Materials Data on ZrBr4 by Materials Project
ZrBr4 is Silicon tetrafluoride-like structured and crystallizes in the cubic Pa-3 space group. The structure is zero-dimensional and consists of eight zirconium tetrabromide molecules. Zr4+ is bonded in a tetrahedral geometry to four Br1- atoms. All Zr–Br bond lengths are 2.49 Å. There are two inequivalent Br1- sites. In the first Br1- site, Br1- is bonded in a single-bond geometry to one Zr4+ atom. In the second Br1- site, Br1- is bonded in a single-bond geometry to one Zr4+ atom.
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