Sterically controlled syntheses of optically active organic compounds. XV - Syntheses of optically active aspartic acid through beta-lactam.
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Active optical (Laser/Lidar) measurement techniques are critical for the future National Aeronautics and Space Administration (NASA) Earth, Planetary Science, Exploration, and Aeronautics measurements. The latest science decadal surveys recommend a number of missions requiring active optical systems to meet the science measurement objectives and the aeronautics community continues to use Laser/Lidar technologies to meet the aeronautics measurement objectives. With these drivers, the NASA Agency Program Management Council (APMC), chaired by the NASA Associate Administrator, has tasked the NASA Sensors and Instrumentation (S&I) Capability Leadership Team (CLT) Leader to determine if the Agency has the necessary expertise and capabilities to execute successfully the active optical-based systems necessary to make the required measurements for Science, Exploration, and Aeronautics. This NASA Technical Interchange Meeting (TIM) was a forum to exchange perspectives on the current state of the discipline’s technologies and the direction NASA needs to take in the future to raise the Technical Readiness Level (TRL) of the measurement technologies to meet these measurement needs in the applications domains. The information developed at this TIM was used in formulating the Agency-level strategy and solutions for advancing high-risk Laser/Lidar technologies that are not currently being sufficiently planned, developed, or risk-reduced to meet NASA’s mission requirements. Given the crosscutting synergies in critical Active Optical measurements for NASA Science, Exploration, and Aeronautics, a strategic approach is needed to identify areas where NASA should “lead, leverage or collaborate” with existing national and international industries to meet its future needs. The TIM aimed at focusing NASA’s directions to attain the necessary TRLs to meet the Agency-level priority Active Optical measurements in Space and Aeronautics. The TIM presentations and strategic inputs were synthesized by the NASA Active Optical Tiger Team for presentation to the NASA APMC with a suggested strategy to address the Agency’s needs in a crosscutting, synergistic and cost-effective manner.
Optical activity in organic matter contamination of meteorites
Optical activity in meteorite organic matter, recording observation of low amplitude
Optically activated data storage medium visually and electromagnetically reproduces a recorded signal. In an electric field, particles in heat-fluidized thermoplastic layer form a visible image of the recorded signal. Refluidizing the thermoplastic layer erases the signals. Very high data packing densities are achieved.
The active optics concept using a thin deformable mirror has been successfully demonstrated using a 30 in. diameter, 1/2 in. thick mirror and a 61 point matrix of forces for alignment. Many of the problems associated with the design, fabrication, and launch of large aperture diffraction-limited astronomical telescopes have been resolved and experimental data created that can provide accurate predictions of performance in orbit.
The active optics simulation system (AOSS) is a set of computer programs and associated software to be used in the development, design, and evaluation of a primary mirror control system for a large space telescope, (e.g., the tentatively proposed 3-meter telescope). The mathematical models of component subsystems and the solution of the physical processes that occur within the mirror surface control system were obtained, and based on these models AOSS simulates the behavior of the entire mirror surface control system as well as the behavior of the component subsystems. The program has a modular structure so that any subsystem module can be replaced or modified with minimum disruption of the rest of the simulation program.
STRIVES Entry: 20230013683, Abstract—Active optical (Laser/Lidar) measurement techniques are critical for the future National Aeronautics and Space Administration (NASA) Earth, Planetary Science, Exploration, and Aeronautics measurements. The latest science decadal surveys recommend several missions requiring active optical systems to meet the science measurement objectives and the aeronautics community continues to use Laser/Lidar technologies to meet the aeronautics measurement objectives. This presentation will provide an overview of NASA efforts in developing and maturing state-of-the-art advanced solid-state flight laser/lidar systems for airborne and space-borne remote sensing measurements. The presentation will also provide details of a strategic approach for active optical technologies and techniques to meet the NASA’s future Earth and Space Science measurements/missions needs and requirements for space-based applications.
