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This presentation outlines the performance characteristics of state-of-the-art nonvolatile memory devices and identifies charge storage mechanisms in nanocrystal floating gate materials.
An effort to extend the low-temperature operational limit of supercapacitors is currently underway. At present, commercially available non-aqueous supercapacitors are rated for a minimum operating temperature of -40 C. A capability to operate at lower temperatures would be desirable for delivering power to systems that must operate in outer space or in the Polar Regions on Earth. Supercapacitors (also known as double-layer or electrochemical capacitors) offer a high power density (>1,000 W/kg) and moderate energy density (about 5 to 10 Wh/kg) technology for storing energy and delivering power. This combination of properties enables delivery of large currents for pulsed applications, or alternatively, smaller currents for low duty cycle applications. The mechanism of storage of electric charge in a supercapacitor -- at the electrical double-layer formed at a solid-electrode/liquid-electrolyte interface -- differs from that of a primary or secondary electrochemical cell (i.e., a battery) in such a manner as to impart a long cycle life (typically >10(exp 6) charge/discharge cycles).
Data from life-cycle testing of 22-cell NiCd batteries designed for shuttle-service spacecrafts are analyzed, first by averaging battery cycle lives as a function of temperature and depth of discharge, and then by calculating single cell failure and survival probabilities as a function of temperature, depth of discharge, and number of operating cycles. The single cell data are used to calculate battery survival probabilities. A mathematical failure model which is a function of the quantity of charge through the battery and the temperature is characterized, suggesting a predictive capability for accurate estimation of energy storage subsystem life and performance of accelerated tests. The failure mechanism described is apparently independent of most charge-discharge parameters and common to most cell sizes.
The greatest gains in solar energy conversion efficiency of p-n-junction silicon solar cells come from increasing the open-circuit voltage V sub OC; it is important to understand and characterize the material parameters that limit the V sub OC. Strong experimental evidence exists to support the assertion that either an anomalously large minority carrier charge storage or an anomalously small minority carrier lifetime in the quasi-neutral emitter region limits the open circuit voltage. A method is presented for measuring charge storage and effective lifetime. Static and transient measurements are analyzed using physical models of the solar cell characteristics. This analysis yields the emitter charge storage and life-time, which then can be related to the various physical mechanisms, such as energy band gap shrinkage, that have been proposed earlier as responsible for limiting V sub OC.
Real-time data storage and processing using optical techniques have been considered in recent years. Of particular interest are photosensitive electro-optic crystals which permit volume storage in the form of phase holograms, by means of a charge transfer process. A survey of the state of the art of such holographic memories is presented. The physical mechanism responsible for the formation of phase holograms in such crystals is discussed. Attention is focused on various aspects of materials characterization, development and utilization. Experimental reversible holographic read-write memory systems with fast random access and high storage capacity employing this new class of photosensitive materials have already been demonstrated.
Dissipation of charges built up near the surface of insulators due to space environment interaction is central to understanding spacecraft charging. Conductivity of insulating materials is key to determine how accumulated charge will distribute across the spacecraft and how rapidly charge imbalance will dissipate. To understand these processes requires knowledge of how charge is deposited within the insulator, the mechanisms for charge trapping and charge transport within the insulator, and how the profile of trapped charge affects the transport and emission of charges from insulators. One must consider generation of mobile electrons and holes, their trapping, thermal de-trapping, mobility and recombination. Conductivity is more appropriately measured for spacecraft charging applications as the "decay" of charge deposited on the surface of an insulator, rather than by flow of current across two electrodes around the sample. We have found that conductivity determined from charge storage decay methods is 102 to 104 smaller than values obtained from classical ASTM and IEC methods for a variety of thin film insulating samples. For typical spacecraft charging conditions, classical conductivity predicts decay times on the order of minutes to hours (less than typical orbit periods); however, the higher charge storage conductivities predict decay times on the order of weeks to months leading to accumulation of charge with subsequent orbits. We found experimental evidence that penetration profiles of radiation and light are exceedingly important, and that internal electric fields due to charge profiles and high-field conduction by trapped electrons must be considered for space applications. We have also studied whether the decay constants depend on incident voltage and flux or on internal charge distributions and electric fields; light-activated discharge of surface charge to distinguish among differing charge trapping centers; and radiation-induced conductivity. Our experiments also show that "Malter" electron emission occurs for hours after turning off the electron beam. This Malter emission similar to emission due to negative electron affinity in semiconductors is a result of the prior radiation or optical excitations of valence electrons and their slow drift among traps towards the surface where they are subsequently emitted. This work is supported through funding from the NASA Space Environments and Effects Program.
