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At least 19 records

The Relationship Between Catalyst and Solvent in Hydrogenation via Condensed Phase Heterogeneous Catalysis

To understand a system is to understand its components and their sum. Cascading interactions between catalyst, solvent, and reagent create a complex web of influences when heterogeneous catalysis meets the condensed phase. Due to the importance of heterogeneous catalysis in chemical manufacturing, and the present and growing potential of condensed phase chemistries, the understanding of these interactions is of paramount importance. To develop condensed phase heterogeneous catalysis, the field needs to develop understanding of the role of solvent in heterogeneous catalytic hydrogenation. While no small feat, fields such as biofuel and petroleum refining have established certain applicable generalities that can bridge the knowledge gap in emerging technologies such as integrated carbon capture and conversion to materials (IC 3 M). In this review, we thoughtfully probe the current paradigm of condensed phase catalysis by challenging the idea that catalyst and solvent are independent reaction design choices. Challenges such as lack of experimental stability studies and poor resolution on our conceptualization of the condensed phase environment are discussed. Parameters such as viscosity and the dielectric constant, and their role on reaction activity and stability are explored. Knowledge gained from established biomass and petroleum processes is discussed and used to anticipate behavior in novel processes.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH

Angular Correlation Date Measurements with the GeRMAC system

Advanced modeling and simulation efforts have improved at Idaho National Laboratory in recent years with a solid foundation of experimental results. Current computational methods represent significant modeling capabilities but are limited by the accuracy and availability of nuclear data. The creation of pre- and post-processing software tools to address these limitations is fundamental to the improvement of nuclear science modeling capacities. One aspect of predictive modeling tools deals with gamma-rays emitted from radionuclides, including fissile or fissionable material, fission products, or activation products, produced in reactor experiments or other neutron environments. The resulting radionuclides decay in unique ways, providing complications upon measurement as a result of random and cascade, or true, coincidence summing. These effects are not easily quantified during modeling efforts of gamma-ray source terms., The germanium rotational measurements for angular correlation (GeRMAC) system was built to quantify the relative angles for gamma rays emitted by radionuclides of interest to investigate true coincidence, or cascade, summing as well as the nuclear energy levels of decay schemes of interest. Proof of concept studies utilize a series of laboratory check sources to provide validity, and it will soon be used to perform the same measurements for fission products of interest. The resulting data can be used to implement into a Monte Carlo code, such as Geant4, to provide more precise gamma-ray source terms following irradiations of materials.

73 - NUCLEAR PHYSICS AND RADIATION PHYSICS

A Solar-Pumped Fluorescence Model for Line-By-Line Emission Intensities in the B-X, A-X, and X-X Band Systems of 12C14N

We present a new quantitative model for detailed solar-pumped fluorescent emission of the main isotopologue of CN. The derived fluorescence efficiencies permit estimation and interpretation of ro-vibrational infrared line intensities of CN in exospheres exposed to solar (or stellar) radiation. Our g-factors are applicable to astronomical observations of CN extending from infrared to optical wavelengths, and we compare them with previous calculations in the literature. The new model enables extraction of rotational temperature, column abundance, and production rate from astronomical observations of CN in the inner coma of comets. Our model accounts for excitation and de-excitation of rotational levels in the ground vibrational state by collisions, solar excitation to the A(sup 2)Pi(sub I) and B(sup 2)Sum(sup +) electronically excited states followed by cascade to ro-vibrational levels of X(sup 2)Sum(sup +), and direct solar infrared pumping of ro-vibrational levels in the X(sup 2)Sum(sup +) state. The model uses advanced solar spectra acquired at high spectral resolution at the relevant infrared and optical wavelengths and considers the heliocentric radial velocity of the comet (the Swings effect) when assessing the exciting solar flux for a given transition. We present model predictions for the variation of fluorescence rates with rotational temperature and heliocentric radial velocity. Furthermore, we test our fluorescence model by comparing predicted and measured line-by-line intensities for X(sup 2)Sum(sup +) (1-0) in comet C/2014 Q2 (Lovejoy), thereby identifying multiple emission lines observed at IR wavelengths.

