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YbPd is Tetraauricupride structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. Yb is bonded in a body-centered cubic geometry to eight equivalent Pd atoms. All Yb–Pd bond lengths are 2.99 Å. Pd is bonded in a body-centered cubic geometry to eight equivalent Yb atoms.
YbPd crystallizes in the orthorhombic Pnma space group. The structure is three-dimensional. Yb is bonded in a 7-coordinate geometry to seven equivalent Pd atoms. There are a spread of Yb–Pd bond distances ranging from 2.93–3.04 Å. Pd is bonded in a 7-coordinate geometry to seven equivalent Yb and two equivalent Pd atoms. Both Pd–Pd bond lengths are 2.81 Å.