Materials Data on Y2ZnSe4 by Materials Project
Y2ZnSe4 is Spinel structured and crystallizes in the cubic Fd-3m space group. The structure is three-dimensional. Y3+ is bonded to six equivalent Se2- atoms to form YSe6 octahedra that share corners with six equivalent ZnSe4 tetrahedra and edges with six equivalent YSe6 octahedra. All Y–Se bond lengths are 2.87 Å. Zn2+ is bonded to four equivalent Se2- atoms to form ZnSe4 tetrahedra that share corners with twelve equivalent YSe6 octahedra. The corner-sharing octahedral tilt angles are 55°. All Zn–Se bond lengths are 2.54 Å. Se2- is bonded in a distorted rectangular see-saw-like geometry to three equivalent Y3+ and one Zn2+ atom.
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