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At least 19 records

Virtual Special Issue on Catalysis at the U.S. Department of Energy’s National Laboratories

Catalysis research at the U.S. Department of Energy's (DOE's) National Laboratories covers a wide range of research topics in heterogeneous catalysis, homogeneous/molecular catalysis, biocatalysis, electrocatalysis, and surface science. Since much of the work at National Laboratories is funded by DOE, the research is largely focused on addressing DOE's mission to ensure America's security and prosperity by addressing its energy, environmental, and nuclear challenges through transformative science and technology solutions. The catalysis research carried out at the DOE National Laboratories ranges from very fundamental catalysis science, funded by DOE's Office of Basic Energy Sciences (BES), to applied research and development (R&D) in areas such as biomass conversion to fuels and chemicals, fuel cells, and vehicle emission control with primary funding from DOE's Office of Energy Efficiency and Renewable Energy.

09 BIOMASS FUELS↗

Airborne measurements of western U.S. wildfire emissions: Comparison with prescribed burning and air quality implications: Western U.S. Wildfire Emissions

Wildfires emit significant amounts of pollutants that degrade air quality. Plumes from three wildfires in the western U.S. were measured from aircraft during the Studies of Emissions and Atmospheric Composition, Clouds and Climate Coupling by Regional Surveys (SEAC4RS) and the Biomass Burning Observation Project (BBOP), both in summer 2013. This study reports an extensive set of emission factors (EFs) for over 80 gases and 5 components of submicron particulate matter (PM 1 ) from these temperate wildfires. These include rarely, or never before, measured oxygenated volatile organic compounds and multifunctional organic nitrates. The observed EFs are compared with previous measurements of temperate wildfires, boreal forest fires, and temperate prescribed fires. Furthermore, the wildfires emitted high amounts of PM 1 (with organic aerosol (OA) dominating the mass) with an average EF that is more than 2 times the EFs for prescribed fires. The measured EFs were used to estimate the annual wildfire emissions of carbon monoxide, nitrogen oxides, total nonmethane organic compounds, and PM 1 from 11 western U.S. states. The estimated gas emissions are generally comparable with the 2011 National Emissions Inventory (NEI). However, our PM 1 emission estimate (1530 ± 570 Gg yr -1 ) is over 3 times that of the NEI PM2.5 estimate and is also higher than the PM2.5 emitted from all other sources in these states in the NEI. This study indicates that the source of OA from biomass burning in the western states is significantly underestimated. Additionally, our results indicate that prescribed burning may be an effective method to reduce fine particle emissions.

54 ENVIRONMENTAL SCIENCES↗

U.S. energy sector impacts of technology innovation, fuel price, and electric sector CO2 policy: Results from the EMF 32 model intercomparison study

We study the impact of fuel prices, technology innovation, and a CO2 emissions reduction policy on both the electric power and end-use sectors by comparing outputs from four U.S. energy-economic models through the year 2050. Achieving innovation goals decreases CO2 emissions in all models, regardless of natural gas price, due to increased energy efficiency and low-carbon generation becoming more cost competitive. For the models that include domestic natural gas markets, achieving innovation goals lowers wholesale electricity prices, but this effect diminishes as projected natural gas prices increase. Higher natural gas prices lead to higher wholesale electricity prices but fewer coal capacity retirements. A CO2 electric power sector emissions cap influences electric sector evolution under reference technology assumptions but has little to no incremental influence when added to innovation goals. Long-term, meeting innovation goals achieves a generation mix with similar CO2 emissions compared to the CO2 policy but with smaller increases to wholesale electricity prices. In the short-term, the relative effect on wholesale prices differs by model. Finally, higher natural gas prices, achieving innovation goals, and the combination of the two, increases the amount of renewable generation that is cost-effective to build and operate while slowing the growth of natural-gas fired generation, which is the predominant generation type in 2050 under reference conditions.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

A comparison of battery testing protocols: Those used by the U.S. advanced battery consortium and those used in China

