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Dissociation-excitation reactions of argon metastables with carbon dioxide.

Results of a study showing that a metastable argon-carbon dioxide reaction results in dissociation of carbon dioxide and electronic excitation of one of the products, carbon monoxide or oxygen. A flow system using a 2450-MHz discharge was used to produce metastable argon atoms. Metastable argon in the afterglow was confirmed by adding nitrogen to the afterglow. Without addition of carbon dioxide no argon line emission, or any other emission, is observed from the reaction zone. Absence of argon line emission produced by recombination indicates the absence of charged species.

Starr, W. L.

Excitation of metastable argon and helium atoms by electron impact

Using a time-of-flight method, the excitation of argon and helium metastables by electron impact is investigated in the energy range from threshold to about 50 eV. The secondary-electron yields of the metastable detector used are reviewed in detail. The effect of metastable recoil is also discussed. Comparisons with data from other investigators are presented.

Borst, W. L.

Characteristics of the continuous wave neutral argon laser.

Study of the characteristics of the CW neutral argon IR laser, using a variety of techniques. The output power enhancement effects of helium and chlorine gases are measured, and the reasons for the enhancement are determined. The gain is measured for the 2.397-, 2.208-, 2.062-, and 1.792-micron laser lines, using an internal cavity-loss method and a single-pass amplifier method. In addition, the saturation intensity is measured, and competition effects are studied. It is concluded that helium aids excitation of the upper laser levels by producing a significant increase in the electron temperature. Chlorine is shown to aid deexcitation of the lower laser levels by partially depopulating the metastable argon 4s levels that lie just below them.

Dauger, A. B.