Materials Data on TmPPt by Materials Project
TmPtP is hexagonal omega structure-derived structured and crystallizes in the hexagonal P-6m2 space group. The structure is three-dimensional. Tm3+ is bonded to six equivalent Pt2- and six equivalent P1- atoms to form a mixture of face and edge-sharing TmP6Pt6 cuboctahedra. All Tm–Pt bond lengths are 3.05 Å. All Tm–P bond lengths are 3.05 Å. Pt2- is bonded in a 9-coordinate geometry to six equivalent Tm3+ and three equivalent P1- atoms. All Pt–P bond lengths are 2.38 Å. P1- is bonded in a 9-coordinate geometry to six equivalent Tm3+ and three equivalent Pt2- atoms.
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