Two testing protocols, QC/T 743 and those used by the U.S. Advanced Battery Consortium (USABC), were compared using cells based on LiFePO4/graphite chemistry. Differences in the protocols directly affected the data and the performance decline mechanisms deduced from the data. In all cases, the rate of capacity fade was linear with time. Overall, the testing protocols produced very similar data when the testing conditions and metrics used to define performance were similar. The choice of depth of discharge and pulse width had a direct effect on the apparent rate of resistance increased and estimated cell life. At greater percent depth of discharge (%DOD) and pulse width, the estimated life was shorter that at lower %DOD and shorter pulse width. This indicates that cells which were at the end of life based on the USABC protocol were not at end of life based on the QC/T 743 protocol by a large margin. (C) 2016 ELSEVIER B.V. All rights reserved.

battery testing↗

Multi-decade high-resolution regional hindcasts for wave energy resource characterization in U.S. coastal waters

Long-term, high-resolution, regional wave hindcast datasets were generated using unstructured-grid Simulating WAves Nearshore (SWAN) models for the U.S. coastal waters to support nearshore wave energy development in the U.S. including those bordering U.S. territorial islands. The model domains resolved the entire U.S. exclusive economic zones, with a spatial resolution of approximately 200 m nearshore. The regional SWAN models were driven by the global WAVEWATCH III® model outputs and run for a 42-year period from 1979 to 2020. Extensive model validations were performed using buoy observations and altimeter data. Regional resource characterization was performed based on hindcast data points at 2 km from shore and along the 100 m isobath. Aggregations of wave resource parameters were produced, and spatial and seasonal variations were analyzed for all the regions. Wave resource metrics recommended by international standards, including a 3-hour time series of six resource parameters, hourly frequency- and directionally resolved wave spectra at selected “virtual buoy” locations, and average-annual values of omni-directional wave power, significant wave height, and energy period are publicly disseminated through an Amazon Web Service and a Marine Energy Atlas web application tool to facilitate wave energy research and a wide range of coastal ocean applications.

16 TIDAL AND WAVE POWER↗

High-resolution Hindcasts for U.S. Wave Energy Resource Characterization

The marine and hydrokinetic (MHK) industry is at an early stage of development and has the potential to play a significant role in diversifying the U.S. energy portfolio and reducing the U.S. carbon footprint. Wave energy is the largest among all the U.S. MHK energy resources, which include wave energy, ocean current, tidal-instream, ocean thermal energy conversion, and river-instream. Wave resource characterization is an essential step for regional wave energy assessments, Wave Energy Converter (WEC) project development, site selection and WEC design. The present paper provides an overview of a joint modelling effort by the Pacific Northwest National Laboratory and Sandia National Laboratories on high-resolution wave hindcasts to support the U.S. Department of Energy’s Water Power Technologies Office’s program of wave resource characterization, assessment and classifications in all US coastal regions. Topics covered include the modelling approach, model input requirements, model validation strategies, high performance computing resource requirements, model outputs and data management strategies. Examples of model setup and validation for different regions are provided along with application to development of classification systems, and analysis of regional wave climates. Lessons learned and technical challenges of the long-term, high-resolution regional wave hindcast are discussed.

Yang, Zhaoqing↗

Subseasonal Variability of U.S. Coastal Sea Level from MJO and ENSO Teleconnection Interference

