Materials Data on WO2F by Materials Project
WO2F is High-temperature superconductor-derived structured and crystallizes in the monoclinic C2/c space group. The structure is three-dimensional. W5+ is bonded to four equivalent O2- and two equivalent F1- atoms to form corner-sharing WO4F2 octahedra. The corner-sharing octahedra tilt angles range from 4–6°. There is two shorter (1.87 Å) and two longer (2.02 Å) W–O bond length. Both W–F bond lengths are 2.08 Å. O2- is bonded in a linear geometry to two equivalent W5+ atoms. F1- is bonded in a linear geometry to two equivalent W5+ atoms.
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