Materials Data on V3(PbO3)4 by Materials Project
Pb4(VO4)3 crystallizes in the cubic I-43d space group. The structure is three-dimensional. V+4.67+ is bonded in a tetrahedral geometry to four equivalent O2- atoms. All V–O bond lengths are 1.75 Å. Pb+2.50+ is bonded in a 6-coordinate geometry to six equivalent O2- atoms. There are three shorter (2.35 Å) and three longer (2.75 Å) Pb–O bond lengths. O2- is bonded in a 1-coordinate geometry to one V+4.67+ and two equivalent Pb+2.50+ atoms.
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