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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Detection of hot electrons originating from an upper valley at ∼1.7eV above the Γ valley in wurtzite GaN using electron emission spectroscopy

Using electron emission spectroscopy, measurement and analysis were conducted on the energy distribution of vacuum emitted electrons from electrically driven InGaN/GaN green (peak wavelengths 𝜆 ≈ 515nm) light-emitting diodes (LEDs) with and without a prewell superlattice (SL). Here, we report on the detection of a high-energy upper valley at ∼ 1.7eV above the Γ valley from samples with no prewell SL. We propose that these upper valley electrons originate predominantly from trap-assisted Auger recombination (TAAR) in green LEDs, as the intensity of these peaks is found to have quadratic dependence on the carrier density 𝑛 [see Espenlaub et al., J. Appl. Phys. 126, 184502 (2019)]. The high-energy upper valley peak was not observed in the sample with a prewell SL which is attributed to gettering by the prewell SL of still unidentified impurities that act as TAAR centers.

carrier generation & recombination↗
DOE OSTI2019

Detection of thermodynamic "valley noise" in monolayer semiconductors: access to intrinsic valley relaxation timescales

Together with charge and spin, many novel two-dimensional materials also permit information to be encoded in an electron’s valley degree of freedom—that is, in particular momentum states in the material’s Brillouin zone. With a view toward valley-based (opto)electronic technologies, the intrinsic time scales of valley scattering are therefore of fundamental interest. Here, we demonstrate an entirely noise-based approach for exploring valley dynamics in monolayer transition-metal dichalcogenide semiconductors. Exploiting their valley-specific optical selection rules, we use optical Faraday rotation to passively detect the thermodynamic fluctuations of valley polarization in a Fermi sea of resident carriers. This spontaneous “valley noise” reveals narrow Lorentzian line shapes and, therefore, long exponentially-decaying intrinsic valley relaxation. Moreover, the noise signatures validate both the relaxation times and the spectral dependence of conventional (perturbative) pump-probe measurements. These results provide a viable route toward quantitative measurements of intrinsic valley dynamics, free from any external perturbation, pumping, or excitation.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
NASA NTRS1986

Morphology of large valleys on Hawaii - Evidence for groundwater sapping and comparisons with Martian valleys

Morphometric data on the runoff and sapping valleys on the slopes of Hawaii and Molokai in Hawaii are analyzed. The analysis reveals a clear distinction between the runoff valleys and sapping valleys. The Hawaiian sapping valleys are characterized by: (1) steep valley walls and flat floors, (2) amphitheater heads, (3) low drainage density, (4) paucity of downstream tributaries, (5) low frequency of up-dip tributaries, and (6) structural and stratigraphic control on valley patterns. The characteristics of the Hawaiian sapping valleys are compared to Martian valleys and experimental systems, and good correlation between the data is detected. Flume experiments were also conducted to study the evolution of sapping valleys in response to variable structure and stratigraphy.

Kochel, R. Craig↗
DOE OSTI2020

Valley Polarization and Inversion in Strained Graphene via Pseudo-Landau Levels, Valley Splitting of Real Landau Levels, and Confined States

It is quite easy to control spin polarization and the spin direction of a system via magnetic fields. However, there is no such direct and efficient way to manipulate the valley pseudospin degree of freedom. Here, we demonstrate experimentally that it is possible to realize valley polarization and valley inversion in graphene by using both strain-induced pseudomagnetic fields and real magnetic fields. Pseudomagnetic fields, which are quite different from real magnetic fields, point in opposite directions at the two distinct valleys of graphene. Therefore, the coexistence of pseudomagnetic fields and real magnetic fields leads to imbalanced effective magnetic fields at two distinct valleys of graphene. This allows us to control the valley in graphene as conveniently as the electron spin. In this work, we report a consistent observation of valley polarization and inversion in strained graphene via pseudo-Landau levels, splitting of real Landau levels, and valley splitting of confined states using scanning tunneling spectroscopy. Finally our results highlight a pathway to valleytronics in strained graphene-based platforms.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2025