NASA analyzes, tests, packages, and fabricates electrical, electronic, and electromechanical (EEE) parts used in space vehicles. One area that NASA wishes to advance is energy storage and delivery. Currently, space vehicles use rechargeable batteries that utilize silver zinc or lithium ion electrochemical processes. These current state-of-the-art rechargeable batteries cannot be rapidly charged, contain harmful chemicals, and suffer from early wear-out mechanisms. A solid state ultracapacitor is an EEE part that offers significant advantages over current electrochemical and electrolytic devices. The objective of this research is to develop an internal barrier layer ultracapacitor (IBLC) using novel dielectric materials as a battery replacement with a focus on these advantages: longer life, lower mass-toweight ratio, rapid charging, on-demand pulse power, improved on-pad standby time without maintenance, and environmental friendliness. The approach is unique in two areas. A deposition technique is used that has been shown to produce a more uniformly coated nanoparticle than sol-gel, which has resulted in colossal permittivities. These particles are then distributed in an ink formulation developed at NASA Marshall Space Flight Center (MSFC) and deposited utilizing a 3D aerosol jet technique. This additive manufacturing technique controls layer thickness, resulting in extremely large capacitance and energy density.
The engineering design of a stand alone photovoltaic (PV) powered grain mill and water pump for the village of Tangaye, Upper Volta is described. The socioeconomic effects of reducing the time required by women in rural areas for drawing water and grinding grain were studied. The suitability of photovoltaic technology for use in rural areas by people of limited technical training was demonstrated. The PV system consists of a 1.8-kW (peak) solar cell array, 540 ampere hours of battery storage, instrumentation, automatic controls, and a data collection and storage system. The PV system is situated near an improved village well and supplies d.c. power to a grain mill and a water pump. The array is located in a fenced area and the mill, battery, instruments, controls, and data system are in a mill building. A water storage tank is located near the well. The system employs automatic controls which provide battery charge regulation and system over and under voltage protection. This report includes descriptions of the engineering design of the system and of the load that it serves; a discussion of PV array and battery sizing methodology; descriptions of the mechanical and electrical designs including the array, battery, controls, and instrumentation; and a discussion of the safety features. The system became operational on March 1, 1979.
A control algorithm developed at the NASA Glenn Research Center will allow a flywheel energy storage system to interface with the electrical bus of a space power system. The controller allows the flywheel to operate in both charge and discharge modes. Charge mode is used to store additional energy generated by the solar arrays on the spacecraft during insolation. During charge mode, the flywheel spins up to store the additional electrical energy as rotational mechanical energy. Discharge mode is used during eclipse when the flywheel provides the power to the spacecraft. During discharge mode, the flywheel spins down to release the stored rotational energy.
Textile-based supercapacitors (TSCs) are being used to meet the ever-increasing demand for mobile, safe, and convenient energy sources to power personal electronic devices. To that end, the smart textiles used in wearable technology need to be made from highly conductive yarns that are easily manufacturable. To date, synthetic- and cellulosic-based yarns have been exclusively used for the fabrication of TSCs, while other yarns have not been explored. Here, we used conductive protein-based yarns for TSCs and report on the use of wool coated with Ti 3 C 2 T x MXene as a potential electrode material. To knit TSCs, wool and cotton yarns were coated with MXene flakes and their surfaces were characterized using Scanning Electron Microscopy (SEM) and X-Ray Photoelectron Spectroscopy (XPS). The electrochemical characterization was conducted to examine the performance of wool- and cotton-based MXene electrodes as substrates and determine charge storage and resistive behavior. These tests showed that wool TSCs exhibited more pseudocapacitive behavior, while cotton TSCs exhibited a wider current range. At a scan rate of 5 mV/s, cotton TSCs presented an areal capacitance of 823.9 mF/cm 2 while this value for the wool TSCs was 284 mF/cm 2 . The performance of yarns was also tested under various mechanical deformation conditions and after washing in order to assess the stability of TSCs. This study indicates the potential of protein-based yarns as electrode substrates for integration of MXene to fabricate smart textile-based devices.
