Materials Data on V2P by Materials Project
V2P is Cotunnite structured and crystallizes in the orthorhombic Pnma space group. The structure is three-dimensional. there are two inequivalent V sites. In the first V site, V is bonded in a 4-coordinate geometry to four equivalent P atoms. There are a spread of V–P bond distances ranging from 2.33–2.47 Å. In the second V site, V is bonded in a 5-coordinate geometry to five equivalent P atoms. There are a spread of V–P bond distances ranging from 2.44–2.67 Å. P is bonded in a 9-coordinate geometry to nine V atoms.
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