Abstract Climate variability affects sea levels as certain climate modes can accelerate or decelerate the rising sea level trend, but subseasonal variability of coastal sea levels is underexplored. This study is the first to investigate how remote tropical forcing from the MJO and ENSO impact subseasonal U.S. coastal sea level variability. Here, composite analyses using tide gauge data from six coastal regions along the U.S. East and West Coasts reveal influences on sea level anomalies from both the MJO and ENSO. Tropical MJO deep convection forces a signal that results in U.S. coastal sea level anomalies that vary based on MJO phase. Further, ENSO is shown to modulate both the MJO sea level response and background state of the teleconnections. The sea level anomalies can be significantly enhanced or weakened by the MJO-associated anomaly along the East Coast due to constructive or destructive interference with the ENSO-associated anomaly, respectively. The West Coast anomaly is found to be dominated by ENSO. We examine physical mechanisms by which MJO and ENSO teleconnections impact coastal sea levels and find consistent relationships between low-level winds and sea level pressure that are spatially varying drivers of the variability. Two case studies reveal how MJO and ENSO teleconnection interference played a role in notable coastal flooding events. Much of the focus on sea level rise concerns the long-term trend associated with anthropogenic warming, but on shorter time scales, we find subseasonal climate variability has the potential to exacerbate the regional coastal flooding impacts. Significance Statement Coastal flooding due to sea level rise is increasingly threatening communities, but natural fluctuations of coastal sea levels can exacerbate the human-caused sea level rise trend. This study assesses the role of tropical influences on coastal subseasonal (2 weeks–3 months) sea level heights. Further, we explore the mechanisms responsible, particularly for constructive interference of signals contributing to coastal flooding events. Subseasonal signals amplify or suppress the lower-frequency signals, resulting in higher or lower sea level heights than those expected from known climate modes (e.g., ENSO). Low-level onshore winds and reduced sea level pressure connected to the tropical phenomena are shown to be indicators of increased U.S. coastal sea levels, and vice versa. Two case studies reveal how MJO and ENSO teleconnection interference played a role in notable coastal flooding events. Much of the focus on sea level rise concerns the long-term trend associated with anthropogenic warming, but on shorter time scales, we find subseasonal climate variability has the potential to exacerbate the regional coastal flooding impacts.

Meteorology & Atmospheric Sciences↗

Prevalence of typical operational problems and energy savings opportunities in U.S. commercial buildings

In the United States, as much as 30% of the 19 EJ that commercial buildings consume is considered excess. Much of the excess energy is due to the inability to manage building operations efficiently. Because almost 20% of the total primary energy consumption is associated with commercial buildings, significant energy reductions in this sector are needed to mitigate climate change. Therefore, many cities and states are mandating periodic “tune-ups” of these buildings to eliminate excess energy consumption. Although the benefits of tune-ups and retro-commissioning are clear, focusing these mandates to look for specific opportunities has been a challenge because of the lack of studies that document the prevalence of opportunities. Therefore, we analyzed building automation system data from 151 buildings across the United States to document common operational problems and opportunities to improve building operations. This analysis showed that opportunities to improve building operations exist in almost every building. These opportunities were not strongly correlated with building vintage or size, but were reflective of how the buildings are operated. The prevalence of the top 20 opportunities ranged between 74% and 23%, with 40% of these associated with air-handling units. The rest of the opportunities are associated with schedules, chilled and hot-water distribution, and zone controls. Of the 151 buildings, 69 of them implemented corrective actions of some or all opportunities that were identified. Implementation varied across the Re-tuning categories, with 60% for schedule opportunities, 50% for zone opportunities, over 40% for the air-handling unit and hot-water opportunities, and 35% of the chilled-water opportunities. There was wide variation in whole building energy savings, ranging from 0 to 50% and 0 to 18 $/m2 with median percent annual whole building savings of 12% and median normalized annual cost savings of $1.75/m2. In addition to documenting these key findings, the paper provides a list of opportunities that can be automatically and continuously identified and corrected and offers a list of those opportunities that should be the focus of the mandates.

Katipamula, Srinivas↗

Developing High PV Penetration Cases for Frequency Response Study of U.S. Western Interconnection

Recent large penetrations of solar photovoltaic (PV) generation and the inertial characteristics of inverter-based generation technologies have caught the attention of those in the electric power industry in the United States. This paper presents a systematic approach to developing test cases of high penetrations of PV for the Western Interconnection. First, to examine the accuracy of the base case model, the Western Electricity Coordinating Council (WECC) model is validated by using measurement data from synchronized phasor measurement units. Based on the 2022 Light Spring case, we developed four high PV penetration cases for the WECC system that are of interest to the industry: 5% PV+15 % wind, 25% PV+15% wind, 45% PV+15% wind, 65% PV+15% wind). Additionally, a method to project PV is proposed that is based on collected, realistic PV distribution information, including the current and future PV power plant locations and penetrations in the WECC system. Both the utility-scale PV plant and residential rooftop PV are included in this study.

