Materials Data on Zn(WN)2 by Materials Project
Zn(WN)2 crystallizes in the tetragonal P-4m2 space group. The structure is two-dimensional and consists of one Zn(WN)2 sheet oriented in the (0, 0, 1) direction. W2+ is bonded in a bent 120 degrees geometry to two equivalent N3- atoms. Both W–N bond lengths are 1.93 Å. Zn2+ is bonded to four equivalent N3- atoms to form corner-sharing ZnN4 tetrahedra. All Zn–N bond lengths are 2.07 Å. N3- is bonded to two equivalent W2+ and two equivalent Zn2+ atoms to form corner-sharing NZn2W2 tetrahedra.
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