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ZrPd is alpha-derived structured and crystallizes in the orthorhombic Cmcm space group. The structure is three-dimensional. Zr is bonded in a 7-coordinate geometry to seven equivalent Pd atoms. There are a spread of Zr–Pd bond distances ranging from 2.81–2.93 Å. Pd is bonded in a 7-coordinate geometry to seven equivalent Zr atoms.
ZrPd is Tetraauricupride structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. Zr is bonded in a body-centered cubic geometry to eight equivalent Pd atoms. All Zr–Pd bond lengths are 2.91 Å. Pd is bonded in a body-centered cubic geometry to eight equivalent Zr atoms.