14 SOLAR ENERGY↗

Qualification of the U.S. Conductors for ITER TF Magnet System

The U.S. Domestic Agency is one of the six suppliers of the toroidal field (TF) conductor for ITER. To qualify conductors per ITER requirements, we prepared or provided to the Swiss Plasma Center (SPC) eight test articles, sixteen conductors total, that were tested in the SULTAN facility at SPC in the ITER relevant conditions. The strands that were used in these SULTAN samples were fully characterized in the laboratories. In this paper, we report both test results and analysis of the conductors' performance against expected strand performance. The U.S. TF conductors showed a slightly better than average current sharing temperature and a relatively low sensitivity to warm up-cooldown cycles in comparison with other suppliers' conductors. However, the trend in current sharing temperature versus cycles and warm ups did not saturate, which means a continuing slow degradation of the conductor performance if the number of warm up and cooldown cycles will be significantly higher than expected. The ac losses in the U.S. TF conductors are in line with losses in the other TF conductor suppliers.

Martovetsky, Nicolai↗

An assessment of U.S. rare earth availability for supporting U.S. wind energy growth targets

Global initiatives are focused on deploying clean energy technologies that decrease greenhouse gas emissions. However, many of these technologies rely heavily on a volatile rare earth element (REE) supply chain. In 2016, the global supply of these REEs continues to be concentrated within a small number of countries while clean energy demand continues to grow. To address the critical nature of these REEs, global efforts have been made to diversify supply of REEs. However, it is unclear if the success of these efforts, combined with the most-promising domestic REO production capacity, will be enough to ensure REE supply for domestic clean energy technology demand, including wind energy. We apply a static and dynamic approach to estimate U.S. REE production capacity and its associated effect on U.S. wind energy growth out to 2030. Our static approach shows that U.S. light REE supply from the Mountain Pass, Bear Lodge and potential Phosphate mines operating at maximum production capacity could provide significant light REE supply to satisfy U.S. targets for wind energy REE consumption. Furthermore, when we consider market dynamics, domestic light REE production is inadequate for alleviating the supply constraint which limits overall U.S. wind energy growth out to 2030.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

The Application of Current Mineral Processing and Extractive Metallurgy Technologies to Potential Rare Earth Ores in the U.S. Coal Measures: Near-Term Opportunities to Fill Out the U.S. Value Chain

This report will consider the potential for currently available mineral processing and extractive metallurgy technologies to produce separated rare earth compounds from U.S. coal and coal byproducts. Implementation of production as such would require restoration of elements of the rare earth value chain that have recently been absent in the U.S., notably for chemical extraction of rare earth compounds from the mineral form (i.e. hydrometallurgical extraction). A variety of existing technologies are available for use in both mineral processing and extractive metallurgy applied to RE production in the U.S. As will be discussed, once a mineral concentrate is produced, the contained rare earth value can be large compared with transportation costs, and the sections of the value chain dealing with chemical extraction (the largest cost) and separation into individual rare earth compounds can be remotely located. Also, as will be discussed, this has been the rule rather than exception in the history of the rare earth industry in the U.S. A strategy, possibly to include repurposing of existing metallurgical processing facilities, will be presented for near-term production, using a decentralized set of facilities. Also presented will be research results from the Office of Fossil Energy (FE) and the National Energy Technology Laboratory (NETL), within the U.S. Department of Energy, relevant to economic feasibility of rare earth production, notably from the standpoint of establishing which materials are capable of providing economic production. Simple methodologies are presented for both establishment of cutoff grades and economic evaluation of a process. The goal of this report is to present an overview of methods and pathways that will result in “the achievement of near-term rare earth production, using currently available technologies to produce a mixed, chemical extracted rare earth concentrate, and existing and new facilities to produce separated rare earths that can “plug in” to the metals and magnet production facilities.” A set of recommendations appears at the end of this work, involving both research and project development activities which will enable the achievement of this noble goal. A set of recommendations appears at the end of this work, involving both research and project development activities.