The Short Life of Upvalley Wind in a High‐Altitude Valley in the Colorado Rocky Mountains

Thermally driven upvalley (UV) wind in the upper East River Valley in the Colorado Rocky Mountains often unexpectedly stops in midmorning and reverses back to downvalley (DV) wind. We use a comprehensive observational data set for a nearly two‐year long period to analyze the wind system and boundary layer evolution in this high‐altitude valley and determine the reason for this early wind reversal. Days with short UV wind predominantly occur during the warm season when the valley floor is free of snow and the convective boundary layer (CBL) grows well above the height of the surrounding ridges. UV wind persists throughout the day only on a few days during the warm season. We link differences in valley wind evolution to wind direction at upper levels at and above ridge height and propose forced channeling mechanisms to describe coupling between valley and upper‐level wind when the CBL grows above ridge height. The frequency distribution of upper‐level wind direction is such that channeling in the DV direction is favored, which explains the predominance of days with short UV wind. The deep CBL is supported by the presence of a deep weakly stably stratified residual layer with high aerosol content, which is regularly present over the mountain range during the warm season. On days when the CBL does not grow above ridge height, for example, when the valley floor is covered by snow, thermally driven UV wind is able to persist throughout the day independent of upper‐level wind direction.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2020

Valley pumping via edge states and the nonlocal valley Hall effect in two-dimensional semiconductors

Recent experiments have studied the temperature and gate voltage dependence of nonlocal transport in bilayer graphene, identifying features thought to be associated with the two-dimensional semiconductor's bulk intrinsic valley Hall effect. Here, we use both simple microscopic tight-binding ribbon models and phenomenological bulk transport equations to emphasize the impact of sample edges on the nonlocal voltage signals. We show that the nonlocal valley Hall response is sensitive to electronic structure details at the sample edges and that it is enhanced when the local longitudinal conductivity is larger near the sample edges than in the bulk. We discuss recent experiments in light of these findings and also discuss the close analogy between electron pumping between valleys near two-dimensional sample edges in the valley Hall effect and bulk pumping between valleys due to the chiral anomaly in three-dimensional topological semimetals.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2017

Giant Valley Splitting and Valley Polarized Plasmonics in Group V Transition-Metal Dichalcogenide Monolayers

Two-dimensional group VI transition-metal dichalcogenides (TMDs) provide a promising platform to encode and manipulate quantum information in the valleytronics. However, the two valleys are energetically degenerate, protected by time-reversal symmetry (TRS). To lift this degeneracy, one needs to break the TRS by either applying an external magnetic field or using a magnetic rare-earth oxide substrate. Here, we predict a different strategy to achieve this goal. We propose that the ferromagnetic group V TMD monolayer, in which the TRS is intrinsically broken, can produce a larger valley and spin splitting. A polarized ZnS(0001) surface is also used as a substrate, which shifts the valleys to the low-energy regime (near the Fermi level). Moreover, by calculating its collective electronic excitation behaviors, we show that such a system hosts a giant valley polarized terahertz plasmonics. Our results demonstrate a new way to design and use valleytronic devices, which are both fundamentally and technologically significant.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2023

Tunable spin and valley excitations of correlated insulators in Γ-valley moiré bands

Moiré superlattices formed from transition metal dichalcogenides (TMDs) have been shown to support a variety of quantum electronic phases that are highly tunable using applied electromagnetic fields. While the valley character of the low-energy states dramatically affects optoelectronic properties in the constituent TMDs, this degree of freedom has yet to be fully explored in moiré systems. Here, we establish twisted double bilayer WSe 2 as an experimental platform to study electronic correlations within Γ-valley moiré bands. Through a combination of local and global electronic compressibility measurements, we identify charge-ordered phases at multiple integer and fractional moiré band fillings ν. By measuring the magnetic field dependence of their energy gaps and the chemical potential upon doping, we reveal spin-polarized ground states with novel spin polaron quasiparticle excitations. In addition, an applied displacement field allows us to realize a new mechanism of metal-insulator transition at ν=–1 driven by tuning between Γ- and K-valley moiré bands. Together, our results demonstrate control over both the spin and valley character of the correlated ground and excited states in this system.

