Materials Data on ZrMnP by Materials Project
ZrMnP crystallizes in the orthorhombic Pnma space group. The structure is three-dimensional. Zr is bonded in a 5-coordinate geometry to five equivalent P atoms. There are a spread of Zr–P bond distances ranging from 2.68–2.75 Å. Mn is bonded to four equivalent P atoms to form a mixture of distorted edge and corner-sharing MnP4 tetrahedra. There are a spread of Mn–P bond distances ranging from 2.38–2.51 Å. P is bonded in a 9-coordinate geometry to five equivalent Zr and four equivalent Mn atoms.
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