Abstract—Active optical (Laser/Lidar) measurement techniques are critical for the future National Aeronautics and Space Administration (NASA) Earth, Planetary Science, Exploration, and Aeronautics measurements. The latest science decadal surveys recommend a number of missions requiring active optical systems to meet the science measurement objectives and the aeronautics community continues to use Laser/Lidar technologies to meet the aeronautics measurement objectives. This presentation will provide an overview of NASA efforts in developing and maturing state-of-the-art advanced solid-state flight laser/lidar systems for airborne and space-borne remote sensing measurements. The presentation will also provide details of a strategic approach for active optical technologies and techniques to meet the NASA’s future Earth and Space Science measurement ments for space-based applications.
Procedures for performing polarization ray tracing through birefringent media are presented in a form compatible with the standard methods of geometric ray tracing. The birefringent materials treated include the following: anisotropic optically active materials such as quartz, non-optically active uniaxial materials such as calcite, and isotropic optically active materials such as mercury sulfide or organic liquids. Refraction and reflection algorithms are presented which compute both ray directions and wave directions. Methods for computing polarization modes, refractive indices, optical path lengths, and Fresnel transmission and reflection coefficients are also specified.
Discussion of the segmented and deformable active optics approaches underlying some of the modern electrooptical techniques that are to be used in the design of future generations of giant-aperture orbital space telescopes. Combinations of laser interferometry and precise servomechanisms are shown to make possible the solution of such key problems of large monolithic mirrors in orbit as weight, thermal distortion, launchability, and material stability. The applicability of these active optics approaches to future giant-aperture space astronomy systems in the 200-inch to 400-inch diameter range is reviewed.
The realization of active full-shell x-ray optics will provide ground-breaking capability for future missions. Future X-ray missions, such as Lynx, require high angular-resolution, large effective area, and as wide a field of view(FOV) as possible. It is currently not possible to perform high-resolution imaging of both wide and narrow FOVs with a single X-ray telescope. In this paper, we discuss the use of actuators to switch the optical surface of full-shell x-ray optics between prescriptions optimized for narrow-field and wide-field viewing, as well as correct for low-spatial-frequency errors in the optics. Previously, a pathfinder was developed using finite-element modeling(FEM). Using a combination of the model’s influence functions, the capacity of active full-shell optics was shown to switch between prescriptions with 92% accuracy. Another benefit of the analytical pathfinder was its ability to correct low-spatial frequency errors, which comprise a large percentage of the MSFC full-shell x-ray optics root-mean-square (RMS) slope error. In order to verify the pathfinder, a surface-parallel actuator was bonded to a nickel-replicated coupon. After the actuator was bonded to the coupon, the slope of the surface was measured while the actuator was activated. The proof-of-concept demonstrator development, the influence function data, and the resulting implications on the analytical pathfinder are reported and discussed.
Synthesis of optically active alanine - amino acid
Active optical system for spaceborne, orbiting telescopes
Active optics concept development using thin deformable mirrors
One mechanism previously proposed for the abiotic accumulation of molecules of one chirality in nature is asymmetric adsorption on the chiral surfaces of optically active quartz crystals. Earlier literature in this field is reviewed, with the conclusion that previous investigations of this phenomenon, using optical rotation criteria, have afforded ambiguous results. We now have studied the adsorption of radioactive D- and L-alanine on powdered d- and l-quartz, using change in radioactivity level as a criterion for both gross and differential adsorption, d-Quartz preferentially adsorbed D-alanine from anhydrous dimethyl-formamide solution, and l-quartz L-alanine. The differential adsorption varied between 1.0 and 1.8%. The implications of these observations are discussed from the viewpoint of early chemical evolution and the origin of optically active organic compounds in nature.
Previous experiments undertaken in search of a correlation between the origin of optical activity in biological molecules and the helicity of beta particles emitted in nuclear beta decay have not provided any useful results. A description is presented of an experiment in which a low energy polarized positron beam of controlled helicity interacts with an optically active material to form positronium in vacuum. Advantages of the current study compared to the previous experiments are mainly related to a much greater sensitivity. Initially, it will be possible to detect a helicity-dependent asymmetry in triplet positronium formation of 1 part in 10,000. Improvements to better than 1 part in 100,000 should be attainable.
DL-aspartic acid resolved by optically active methylbenzylamine