36 MATERIALS SCIENCE↗
NASA NTRS1988

Groundwater sapping valleys: Experimental studies, geological controls and implications to the interpretation of valley networks on Mars

An integrated approach using experimental laboratory models, field studies of terrestrial analogs, and remote studies of terrestrial field sites were applied to the goals of understanding the nature and morphology of valley networks formed by groundwater sapping. In spite of problems with scaling, the experimental studies provide valuable insights into concepts relating to the initiation, development, and evolution of valleys by groundwater sapping. These investigations are also aimed at developing geomorphic criteria for distinguishing valleys formed by surface runoff from those formed by groundwater sapping processes. Channels that were field classified as sapping vs. runoff were successfully distinguished using statistical analysis of their respective morphologies; therefore, it may be possible to use similar techniques to interpret channel genesis on Mars. The terrestrial and flume studies provide the ground truth dataset which can be used (and will be during the present year) to help interpret the genesis of valley networks on Mars.

Kochel, R. Craig↗
NASA NTRS2004

Education Outreach Associated with Technology Transfer in a Colonia of South Texas: Green Valley Farms Science and Space Club for Middle School Aged Children in Green Valley Farms, San Benito, Texas

Texas colonias are unincorporated subdivisions characterized by inadequate water and wastewater infrastructure, inadequate drainage and road infrastructure, substandard housing, and poverty. Since 1989 the Texas Legislature has implemented policies to halt further development of colonias and to address water and wastewater infrastructure needs in existing and new colonias along the border with Mexico. Government programs and non-government and private organization projects aim to address these infrastructure needs. Texas Tech University's Water Resources Center demonstrated the use of alternative on-site wastewater treatment in the Green Valley Farms colonia, San Benito, Texas. The work in Green Valley Farms was a component of a NASA-funded project entitled Evaluation of NASA's Advanced Life Support Integrated Water Recovery System for Non-Optimal Conditions and Terrestrial Applications. Two households within the colonia are demonstration sites for constructed wetlands. A colonia resident and activist identified educational opportunities for colonia children as a primary goal for many colonia residents. Colonia parents view education as the door to opportunity and escape from poverty for their children. The educational outreach component of the project in Green Valley Farms was a Science and Space Club for middle-school age students. Involved parents, schoolteachers, and school administrators enthusiastically supported the monthly club meetings and activities. Each month, students participated in interactive learning experiences about water use and reuse in space and on earth. Activities increased knowledge and interest in water resource issues and in science and engineering fields. The Institute for the Development and Enrichment of Advanced Learners (IDEAL) at Texas Tech University provided full scholarships for five students from Green Valley Farms to attend the Shake Hands With Your Future camp at Texas Tech University in June 2003. The educational outreach component was evaluated in February 2004 using survey instruments for students and parents, and interviews with science teachers and counselors.

Potess, Marla D.↗
DOE OSTI2016

Taxonomic and Functional Diversity of Soil and Hypolithic Microbial Communities in Miers Valley, McMurdo Dry Valleys, Antarctica

The McMurdo Dry Valleys of Antarctica are an extreme polar desert. Mineral soils support subsurface microbial communities and translucent rocks support development of hypolithic communities on ventral surfaces in soil contact. Despite significant research attention, relatively little is known about taxonomic and functional diversity or their inter-relationships. Here we report a combined diversity and functional interrogation for soil and hypoliths of the Miers Valley in the McMurdo Dry Valleys of Antarctica. The study employed 16S rRNA fingerprinting and high throughput sequencing combined with the GeoChip functional microarray. The soil community was revealed as a highly diverse reservoir of bacterial diversity dominated by actinobacteria. Hypolithic communities were less diverse and dominated by cyanobacteria. Major differences in putative functionality were that soil communities displayed greater diversity in stress tolerance and recalcitrant substrate utilization pathways, whilst hypolithic communities supported greater diversity of nutrient limitation adaptation pathways. A relatively high level of functional redundancy in both soil and hypoliths may indicate adaptation of these communities to fluctuating environmental conditions.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS2020