Recent tests at Hughes have shown that Ni/H2 cells cycled in 26 percent KOH have much longer lives than those cycled in other concentrations. As part of an ongoing program to try to correlate the impedances of nickel electrodes with their life and performance, impedances were measured of a number of electrodes from these tests that had been cycled in concentrations from 21 to 36 percent KOH. These had ranged from about 1000 to 40,000 cycles. After cycling ten times to reduce possible changes due to storage, impedances were measured at five voltages corresponding to low states of charge. The results were analyzed using a standard circuit model including Warburg impedance term. Lower kinetic resistances and Warburg slopes were found for several electrodes which had been cycled in 26 percent KOH even though they had been cycled for a much longer time than the others. Interpretation of the data is complicated by the fact that the cycle lives, storage times, and failure mechanisms varied. Several other circuit models have also been examined, but the best correlations with life were found with parameters obtained from the simple model.
The NASA Glenn Research Center has constructed a closed-cycle hydrogen-oxygen PEM regenerative fuel cell (RFC) to explore its potential use as an energy storage device for a high altitude solar electric aircraft. Built up over the last 2 years from specialized hardware and off the shelf components the Glenn RFC is a complete "brassboard" energy storage system which includes all the equipment required to (1) absorb electrical power from an outside source and store it as pressurized hydrogen and oxygen and (2) make electrical power from the stored gases, saving the product water for re-use during the next cycle. It consists of a dedicated hydrogen-oxygen fuel cell stack and an electrolyzer stack, the interconnecting plumbing and valves, cooling pumps, water transfer pumps, gas recirculation pumps, phase separators, storage tanks for oxygen (O2) and hydrogen (H2), heat exchangers, isolation valves, pressure regulators, nitrogen purge provisions, instrumentation, and other components. It specific developmental functions include: (1) Test fuel cells and fuel cell components under repeated closed-cycle operation (nothing escapes; everything is used over and over again). (2) Simulate diurnal charge-discharge cycles (3) Observe long-term system performance and identify degradation and loss mechanisms. (4) Develop safe and convenient operation and control strategies leading to the successful development of mission-capable, flight-weight RFC's.
A proposed gas strut system would separate a liquid-fueled second rocket stage from a solid-fueled first stage using an array of pre-charged struts. The strut would be a piston-and-cylinder mechanism containing a compressed gas. Adiabatic expansion of the gas would drive the extension of the strut. The strut is designed to produce a force-versus-time profile, chosen to prevent agitation of the liquid fuel, in which the force would increase from an initial low value to a peak value, then decay toward the end of the stroke. The strut would include a piston chamber and a storage chamber. The piston chamber would initially contain gas at a low pressure to provide the initial low separation force. The storage chamber would contain gas at a higher pressure. The piston would include a longitudinal metering rod containing an array of small holes, sized to restrict the flow gas between the chambers, that would initially not be exposed to the interior of the piston chamber. During subsequent expansion, the piston motion would open more of the metering holes between the storage and piston chambers, thereby increasing the flow of gas into the piston chamber to produce the desired buildup of force.
The real impetus for developing a production parylene coating process for internal hybrid passivation came as a result of the possibility of loose conductive particles in hybrid microelectronic circuits, causing intermittent and sometimes permanent failures. Because of the excellent mechanical properties of parylene, it is capable of securing the loose particles in place and prevent such failures. The process of coating described consists of (1) vaporizing the initial charge, which is in the form of a dimer; (2) conversion of the dimer into a reactive monomer; and (3) deposition and subsequent polymerization of the monomer in the deposition chamber which forms a uniform parylene film over all the cold surfaces in contact. Experimental results are discussed in terms of wire bond reliability, resistor drift, high-temperature storage characteristics of parylene, and coating acceptance standards. It is concluded that internal cavities of microelectronic circuits can be successfully coated with parylene provided appropriate tooling is used to protect external leads from the parylene monomer.
