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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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NASA NTRS1981

The isotopic composition of uranium and lead in Allende inclusions and meteoritic phosphates

The isotopic compositions of uranium and lead in Ca-Al-rich inclusions from the Allende chondrite and in whitlockite from the St. Severin chondrite and the Angra dos Reis achondrite are reported. Isoptopic analysis of acid soluble fractions of the Allende inclusions and the meteoritic whitlockite, which show isotopic anomalies in other elements, reveals U-235/U-238 ratios from 1/137.6 to 1/138.3, within 20 per mil of normal terrestrial U abundances. The Pb isotopic compositions of five coarse-grained Allende inclusions give a mean Pb-207/Pb-206 model age of 4.559 + or - 0.015 AE, in agreement with the U results. Pb isotope ratios of two fine-grained inclusions and a coarse-grained inclusion with strong mass fractionation and some nonlinear isotopic anomalies indicate that the U-Pb systems of these inclusions have evolved differently from the rest of Allende. Th/U abundance ratios in the Allende inclusions and meteoritic phosphate are found to range from 3.8 to 96, presumably indicating an optimal case for Cm/U fractionation, although the normal U concentrations do not support claims of abundant live Cm-247 or Cm-247/U-238 fractionation at the time of meteorite formation, in contrast to previous results. A limiting Cm-247/U-235 ratio of 0.004 at the time of meteorite formation is calculated which implies that the last major r process contribution at the protosolar nebula was approximately 100 million years prior to Al-26 formation and injection.

Chen, J. H.↗

NASA NTRS1982

Chemistry of uranium in aluminophosphate glasses

The U(VI)-U(V)-U(IV) redox equilibria are investigated in two sodium aluminophosphate base compositions at a variety of melt temperatures, imposed oxygen fugacities, and uranium contents. Results show that the higher redox states of uranium are quite soluble in the phosphate glasses, although U(IV) readily precipitates from the melts as UO2. In addition, comparisons of the uranium redox equilibria established in phosphate melts versus those in silicate melts shows that the coordination sites of the individual uranium species are generally the same in both solvent systems although they differ in detail.

Schreiber, H. D.↗

NASA NTRS1975

Improved ion exchange membrane

Membrane, made from commercially-available hollow fibers, is used in reverse osmosis, or dialysis. Fiber has skin layers which pass only small molecules. Macromolecules cannot penetrate skin. Fibers can also be used to remove other undesirable anions, such as phosphate, sulfate, carbonate, and uranium in form of uranium-sulfate complex.

Rembaum, A.↗

NASA NTRS1982

Fission track studies of xenolithic chondrites - Implications regarding brecciation and metamorphism

Fission tracks in phosphates from one gas-poor chondrite and three gas-rich ones are studied to determine their thermal history and brecciation time scales. Model fission track ages are calculated for given track densities due to Pu-244 and U-238; track densities and uranium measurements for whitlockite are shown, and possible sources of the tracks are mentioned. Details of track density and uranium measurements are discussed for each meteorite separately. Whitlockites from all the meteorites give model fission track ages of 4.4 Gyr assuming a Pu/U ratio at 4.55 Gyr of 0.045. The final brecciation event definitely did not reset the track clock in phosphates of one meteor and probably not in another two. It is concluded that the observed fission track ages date the end of metamorphic cooling in the meteorite parent bodies and support the planetesimal model for the formation of xenolithic chondrites.

Kothari, B. K.↗

NASA NTRS1992

TREK - A cosmic-ray experiment on the Russian space station Mir

The goals of the TREK experiment, now in place on the Mir space station, are to resolve and measure the composition of both odd-Z and even-Z cosmic-ray nuclei up to uranium, to measure the isotopic composition of Fe-group nuclei, and to search for transuranic nuclei and exotic particles such as strangelets. To collect tracks of ultraheavy cosmic rays, exterior panels holding an array of BP-1 phosphate glass 1.2 sq m in area and 16 plates thick are now mounted outside the Kvant-2 module on Mir. Heaters and relays regulate the temperature of the glass at 25 +/- 5 C. The detectors will record about 1000 cosmic-ray tracks with Z greater than or equal to 50 during about 2.5 years. An interior panel consisting of an array 0.09 sq m in area and 32 plates thick and mounted on the inside wall of the Soyuz spacecraft will collect tracks of about 13,000 Fe and 500 Ni nuclei.

Price, P. B.↗

NASA NTRS1986

Nuclear tracks, Sm isotopes and neutron capture effects in the Elephant Morraine shergottite

Nuclear track studies, uranium concentration measurements and Sm-isotope studies have been performed on both lithologies A and B of the Elephant Morraine shergottite, EETA 79001. Track studies show that EETA 79001 was a rather small object in space with a preatmospheric radius of 12 + or - 2 cm, corresponding to a preatmospheric mass of 28 + or - 13 kg. Phosphates have U concentrations ranging from 0.3 to 1.3 ppm. There are occasional phosphates with excess fission tracks, possibly produced from neutron-induced fission of U and Th, during the regolith exposure in the shergottite parent body (SPB). Sm-isotope studies, while not showing any clear-cut excess in Sm-150, make it possible to derive meaningful upper limits to thermal neutron fluences of 2 to 3 x 10 to the 15th n/sq cm, during a possible regolith irradiation. These limits are consistent with the track data and also make it possible to derive an upper limit to the neutron exposure age of EETA 79001 of 55 Myr in the SPB regolith.

Rajan, R. S.↗