Central Valley Water Resources II: Groundwater Sustainability Management Support in the California Central Valley using GRACE and InSAR Datasets

California’s Central Valley is one of the most productive agricultural regions in the United States, producing a fourth of the nation’s food supply. The water demand in this region is heavily dependent on groundwater resources, resulting in over pumping of aquifers at unsustainable rates during recent periods of severe drought. Over the past century, Central Valley aquifers have experienced a significant decline in groundwater levels, resulting in land subsidence and irreversible loss in groundwater storage. In 2014, the state enacted the Sustainable Groundwater Management Act, requiring high and medium priority subbasins to suspend overdraft and achieve sustainable levels of pumping and recharge by 2042.The California Department of Water Resources (DWR) oversees subbasin groundwater management; however, monitoring remains challenging due to sparse and inconsistent in situ data. To assist the DWR, this project developed a user-friendly executable application and an interactive visualization tool to quantify groundwater storage and land subsidence trends using remotely sensed and in situ data. The team utilized NASA’s Gravity Recovery and Climate Experiment (GRACE), GRACE Follow-On (GRACE-FO), Sentinel-1 C-band Synthetic Aperture Radar (C-SAR) interferograms, and Advanced Land Observing Satellite 2 (ALOS-2) Phased Array L-band Synthetic Aperture Radar 2 (PALSAR-2) interferograms in conjunction with well and GPS measurements to analyze groundwater and subsidence trends. GRACE and well data returns produced a strong Pearson correlation of .84, while Sentinel-1 and GPS data returns produced a Pearson correlation of .41 over the entire Central Valley. These findings suggest remotely sensed GRACE and interferometric SAR data can be used in the absence of in situ data.

DEVELOP Project Summary↗
DOE OSTI2024

High-temperature quantum valley Hall effect with quantized resistance and a topological switch

Edge states of a topological insulator can be used to explore fundamental science emerging at the interface of low dimensionality and topology. Achieving a robust conductance quantization, however, has proven challenging for helical edge states. In this work, we show wide resistance plateaus in kink states—a manifestation of the quantum valley Hall effect in Bernal bilayer graphene—quantized to the predicted value at zero magnetic field. The plateau resistance has a very weak temperature dependence up to 50 kelvin and is flat within a dc bias window of tens of millivolts. We demonstrate the electrical operation of a topology-controlled switch with an on/off ratio of 200. These results demonstrate the robustness and tunability of the kink states and its promise in constructing electron quantum optics devices.

Science & Technology - Other Topics↗
DOE OSTI2013

Scotts Valley Energy Office and Human Capacity Project: Scotts Valley Band of Pomo Indians

The primary goal of this project is to develop a Scotts Valley Energy Development Office (SVEDO). This office will further support the mission of the Tribe's existing leadership position as the DOE Tribal Multi-County Weatherization Energy Program (TMCWEP) in creating jobs and providing tribal homes and buildings with weatherization assistance to increase energy efficiency, occupant comfort and improved indoor air quality. This office will also spearhead efforts to move the Tribe towards its further strategic energy goals of implementing renewable energy systems through specific training, resource evaluation, feasibility planning, and implementation. Human capacity building and continuing operations are two key elements of the SVEDO objectives. Therefore, the project will 1) train and employ additional Tribal members in energy efficiency, conservation and renewable resource analyses and implementation; 2) purchase materials and equipment required to implement the strategic priorities as developed by the Scotts Valley Tribe which specifically include implementing energy conservation measures and alternative energy strategies to reduce energy costs for the Tribe and its members; and 3) obtain a dedicated office and storage space for ongoing SVEDO operations.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