58 GEOSCIENCES↗

Potentials for Platooning in U.S. Highway Freight Transport

Smart technologies enabling connection among vehicles and between vehicles and infrastructure as well as vehicle automation to assist human operators are receiving significant attention as a means for improving road transportation systems by reducing fuel consumption - and related emissions - while also providing additional benefits through improving overall traffic safety and efficiency. For truck applications, which are currently responsible for nearly three-quarters of the total U.S. freight energy use and greenhouse gas (GHG) emissions, platooning has been identified as an early feature for connected and automated vehicles (CAVs) that could provide significant fuel savings and improved traffic safety and efficiency without radical design or technology changes compared to existing vehicles. A statistical analysis was performed based on a large collection of real-world U.S. truck usage data to estimate the fraction of total miles that are technically suitable for platooning. In particular, our analysis focuses on estimating 'platoonable' mileage based on overall highway vehicle use and prolonged high-velocity traveling, and established that about 65% of the total miles driven by combination trucks from this data sample could be driven in platoon formation, leading to a 4% reduction in total truck fuel consumption. This technical potential for 'platoonable' miles in the United States provides an upper bound for scenario analysis considering fleet willingness and convenience to platoon as an estimate of overall benefits of early adoption of connected and automated vehicle technologies. A benefit analysis is proposed to assess the overall potential for energy savings and emissions mitigation by widespread implementation of highway platooning for trucks.

30 DIRECT ENERGY CONVERSION↗

Characteristics of low-priced solar PV systems in the U.S.

Despite impressive declines in average prices, there is wide dispersion in the prices of U.S. solar photovoltaic (PV) systems; prices span more than a factor of four. What are the characteristics of the systems with low-prices? Using detailed characteristics of 42,611 small-scale (<15 kW) PV systems installed in 15 U.S. states during 2013, we identify the most important factors that make a system likely to be low-priced (LP). Comparing LP and non-LP systems, we find statistically significant differences in nearly all characteristics for which we have data. Logit and probit model results robustly indicate that LP systems are associated with: markets with few active installers; experienced installers; customer ownership; large systems; retrofits; and thin-film, low-efficiency, and Chinese modules. We also find significant differences across states, with LP systems much more likely to occur in some states, such as Arizona, New Jersey, and New Mexico, and less likely in others, such as California. Our focus on the left tail of the price distribution provides implications for policy that are distinct from recent studies of mean prices. While those studies find that PV subsidies increase mean prices, we find that subsidies also generate LP systems. PV subsidies appear to simultaneously shift and broaden the price distribution. Much of this broadening occurs in a particular location, northern California.

14 SOLAR ENERGY↗

Particulate and Trace Gas Emissions from Prescribed Burns in Southeastern U.S. fuel types: Summary of a 5-year Project

Prescribed burning is an accepted practice to manage biomass in the United States and throughout the world. It is a particularly important practice in pine forests throughout the world, many of which have evolved in the presence of fire [1]. A recent survey [2] of prescribed fire use reported that 2.62 x 106 ha of forest land in the southeastern U.S. (defined by the National Association of State Foresters) burned in 2011 for silvicultural purposes such as hazardous fuel reduction, wildlife habitat improvement, and forest regeneration. Earlier surveys reported 0.9 to 1.7 x 106 ha of prescribed burning in the southern U.S. [3–5] using different survey techniques. While it is not possible to determine confidence intervals on these estimates, it is clear that the use of prescribed burning has increased since the first published estimate of 1 x 106 ha we were able to locate or the recent survey captured more information. Smoke is an important consequence of prescribed burning that must be managed, [6] and a great deal of research has been performed since the 1970s trying to characterize the composition, production, and transport of smoke from such fires. A recent review of the state of science behind estimation of the contribution of wildland fire to greenhouse gases and black carbon in the U.S. identified several areas of research that must be performed [7]. In particular, two areas of knowledge that still need improvement are fuel characterization and smoke emissions, and the correlation(s) between the two. While many fuel types in the southeastern U.S. have been described for fire behavior and fire danger prediction, characterization of fuel bed components important for smoke production is more limited. Emissions characterization, both chemical and particulate, is needed to determine potential impacts of prescribed burning on nutrient cycling, planetary albedo, human health, and highway visibility [e.g. 8–10].

Weise, David↗