Materials Data on V3F by Materials Project
(V)2V1F crystallizes in the tetragonal I4/mmm space group. The structure is two-dimensional and consists of two V sheets oriented in the (0, 0, 1) direction and two V1F sheets oriented in the (0, 0, 1) direction. In each V sheet, V is bonded in a distorted square co-planar geometry to four equivalent V atoms. All V–V bond lengths are 2.60 Å. In each V1F sheet, V is bonded in a square co-planar geometry to four equivalent F atoms. All V–F bond lengths are 2.60 Å. F is bonded in a square co-planar geometry to four equivalent V atoms.
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