Emission

Inertial transfers in the helical decomposition

The directions of the triadic energy transfers assumed in a previous paper agree with the spectral closures, in a similarity range, if the exponent of the power-law energy spectrum is less than unity. The helical interactions showing a strong local energy transfer when the triad is nonlocal, sum up to a reverse cascade unless the spectrum falls off faster than a -7/3 power of the wave number. The energy cascades from each type of helical interaction are calculated for a -5/3 inertial range using the eddy damped quasinormal Markovian model. One type of interaction is responsible for 86 percent of the cascade. The contributions of the two classes of helical interactions to the subgrid-scale eddy viscosity are presented, together with the contributions from the forward and reverse cascading interactions. An application of the assumption on the triadic energy transfers to turbulence under rapid rotation gives a simple argument for the tendency toward nonlinear two-dimensionalization of the flow.

Waleffe, Fabian

Initial Kernel Timing Using a Simple PIM Performance Model

This presentation will describe some initial results of paper-and-pencil studies of 4 or 5 application kernels applied to a processor-in-memory (PIM) system roughly similar to the Cascade Lightweight Processor (LWP). The application kernels are: * Linked list traversal * Sun of leaf nodes on a tree * Bitonic sort * Vector sum * Gaussian elimination The intent of this work is to guide and validate work on the Cascade project in the areas of compilers, simulators, and languages. We will first discuss the generic PIM structure. Then, we will explain the concepts needed to program a parallel PIM system (locality, threads, parcels). Next, we will present a simple PIM performance model that will be used in the remainder of the presentation. For each kernel, we will then present a set of codes, including codes for a single PIM node, and codes for multiple PIM nodes that move data to threads and move threads to data. These codes are written at a fairly low level, between assembly and C, but much closer to C than to assembly. For each code, we will present some hand-drafted timing forecasts, based on the simple PIM performance model. Finally, we will conclude by discussing what we have learned from this work, including what programming styles seem to work best, from the point-of-view of both expressiveness and performance.

BRIEFING CHARTS

LPM effect and primary energy estimations

The distortion of the electron cascade development under LPM effects is now admitted; it consists of an increase of depth of showers origin, of shower maximum T sum max, a decrease of the number of particles at maximum N sub max and results in a flattening and a widening of the cascade transition curve. Connected with the influence of multiple Coulomb scattering on basic electromagnetic processes (bremsstrahlung, pair production), this effect appears at high energy with a threshold dependent on the density of the medium (more than 10 TeV for lead, more than 10 sup 6 TeV in air). Consequently, the electromagnetic components of hadron induced showers in lead and EAS in air calculated for the same hadronic cascades in the different alternative, including or not the LPM effect are examined here.

Bourdeau, M. F.

Real time pipelined system for forming the sum of products in the processing of video data

A 3-by-3 convolver utilizes 9 binary arithmetic units connected in cascade for multiplying 12-bit binary pixel values P sub i which are positive or two's complement binary numbers by 5-bit magnitide (plus sign) weights W sub i which may be positive or negative. The weights are stored in registers including the sign bits. For a negative weight, the one's complement of the pixel value to be multiplied is formed at each unit by a bank of 17 exclusive or gates G sub i under control of the sign of the corresponding weight W sub i, and a correction is made by adding the sum of the absolute values of all the negative weights for each 3-by-3 kernel. Since this correction value remains constant as long as the weights are constant, it can be precomputed and stored in a register as a value to be added to the product PW of the first arithmetic unit.

