Materials Data on ZrTiW4 by Materials Project
ZrTiW4 is Cubic Laves-derived structured and crystallizes in the cubic F-43m space group. The structure is three-dimensional. Zr is bonded in a 12-coordinate geometry to four equivalent Ti and twelve equivalent W atoms. All Zr–Ti bond lengths are 3.28 Å. All Zr–W bond lengths are 3.14 Å. Ti is bonded in a 12-coordinate geometry to four equivalent Zr and twelve equivalent W atoms. All Ti–W bond lengths are 3.14 Å. W is bonded to three equivalent Zr, three equivalent Ti, and six equivalent W atoms to form a mixture of face, edge, and corner-sharing WZr3Ti3W6 cuboctahedra. All W–W bond lengths are 2.68 Å.
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