Magnetic reconnection is a fundamental plasma-physical process by which energy stored in a magnetic field is converted, often explosively, into heat and the kinetic energy of the charged particles that constitute the plasma. It occurs in a variety of astrophysical settings, ranging from the solar corona to pulsar magnetospheres and winds, as well as in laboratory fusion experiments, where it is responsible for sawtooth crashes. First proposed by R.G. Giovanelli in the late I 940s as the mechanism responsible for solar flares, magnetic reconnection was invoked at the beginning of the space age to explain not just solar flares but also the transfer of energy, mass, and momentum from the solar wind to Earth's magnetosphere and the subsequent storage and release of the transferred energy in the magnetotai\. During the half century or so that has followed the seminal theoretical works by J.W. Dungey, P.A. Sweet, E.N. Parker, and H.E. Petschek, in-situ measurements by Earth-orbiting satellites and remote-sensing observations of the solar corona have provided a growing body of evidence for the occurrence of reconnection at the Sun, in the solar wind, and in the near-Earth space environment. The last thirty years have also seen the development of laboratory reconnection experiments at a number of institutions. In parallel with the efforts of experimentalists in both space and laboratory plasma physics, theorists have investigated, analytically and with the help of increasingly powerful MHD, hybrid, and kinetic numerical simulations, the structure of the diffusion region, the factors controlling the rate, onset, and cessation of reconnection, and the detailed physics that enables the demagnetization of the ions and electrons and the topological reconfiguration of the magnetic field. Moreover, the scope of theoretical reconnection studies has been extended well beyond solar system and laboratory plasmas to include more exotic astrophysical plasma systems whose strong (10(exp 14)-10(exp 15) G) magnetic fields require that models of reconnection in these systems incorporate quantum electrodynamical, special relativistic, and radiative effects. The papers collected in this topical issue of Space Science Reviews cover different aspects of recent theoretical and observational work on magnetic reconnection in solar and space physics, astrophysics, and laboratory plasma physics. They derive from presentations given at a workshop on magnetic reconnection held in the Yosemite National Park, February 8-12,2010. The intent of the workshop was to stimulate, through a combination of tutorial talks, shorter focused talks, and extensive informal discussions, an interdisciplinary dialogue among members of the different research communities working on the problem of magnetic reconnection. One of the motivating considerations for holding the workshop was its relevance to NASA's Magnetospheric Multiscale (MMS) mission, scheduled for launch in 2014. The four identically instrumented MMS spacecraft are designed to study reconnect ion in Earth's magnetosphere and, specifically, to probe the electron diffusion region in order to determine the microphysical processes that enable the change in the topology of the magnetic field. Building on the achievements of the multi spacecraft Cluster and THEMIS missions, MMS will use the magnetosphere as an astrophysical plasma laboratory in which to test, through in-situ measurement of the plasma, energetic particles, and electric and magnetic fields, various models and theories that have emerged during the past twenty years, a period of extraordinarily productive theoretical and observational work.
The charge states of carbon and oxygen of solar origin were measured directly in interplanetary space. At 100 keV per nucleon the C(+5)/C(+6) and O(+7)/O(+8) ratios are 1.8 and 1.6 respectively. It was found that the abundance ratios of low energy heavy nuclei to He is significantly larger than corresponding photospheric values: the enhancement of O/He is 35 and both Si/He and Fe/He are overabundant by a factor of 100. To explain these observations a mechanism is proposed which first preferentially accelerates heavy ions and is followed by either storage of these ions in the coronal regions or strong adiabatic deceleration.
The charge states of carbon and oxygen of solar origin have been measured directly in interplanetary space. At 100 keV per nucleon the C(+5)/C(+6) and O(+7)/O(+8) ratios are 1.8 and 1.6, respectively. Abundance ratios of low energy heavy nuclei to He are found which are significantly larger than the corresponding photospheric values. The enhancement of O/He is 35, and both Si/He and Fe/He are overabundant by a factor of 100. To explain these observations a mechanism is proposed which first preferentially accelerates heavy ions and is followed by either storage of these ions in the coronal regions or strong adiabatic deceleration.
An experiment was conducted at the CERN intersecting storage rings using colliding proton beams to investigate high-multiplicity gamma-ray events. The objective of the study was to reveal certain features of multiple pion production as well as other possible mechanisms of gamma-ray production. The detector system consisted of ten planes of spark chambers, three scintillation counter hodoscopes and two arrays of lead-glass Cerenkov counters, the first array containing 16 counters and the second, 60 counters. The event trigger was obtained from the Cerenkov counters, and the energies in all the Cerenkov counters after trigger, as well as the information on all the charged particles given by the scintillation counters and spark chambers were recorded on magnetic tape. The relationship between the number of gamma-rays per event and the number of Cerenkov counters triggered by a neutral secondary was established by means of a Monte Carlo calculation.