Wilcox, Brian

Fidelity Analysis of Sampled Imaging Systems

Many modeling, simulation and performance analysis studies of sampled imaging systems are inherently incomplete because they are conditioned on a discrete-input, discrete-output model that only accounts for blurring during image acquisition and additive noise. For those sampled imaging systems where the effects of digital image acquisition, digital filtering and reconstruction are significant, the modeling, simulation and performance analysis should be based on a more comprehensive continuous-input, discrete-processing, continuous-output end-to-end model. This more comprehensive model should properly account for the low-pass filtering effects of image acquisition prior to sampling, the potentially important noiselike effects of the aliasing caused by sampling, additive noise due to device electronics and quantization, the generally high-boost filtering effects of digital processing, and the low-pass filtering effects of image reconstruction. This model should not, however, be so complex as to preclude significant mathematical analysis, particularly the mean-square (fidelity) type of analysis so common in linear system theory. We demonstrate that, although the mathematics of such a model is more complex, the increase in complexity is not so great as to prevent a complete fidelity-metric analysis at both the component level and at the end-to-end system level: that is, computable mean-square-based fidelity metrics are developed by which both component-level and system-level performance can be quantified. In addition, we demonstrate that system performance can be assessed qualitatively by visualizing the output image as the sum of three component images, each of which relates to a corresponding fidelity metric. The cascaded, or filtered, component accounts for the end-to-end system filtering of image acquisition, digital processing, and image reconstruction; the random noise component accounts for additive random noise, modulated by digital processing and image reconstruction filtering; and the aliased noise component accounts for the frequency folding effect of sampling, modulated by digital processing and image reconstruction filtering.

Park, Stephen K.

Program Predicts Broadband Noise from a Turbofan Engine

Broadband Fan Noise Prediction System (BFaNS) is a computer program that, as its name indicates, predicts the broadband noise generated by the fan stage of a turbofan engine. This noise is the sum of (1) turbulent-inflow noise, which is caused by turbulence impinging on leading edges of the fan and the fan exit guide vane and (2) self noise, which is caused by turbulence convecting past the corresponding trailing edges. The user provides input data on the fan-blade, vane, and flow-path geometries and on the mean and turbulent components of the flow field. BFaNS then calculates the turbulent-inflow noise by use of D. B. Hanson's theory, which relates sound power to the inflow turbulence characteristics and the cascade geometry. Hanson s program, BBCASCADE, is incorporated into BFaNS, wherein it is applied to the rotor and stator in a stripwise manner. The spectra of upstream and downstream sound powers radiated by each strip are summed to obtain the total upstream and downstream sound-power spectra. The self-noise contributions are calculated by S. A. L. Glegg's theory, which is also applied in a stripwise manner. The current version of BFaNS is limited to fans with subsonic tip speeds.

Morin, Bruce L.

Bending-torsion flutter of a highly swept advanced turboprop

Experimental and analytical results are presented for a bending-torsion flutter phenomena encountered during wind-tunnel testing of a ten-bladed, advanced, high-speed propeller (turboprop) model with thin airfoil sections, high blade sweep, low aspect ratio, high solidity and transonic tip speeds. Flutter occurred at free-stream Mach numbers of 0.6 and greater and when the relative tip Mach number (based on vector sum of axial and tangential velocities) reached a value of about one. The experiment also included two- and five-blade configurations. The data indicate that aerodynamic cascade effects have a strong destabilizing influence on the flutter boundary. The data was correlated with analytical results which include aerodynamic cascade effects and good agreement was found.

Mehmed, O.

A cosmic ray super high multicore family event. 1: Experiment and general features

Information on the fragmentation region in super high energy hadronic interactions can be obtained through the observations of gamma-ray families produced by cosmic rays. Gamma-ray families with the sum of E sub gamma or 1000 TeV are receiving increasing interests in emulsion chamber experiments. There exist some complications caused by the superposition of nuclear and electromagnetic cascades and the uncertainty in the nature of the primary particles. These complications usually make the conclusions drawn from various interesting phenomena observed in family events not so definite. An interesting family event KO E19, which is likely to have suffered only very slight disturbances is described. It was found in the Mt. Kambala emulsion chamber experiment. The production height of the event is determined to be H=(70 + or - 30)m and some conclusions are given.

Ren, J. R.

Large-signal Stability Analysis of Grid-forming Inverters with Equivalent-circuit Models

Here, this paper proposes an energy function-based direct method for large-signal stability assessment of grid-forming (GFM) inverters leveraging an equivalent-circuit representation of all involved control- and physical-layer dynamics. Three different primary controls, a standard inner-current outer-voltage cascaded-control architecture, output LCL filter, and reference-current saturation limiting are featured in the modeling and analysis framework. A composite energy function for the GFM inverter is obtained by summing up individual energy contributions gleaned from the circuit representation. The approach can readily be generalized to different primary controls, output-filter arrangements, and current limiters since it is based on a circuit-theoretic foundation. Numerical simulations validate the efficacy of the approach in estimating the critical clearing time following a large-signal disturbance.

