concentration using dual-pump coherent anti-Stokes Raman scattering, (CARS) are described. The measurements were performed in laboratory flames,in a room-temperature gas cell, and on an engine test stand at the U.S. Air Force Research Laboratory, Wright-Patterson Air Force Base. A modeless dye laser, a single-mode Nd:YAG laser, and an unintensified back-illuminated charge-coupled device digital camera were used for these measurements. The CARS measurements were performed on a single-laser-shot basis. The standard deviations of the temperatures and CO2 mole fractions determined from single-shot dual-pump CARS spectra in steady laminar propane/air flames were approximately 2 and 10% of the mean values of approximately 2000 K and 0.10, respectively. The precision and accuracy of single-shot temperature measurements obtained from the nitrogen part of the dual-pump CARS system were investigated in detail in near-adiabatic hydrogen/air/CO2 flames. The precision of the CARS temperature measurements was found to be comparable to the best results reported in the literature for conventional two-laser, single-pump CARS. The application of dual-pump CARS for single-shot measurements in a swirl-stabilized combustor fueled with JP-8 was also demonstrated.

Lucht, Robert P.↗

Coherent Anti-Stokes Raman Scattering (CARS) as a Probe for Supersonic Hydrogen-Fuel/Air Mixing

The dual-pump coherent anti-Stokes Raman spectroscopy (CARS) method was used to measure temperature and the absolute mole fractions of N2, O2 and H2 in a supersonic non-reacting fuel-air mixing experiment. Experiments were conducted in NASA Langley Research Center s Direct Connect Supersonic Combustion Test Facility. Under normal operation of this facility, hydrogen and air burn to increase the enthalpy of the test gas and O2 is added to simulate air. This gas is expanded through a Mach 2 nozzle and into a combustor model where fuel is then injected, mixes and burns. In the present experiment the O2 of the test gas is replaced by N2. The lack of oxidizer inhibited combustion of the injected H2 fuel jet allowing the fuel/air mixing process to be studied. CARS measurements were performed 427 mm downstream of the nozzle exit and 260 mm downstream of the fuel injector. Maps were obtained of the mean temperature, as well as the N2, O2 and H2 mean mole fraction fields. A map of mean H2O vapor mole fraction was also inferred from these measurements. Correlations between different measured parameters and their fluctuations are presented. The CARS measurements are compared with a preliminary computational prediction of the flow.

Danehy, P. M.↗

Coherent Anti-Stokes Raman scattering with reflective optics

Attention is given to the implementation of a novel reflective optics configuration in which the lens normally employed for focusing and crossing the input laser beams in Coherent Anti-Stokes Raman spectroscopy (CARS) is replaced by a spherical mirror, allowing large crossing angles to be obtained with a single focusing device and permitting the laser generation and collection equipment to be located on one side of the sample region. The experimental results obtained demonstrate the feasibility of mirror-based CARS in remote combustion diagnostics.

Antcliff, R. R.↗

Picosecond coherent anti-Stokes Raman scattering (CARS) study of vibrational dephasing of carbon disulfide and benzene in solution

The vibrational dephasing of the 656/cm mode (nu1, a1g) of CS2 and the 991/cm mode (nu2, a1g) of benzene have been studied as a function of concentration in mixtures with a number of solvents using a ps time-resolved CARS technique. This technique employs two tunable synchronously-pumped mode-locked dye lasers in a stimulated Raman pump, coherent anti-Stokes Raman probe time-resolved experiment. Results are obtained for CS2 in carbon tetrachloride, benzene, nitrobenzene, and ethanol and for benzene nu2 in CS2. The dephasing rates of CS2 nu1 increase on dilution with the polar solvents and decrease or remain constant on dilution with the nonpolar solvents. The CS2/benzene solutions show a contrasting behavior, with the CS2 nu1 dephasing rate being nearly independent of concentration whereas the benzene nu2 dephasing rate decreases on dilution. These results are compared to theoretical models for vibrational dephasing of polyatomic molecules in solution.

Perry, Joseph W.↗

Multispecies coherent anti-Stokes Raman scattering instrument for turbulent combustion

A nonintrusive diagnostic system is described which permits simultaneous measurement of temperature, nitrogen number density, and oxygen number density in hostile combustion environments. This system is pumped by a 10-Hz neodymium YAG laser, and signals are detected with an intensified photodiode array and dual photomultipliers. The system utilizes a folded BOXCARS beam arrangement, two probe dye lasers, dynamic range expansion, polarization rejection of nonresonant background, and multiplexing of the signal beams.

