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Materials Data on WCO2 by Materials Project

WCO2 crystallizes in the tetragonal P4/mmm space group. The structure is three-dimensional. W6+ is bonded to two equivalent C2- and four equivalent O2- atoms to form corner-sharing WC2O4 octahedra. The corner-sharing octahedral tilt angles are 0°. Both W–C bond lengths are 2.11 Å. All W–O bond lengths are 1.94 Å. C2- is bonded in a linear geometry to two equivalent W6+ atoms. O2- is bonded in a linear geometry to two equivalent W6+ atoms.

36 MATERIALS SCIENCE↗