24 POWER TRANSMISSION AND DISTRIBUTION

Sound generated in a cascade by three-dimensional disturbances convected in a subsonic flow

Discrete tone sound generation in a subsonic fan subject to three-dimensional disturbances is investigated. The analytical model used treats the fan rotor and stator as linear cascades of thin airfoils in a rectangular duct subject to a three-dimensional gust for which a complete aerodynamic theory already exists. The sound pressure can then be cast as the sum of a finite number of discrete sound waves (modes) the magnitude of which depends on an unknown function satisfying a singular integral equation. Similarity rules are derived to reduce the problem to that of a two-dimensional gust. Three-dimensional effects on the cut-off condition, the sound pressure, and the acoustic power are first investigated for each mode. The theory is then applied to noise generated by typical rotor-wake-defect and rotor-tip-vortex disturbances interacting with a stator.

Atassi, H.

Line broadening in multiphoton processes with a resonant intermediate transition

It is found that the line width of the excitation spectrum for multiphoton ionization is broadened much more severely than the cascade fluorescence originating from the resonant intermediate level. These results derive from the mutual effects of the ionizing and resonating transitions, which are not properly accounted for in perturbative treatments. In general, the ionization line shape can be expressed as the sum of two Lorentzian components, each with different degrees of broadening. This line shape reduces to that of the resonating transition in the limit of vanishing intensities. Moreover, the fluorescence line shape may also exhibit a second component whose amplitude may become important under certain conditions.

Wang, C. C.

Electronic filters, repeated signal charge conversion apparatus, hearing aids and methods

An electronic filter for filtering an electrical signal. Signal processing circuitry therein includes a logarithmic filter having a series of filter stages with inputs and outputs in cascade and respective circuits associated with the filter stages for storing electrical representations of filter parameters. The filter stages include circuits for respectively adding the electrical representations of the filter parameters to the electrical signal to be filtered thereby producing a set of filter sum signals. At least one of the filter stages includes circuitry for producing a filter signal in substantially logarithmic form at its output by combining a filter sum signal for that filter stage with a signal from an output of another filter stage. The signal processing circuitry produces an intermediate output signal, and a multiplexer connected to the signal processing circuit multiplexes the intermediate output signal with the electrical signal to be filtered so that the logarithmic filter operates as both a logarithmic prefilter and a logarithmic postfilter. Other electronic filters, signal conversion apparatus, electroacoustic systems, hearing aids and methods are also disclosed.

Morley, Jr., Robert E.

Electronic filters, signal conversion apparatus, hearing aids and methods

An electronic filter for filtering an electrical signal. Signal processing circuitry therein includes a logarithmic filter having a series of filter stages with inputs and outputs in cascade and respective circuits associated with the filter stages for storing electrical representations of filter parameters. The filter stages include circuits for respectively adding the electrical representations of the filter parameters to the electrical signal to be filtered thereby producing a set of filter sum signals. At least one of the filter stages includes circuitry for producing a filter signal in substantially logarithmic form at its output by combining a filter sum signal for that filter stage with a signal from an output of another filter stage. The signal processing circuitry produces an intermediate output signal, and a multiplexer connected to the signal processing circuit multiplexes the intermediate output signal with the electrical signal to be filtered so that the logarithmic filter operates as both a logarithmic prefilter and a logarithmic postfilter. Other electronic filters, signal conversion apparatus, electroacoustic systems, hearing aids and methods are also disclosed.

Morley, Jr., Robert E.

Optimization of cascade blade mistuning. I - Equations of motion and basic inherent properties

Attention is given to the derivation of the equations of motion of mistuned compressor blades, interpolating aerodynamic coefficients by means of quadratic expressions in the reduced frequency. If the coefficients of the quadratic expressions are permitted to assume complex values, excellent accuracy is obtained and Pade rational expressions are obviated. On the basis of the resulting equations, it is shown analytically that the sum of all the real parts of the eigenvalues is independent of the mistuning introduced into the system. Blade mistuning is further treated through the aerodynamic energy approach, and the limiting vibration modes associated with alternative mistunings are identified.

Nissim, E.