Antcliff, Richard R.↗

Distinguishing non-resonant four-wave-mixing noise in coherent stokes and anti-stokes Raman scattering

A method of examining a sample comprises exposing the sample to a pump pulse of electromagnetic radiation for a first period of time, exposing the sample to a stimulant pulse of electromagnetic radiation for a second period of time which overlaps in time with at least a portion of the first exposing, to produce a signal pulse of electromagnetic radiation for a third period of time, and interfering the signal pulse with a reference pulse of electromagnetic radiation, to determine which portions of the signal pulse were produced during the exposing of the sample to the stimulant pulse. The first and third periods of time are each greater than the second period of time.

Marks, Daniel L.↗

Stimulated Raman scattering seeded by a fibre continuum

A broadband continuum generated in a germanosilicate optical fiber has been used as a coherent seed to initiate stimulated Raman scattering in gases. The technique used is described. The results show a fivefold increase in conversion efficiency and a similar reduction in the requisite pump power.

Selker, M. D.↗

Single-pulse broad-band rotational CARS thermometry of cold N2 gas

Coherent anti Stokes Raman scattering (CARS) from the pure rotational Raman lines of N2 was employed to measure the instantaneous (10 nsec) rotational temperature of the gas at room temperature and below. An entire rotational CARS spectrum was generated by a single laser pulse using a broad bandwidth dye laser and was recorded on an optical multichannel analyzer. A best fit temperature obtained for individual experimental spectra by comparison with calculated spectra. Good agreement between CARS temperatures and thermocouple temperatures was observed.

Chang, R. K.↗

Simultaneous CARS and Interferometric Rayleigh Scattering

This paper reports for the first time the combination of a dual-pump coherent anti-Stokes Raman scattering system with an interferometric Rayleigh scattering system (CARS - IRS) to provide time-resolved simultaneous measurement of multiple properties in combustion flows. The system uses spectrally narrow green (seeded Nd:YAG at 532 nm) and yellow (552.9 nm) pump beams and a spectrally-broad red (607 nm) beam as the Stokes beam. A spectrometer and a planar Fabry-Perot interferometer used in the imaging mode are used to record the spectrally broad CARS spectra and the spontaneous Rayleigh scattering spectra, respectively. Time-resolved simultaneous measurement of temperature, absolute mole fractions of N2, O2, and H2, and two components of velocity in a Hencken burner flame were performed to demonstrate the technique.

Bivolaru, Daniel↗

The temperature dependence of inelastic light scattering from small particles for use in combustion diagnostic instrumentation

A computer calculation of the expected angular distribution of coherent anti-Stokes Raman scattering (CARS) from micrometer size polystyrene spheres based on a Mie-type model, and a pilot experiment to test the feasibility of measuring CARS angular distributions from micrometer size polystyrene spheres by simply suspending them in water are discussed. The computer calculations predict a very interesting structure in the angular distributions that depends strongly on the size and relative refractive index of the spheres.

Cloud, Stanley D.↗

Absolute two-photon excitation cross-sections in NO

A technique has been developed which allows the determination of a two-photon absorption cross-section to be made relative to the Raman scattering cross-section in nitrogen. Spatial and temporal effects associated with the lasers are ratioed out to give a result independent of laser parameters. The necessary theory to extract a cross-section from the measured ratio of a Coherent Anti-Stokes Raman Scattering (CARS) signal in N2 to a four-wave mixing signal in NO has been developed. The technique has been demonstrated on the R(22) + S(12) (J-double-prime = 9 1/2) line in NO and a cross-section of (2.9 + or - 1.8) x 10 to the -49th (cm to the 4th power)-s was determined. This technique appears to be applicable to a number of other diatomic molecules.

Burris, J.↗

Laser Diagnostics for combustion temperature and species measurements

Laser optical diagnostic techniques for the measurement of combustion gaseous-phase temperatures and, or species concentrations are discussed. The techniques fall into two classes: incoherent (Rayleigh scattering, spontaneous Raman scattering, laser induced fluorescence spectroscopy) and coherent (coherent anti-Stokes Raman spectroscopy). The advantages, disadvantages and applicability of each method are outlined.

Eckbreth, Alan C.↗