Materials Data on Zn(SnN)2 by Materials Project
Zn(SnN)2 crystallizes in the monoclinic C2 space group. The structure is two-dimensional and consists of one Zn(SnN)2 sheet oriented in the (0, 0, 1) direction. Zn2+ is bonded to four equivalent N3- atoms to form corner-sharing ZnN4 tetrahedra. All Zn–N bond lengths are 2.05 Å. Sn2+ is bonded in a water-like geometry to two equivalent N3- atoms. There are one shorter (2.11 Å) and one longer (2.12 Å) Sn–N bond lengths. N3- is bonded to two equivalent Zn2+ and two equivalent Sn2+ atoms to form corner-sharing NZn2Sn2 tetrahedra.